{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T16:05:51Z","timestamp":1789747551668,"version":"4.0.1"},"reference-count":38,"publisher":"American Chemical Society (ACS)","issue":"37","license":[{"start":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T00:00:00Z","timestamp":1788912000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100018818","name":"National Research, Development and Innovation Office","doi-asserted-by":"publisher","award":["149447"],"award-info":[{"award-number":["149447"]}],"id":[{"id":"10.13039\/501100018818","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,18]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The title compounds, (RO)(NHR\u2032)P(O)H, were synthesized earlier from P-chloro intermediates by substitutions or from dialkyl phosphites by reaction with organometallic reagents. Instead of these not clear-cut and not efficient transformations, a green, solvent- and catalyst-free synthesis of alkyl phosphonamidates has been developed by the microwave-assisted aminolysis of dialkyl phosphites. The monosubstitution was fully selective. Under more forcing conditions, an interesting side reaction was observed. The resulting products may be valuable reagents to prepare \u03b1-hydroxy- and \u03b1-aminophosphonic derivatives.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03484","type":"journal-article","created":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T15:02:02Z","timestamp":1788966122000},"page":"11784-11788","source":"Crossref","is-referenced-by-count":0,"title":["Preparation\nof Alkyl\n                    <i>N<\/i>\n                    -Alkylphosphonamidates\nby the Microwave-Assisted Selective Monoaminolysis of Dialkyl Phosphites"],"prefix":"10.1021","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-3559-6011","authenticated-orcid":true,"given":"Zsuzsanna","family":"Szalai","sequence":"first","affiliation":[{"name":"Budapest University of Technology and Economics , , Mu\u030begyetem rkp. 3 , ,","place":["Budapest, Hungary, 1111"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anna Sa\u0301ra","family":"Kis","sequence":"additional","affiliation":[{"name":"Budapest University of Technology and Economics , , Mu\u030begyetem rkp. 3 , ,","place":["Budapest, Hungary, 1111"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pe\u0301ter","family":"Keglevich","sequence":"additional","affiliation":[{"name":"Budapest University of Technology and Economics , , Mu\u030begyetem rkp. 3 , ,","place":["Budapest, Hungary, 1111"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5366-472X","authenticated-orcid":true,"given":"Gyo\u0308rgy","family":"Keglevich","sequence":"additional","affiliation":[{"name":"Budapest University of Technology and Economics , , Mu\u030begyetem rkp. 3 , ,","place":["Budapest, Hungary, 1111"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,9]]},"reference":[{"key":"2026091809423841500_cit1a","doi-asserted-by":"publisher","first-page":"83","DOI":"10.1007\/128_2014_583","article-title":"Synthesis of non-racemic \u03b1-hydroxyphosphonates\nvia asymmetric phosphor-aldol reaction","volume":"361","author":"Spilling","year":"2014","journal-title":"Top.\nCurr. 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