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The protocol affords diverse \u03b1,\u03b1-difluoromonofluoromethoxy ketones from readily available \u03b1-halo ketones under mild conditions with broad substrate scope and excellent functional group tolerance. It is amenable to one-pot synthesis and late-stage diversification of pharmaceuticals and bioactive molecules. The strategy is further applicable to trifluoroethoxylation and alkoxylation, demonstrating the versatility of this radical fluoroalkoxylation platform. 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