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This transformation exploits commercially accessible O-diphenylphosphinylhydroxylamine (DPPH) as a mild activator, enabling readily available alkyl and aryl primary amines to serve as versatile radical precursors. These radical species efficiently couple with electrophilic sulfinylamine partners to furnish a broad spectrum of alkyl and aryl sulfinamides in generally moderate to good yields. The synthetic robustness and generality of this protocol are further demonstrated by late-stage functionalization of various pharmaceutical scaffolds, scalable synthesis, and diversified downstream derivatization of the obtained sulfinamide products. Mechanistic studies corroborate a radical addition pathway as the plausible reaction mechanism underlying this deaminative transformation.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03711","type":"journal-article","created":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T09:02:27Z","timestamp":1791190947000},"page":"12928-12934","source":"Crossref","is-referenced-by-count":0,"title":["Deaminative\nRadical Sulfinylation Reaction"],"prefix":"10.1021","volume":"28","author":[{"given":"Juan","family":"Tang","sequence":"first","affiliation":[{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]},{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhen-Fu","family":"Ke","sequence":"additional","affiliation":[{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]},{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"En-Yin","family":"Yang","sequence":"additional","affiliation":[{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]},{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mi","family":"Li","sequence":"additional","affiliation":[{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]},{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xue-Qing","family":"Mou","sequence":"additional","affiliation":[{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]},{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yun","family":"Zhang","sequence":"additional","affiliation":[{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]},{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1211-3486","authenticated-orcid":true,"given":"Yong-Zheng","family":"Chen","sequence":"additional","affiliation":[{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]},{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5693-5188","authenticated-orcid":true,"given":"Bao-Dong","family":"Cui","sequence":"additional","affiliation":[{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]},{"name":"Zunyi Medical University , , ,","place":["Zunyi, China, 563000"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,5]]},"reference":[{"key":"2026101608463869800_cit1a","doi-asserted-by":"publisher","first-page":"2976","DOI":"10.1002\/adsc.201800273","article-title":"Sulfonimidamides: Synthesis and Applications\nin Preparative Organic Chemistry","volume":"360","author":"Nandi","year":"2018","journal-title":"Adv. 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