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The reaction proceeds through a radical 1,2-boron shift cascade, enabling the efficient conversion of \u03b2-boryl radicals into carbon radicals for subsequent SH2 cross-coupling with a monofluoromethyl radical. This method provides a mild and practical approach to access \u03b2-fluoromethylated boronic esters bearing versatile boronate functionalities. 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Soc."},{"key":"2026090409100033600_cit17b","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202207988","article-title":"Dual Nickel\/Photoredox-Catalyzed\nSite-Selective Cross-Coupling of 1,2-Bis-Boronic Esters Enabled by\n1,2-Boron Shifts","volume":"61","author":"Wang","year":"2022","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026090409100033600_cit17c","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202202061","article-title":"Selective\nCoupling of 1,2-Bis-Boronic Esters at the more Substituted Site through\nVisible-Light Activation of Electron Donor\u2013Acceptor Complexes","volume":"61","author":"Wang","year":"2022","journal-title":"Angew. Chem., Int. 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Lett."},{"key":"2026090409100033600_cit19b","doi-asserted-by":"publisher","first-page":"5693","DOI":"10.1038\/s41467-023-41254-1","article-title":"Decarboxylation of \u03b2-boryl NHPI esters enables\nradical 1,2-boron shift for the assembly of versatile organoborons","volume":"14","author":"Guo","year":"2023","journal-title":"Nat. Commun."},{"key":"2026090409100033600_cit20a","doi-asserted-by":"publisher","first-page":"1021","DOI":"10.1038\/s44160-026-01018-3","article-title":"Positional editing of diverse functional groups through radical 1,2-boron\nshifts","volume":"5","author":"Zhang","year":"2026","journal-title":"Nat. Synth."},{"key":"2026090409100033600_cit20b","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2026.102961","article-title":"1,2-Boryl\/hydrogen\ntransposition via reversible C\u2013H sampling","volume":"12","author":"Xie","year":"2026","journal-title":"Chem."},{"key":"2026090409100033600_cit20c","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adn8401","article-title":"N-Heterocyclic carbene catalytic 1,2-boron migrative acylation accelerated\nby photocatalysis","volume":"10","author":"Huang","year":"2024","journal-title":"Sci. Adv."},{"key":"2026090409100033600_cit20d","doi-asserted-by":"publisher","first-page":"5270","DOI":"10.1021\/acs.orglett.5c01486","article-title":"Zn-Mediated Fragmentation of \u03b2-Boryl NHPI Esters\nEnabling the Radical 1,2-Boron Shift for the Synthesis of gem-Difluoroalkenyl\nBoronates","volume":"27","author":"Pang","year":"2025","journal-title":"Org. Lett."},{"key":"2026090409100033600_cit20e","doi-asserted-by":"publisher","first-page":"2918","DOI":"10.1002\/cjoc.70684","article-title":"Controllable Chemodivergent\nSynthesis of \u03b1-Trifluoromethyl Boronates and gem-Difluoroalkenyl\nBoronates via Photoredox 1,2-Boron Migratory Carbonylation","volume":"44","author":"Cui","year":"2026","journal-title":"Chin. J. Chem."},{"key":"2026090409100033600_cit21a","doi-asserted-by":"publisher","first-page":"1258","DOI":"10.1126\/science.abl4322","article-title":"A biomimetic\nSH2 cross-coupling mechanism for quaternary sp3-carbon formation","volume":"374","author":"Liu","year":"2021","journal-title":"Science"},{"key":"2026090409100033600_cit21b","doi-asserted-by":"publisher","first-page":"1569","DOI":"10.1038\/s41557-023-01317-8","article-title":"Iron(III)-based\nmetalloradical catalysis for asymmetric cyclopropanation via a stepwise\nradical mechanism","volume":"15","author":"Lee","year":"2023","journal-title":"Nat. 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Soc."},{"key":"2026090409100033600_cit21e","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202400955","article-title":"Bimolecular Homolytic\nSubstitution (SH2) at a Transition Metal","volume":"16","author":"Zhang","year":"2024","journal-title":"ChemCatChem."},{"key":"2026090409100033600_cit21f","doi-asserted-by":"publisher","first-page":"1232","DOI":"10.1038\/s44160-025-00840-5","article-title":"Nickel-catalysed enantioselective migratory reductive cross-coupling\nenabled by radical 1,2-amino migration","volume":"4","author":"Ren","year":"2025","journal-title":"Nat.\nSynth."},{"key":"2026090409100033600_cit21g","doi-asserted-by":"publisher","first-page":"7218","DOI":"10.1038\/s41467-025-62092-3","article-title":"Asymmetric synthesis of \u03b2-amino acid derivatives by stereocontrolled\nC(sp3)-C(sp2) cross-electrophile coupling via radical 1,2-nitrogen\nmigration","volume":"16","author":"Liao","year":"2025","journal-title":"Nat. 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