{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,23]],"date-time":"2026-10-23T19:44:05Z","timestamp":1792784645501,"version":"4.5.0"},"reference-count":31,"publisher":"American Chemical Society (ACS)","issue":"38","license":[{"start":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T00:00:00Z","timestamp":1789344000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T00:00:00Z","timestamp":1789344000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T00:00:00Z","timestamp":1789344000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001412","name":"Council of Scientific and Industrial Research, India","doi-asserted-by":"publisher","award":["09\/1217(17987)\/2024-EMR-I"],"award-info":[{"award-number":["09\/1217(17987)\/2024-EMR-I"]}],"id":[{"id":"10.13039\/501100001412","id-type":"DOI","asserted-by":"publisher"}]},{"name":"SERB","award":["CRG\/2023\/008284"],"award-info":[{"award-number":["CRG\/2023\/008284"]}],"id":[{"id":"https:\/\/ror.org\/03ffdsr55","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,25]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A photocatalytic decarboxylative amidation methodology turns out to be a straightforward, sustainable, effective, mild, and metal-free protocol for the synthesis of amides. Here, we report a metal-free, environmentally friendly approach to the synthesis of amides via decarboxylative amidation of eco-friendly aryl glyoxylic acids with readily available hydrazines through C\u2013N coupling using eosin Y as a photocatalyst, a CH3CN\/H2O mixture as a green solvent, visible light as a renewable energy source, and air as an oxidant. More importantly, this approach exhibits a broad substrate scope, enabling the efficient conversion of diverse aryl glyoxylic acids and hydrazines into the desired products. Overall, this strategy establishes an excellent eco-friendly approach for the synthesis of biological drugs.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03577","type":"journal-article","created":{"date-parts":[[2026,9,14]],"date-time":"2026-09-14T15:02:19Z","timestamp":1789398139000},"page":"12052-12058","source":"Crossref","is-referenced-by-count":0,"title":["Photocatalytic\nApproach to Decarboxylative Amidation\nof Aryl Glyoxylic Acids with Hydrazines"],"prefix":"10.1021","volume":"28","author":[{"given":"Sandeep","family":"Kumar","sequence":"first","affiliation":[{"name":"Indian Institute of Technology (BHU) , , , ,","place":["Varanasi, U.P., India, 221005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shikha","family":"Pandey","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology (BHU) , , , ,","place":["Varanasi, U.P., India, 221005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Harshita","family":"Pandey","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology (BHU) , , , ,","place":["Varanasi, U.P., India, 221005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Saumitra","family":"Singh","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology (BHU) , , , ,","place":["Varanasi, U.P., India, 221005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7931-9652","authenticated-orcid":true,"given":"Sundaram","family":"Singh","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology (BHU) , , , ,","place":["Varanasi, U.P., India, 221005"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,14]]},"reference":[{"issue":"14","key":"2026092510105954100_cit1","doi-asserted-by":"publisher","first-page":"9219","DOI":"10.1021\/acs.joc.0c01222","article-title":"Oxidative\nAmidation of Amines in Tandem with Transamidation: A Route to Amides\nUsing Visible-Light Energy","volume":"85","author":"Nandi","year":"2020","journal-title":"J. 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