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Here we report a visible-light-driven lanthanum-catalyzed oxidative cleavage strategy that efficiently converts unstrained cycloalkanols into 1,n-dicarbonyls under mild conditions. The strategy exploits a ligand-to-metal charge transfer process to achieve precise site-selective cleavage of unactivated C\u2013C bonds. This method accommodates four- to 15-membered-ring substrates and displays broad functional-group tolerance. Importantly, simply by tuning the substrate structure, diverse 1,n-dicarbonyl products\u2500including 1,n-keto acids, 1,n-diketones, and 1,n-keto esters\u2500can be conveniently accessed. The overall tandem process avoids the destruction of sensitive functional groups typical of conventional oxidation systems and unveils a dual role for O2: it serves as the terminal oxidant that drives the catalytic cycle while directly participating in substrate oxygenation, offering a synergistic catalytic mode for carbon-skeleton editing.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03352","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T08:01:51Z","timestamp":1788768111000},"page":"11688-11694","source":"Crossref","is-referenced-by-count":0,"title":["Lanthanum-Catalyzed\nSkeletal Editing of Cycloalkanols:\nOxidative C\u2013C Cleavage to 1,\n                    <i>n<\/i>\n                    -Dicarbonyls"],"prefix":"10.1021","volume":"28","author":[{"given":"Sirui","family":"Zhu","sequence":"first","affiliation":[{"name":"Minnan Normal University , , ,","place":["Zhangzhou, China, 363000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lele","family":"Zhang","sequence":"additional","affiliation":[{"name":"Peking University , , ,","place":["Shenzhen, China, 518055"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Siqi","family":"Wang","sequence":"additional","affiliation":[{"name":"Minnan Normal University , , ,","place":["Zhangzhou, China, 363000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weihan","family":"Lin","sequence":"additional","affiliation":[{"name":"Minnan Normal University , , ,","place":["Zhangzhou, China, 363000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gengqiang","family":"Zhang","sequence":"additional","affiliation":[{"name":"Minnan Normal University , , ,","place":["Zhangzhou, China, 363000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6458-870X","authenticated-orcid":true,"given":"Zhixiong","family":"Cai","sequence":"additional","affiliation":[{"name":"Minnan Normal University , , ,","place":["Zhangzhou, China, 363000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-3963-4847","authenticated-orcid":true,"given":"Feiming","family":"Li","sequence":"additional","affiliation":[{"name":"Minnan Normal University , , ,","place":["Zhangzhou, China, 363000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingqiang","family":"Huang","sequence":"additional","affiliation":[{"name":"Minnan Normal University , , ,","place":["Zhangzhou, China, 363000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8959-245X","authenticated-orcid":true,"given":"Shunyou","family":"Cai","sequence":"additional","affiliation":[{"name":"Minnan Normal University , , ,","place":["Zhangzhou, China, 363000"]},{"name":"Peking University , , ,","place":["Shenzhen, China, 518055"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,7]]},"reference":[{"key":"2026091809431813800_cit1a","doi-asserted-by":"publisher","first-page":"506","DOI":"10.1021\/acs.chemrev.0c00030","article-title":"Visible light-driven radical-mediated\nC\u2013C bond cleavage\/functionalization in organic synthesis","volume":"121","author":"Yu","year":"2021","journal-title":"Chem. 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