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Notably, the mild and redox-neutral conditions of the method are compatible with a broad range of substrates, including alkenes containing biologically relevant motifs (40 examples, up to 83% yield). The resulting \u03b2-fluoroalkylated nitriles can be diversely derivatized to afford other valuable fluorinated sp3-rich architectures. Mechanistic studies have revealed the key role of a protonated bipyridine-based ligand in enhancing reaction efficiency.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03828","type":"journal-article","created":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T04:01:52Z","timestamp":1791518512000},"page":"13972-13978","source":"Crossref","is-referenced-by-count":0,"title":["Modular Cyano-fluoroalkylation of Unactivated Alkenes\nEnabled by Photoinduced Fe-LMCT Catalysis"],"prefix":"10.1021","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-5238-3252","authenticated-orcid":true,"given":"Mario","family":"Martinez-Lopez","sequence":"first","affiliation":[{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["San Vicente del Raspeig, Spain, 03080"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0321-2167","authenticated-orcid":true,"given":"Irene","family":"Bosque","sequence":"additional","affiliation":[{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["San Vicente del Raspeig, Spain, 03080"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5334-7938","authenticated-orcid":true,"given":"Jose C.","family":"Gonzalez-Gomez","sequence":"additional","affiliation":[{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["San Vicente del Raspeig, Spain, 03080"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6179-7306","authenticated-orcid":true,"given":"Sara","family":"Cuadros","sequence":"additional","affiliation":[{"name":"Universidad de Alicante , , Apdo. 99 , ,","place":["San Vicente del Raspeig, Spain, 03080"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,8]]},"reference":[{"key":"2026111309065499800_cit1","doi-asserted-by":"crossref","DOI":"10.1002\/9781444312096","volume-title":"Fluorine in medicinal\nchemistry and chemical biology","author":"Ojima","year":"2009"},{"key":"2026111309065499800_cit2","doi-asserted-by":"publisher","first-page":"1881","DOI":"10.1126\/science.1131943","article-title":"Fluorine in pharmaceuticals: looking\nbeyond intuition","volume":"317","author":"Mu\u0308ller","year":"2007","journal-title":"Science"},{"key":"2026111309065499800_cit3","doi-asserted-by":"publisher","first-page":"13830","DOI":"10.1039\/D6RA01711H","article-title":"Fluorine-containing FDA-approved\nsmall-molecule drugs\nin 2025: significance, synthetic insights, and therapeutic applications","volume":"16","author":"Mishra","year":"2026","journal-title":"RSC Adv."},{"key":"2026111309065499800_cit4","doi-asserted-by":"publisher","first-page":"637","DOI":"10.1002\/cbic.200301023","article-title":"Fluorine in Medicinal\nChemistry","volume":"5","author":"Bo\u0308hm","year":"2004","journal-title":"ChemBioChem."},{"key":"2026111309065499800_cit5","doi-asserted-by":"publisher","first-page":"8315","DOI":"10.1021\/acs.jmedchem.5b00258","article-title":"Applications\nof Fluorine in Medicinal Chemistry","volume":"58","author":"Gillis","year":"2015","journal-title":"J. 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