{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T13:57:37Z","timestamp":1790949457370,"version":"4.1.0"},"reference-count":36,"publisher":"American Chemical Society (ACS)","issue":"39","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100018694","name":"HORIZON EUROPE Marie Sklodowska-Curie Actions","doi-asserted-by":"publisher","award":["101151638"],"award-info":[{"award-number":["101151638"]}],"id":[{"id":"10.13039\/100018694","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Carbazoles are valuable building blocks for emerging pharmaceuticals and bioactive compounds. However, methods to access C1\u2013H-aminated carbazoles remain underdeveloped. Current approaches often require multistep syntheses or the use of toxic metals. Herein, we report the first Pd\/NBE-catalyzed C1\u2013H amination of NH-free carbazoles. The method introduces a broad range of cyclic amines onto carbazole scaffold and tolerates several functional groups, including acyl, pivaloyl, and halogen substituents. This approach expands the scope of the Catellani reactions to the direct amination of unprotected carbazoles, offering a concise entry to otherwise challenging C1-aminated scaffolds.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03473","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T10:02:30Z","timestamp":1790071350000},"page":"12339-12344","source":"Crossref","is-referenced-by-count":0,"title":["Direct C1\u2013H\nAmination of Free NH Carbazoles\nEnabled by the Catellani Reaction"],"prefix":"10.1021","volume":"28","author":[{"given":"Ganesh Shivayogappa","family":"Sorabad","sequence":"first","affiliation":[{"name":"University of Parma , , Parco Area delle Scienze 17\/A , ,","place":["Parma (PR), Italy, 43124"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5787-3609","authenticated-orcid":true,"given":"Paolo Pio","family":"Mazzeo","sequence":"additional","affiliation":[{"name":"University of Parma , , Parco Area delle Scienze 17\/A , ,","place":["Parma (PR), Italy, 43124"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Elena","family":"Motti","sequence":"additional","affiliation":[{"name":"University of Parma , , Parco Area delle Scienze 17\/A , ,","place":["Parma (PR), Italy, 43124"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7853-7954","authenticated-orcid":true,"given":"Nicola","family":"Della Ca\u2019","sequence":"additional","affiliation":[{"name":"University of Parma , , Parco Area delle Scienze 17\/A , ,","place":["Parma (PR), Italy, 43124"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,22]]},"reference":[{"key":"2026100208374684000_cit1","doi-asserted-by":"publisher","first-page":"4304","DOI":"10.1039\/D3QM00399J","article-title":"A Review of Fused-Ring Carbazole Derivatives as Emitter\nand\/or Host Materials in Organic Light-Emitting Diode (OLED) Applications","volume":"7","author":"Oner","year":"2023","journal-title":"Mater. 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