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This transformation enabled access to functionalized allyl-tethered 3-azabicyclo[3.1.0]hexan-2-one scaffolds via skeletal remodeling. The excellent tolerance of the reaction to functional groups across structurally and electronically diverse substrates demonstrates their broad applicability. The operational simplicity and practical utility of this protocol scale to gram-scale synthesis of azabicyclo[3.1.0]hexan-2-ones as well as to synthetic utility and late-stage structural modifications.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03836","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T15:03:43Z","timestamp":1790089423000},"page":"12502-12507","source":"Crossref","is-referenced-by-count":0,"title":["Pd-Catalyzed\nSkeletal Remodeling of Bicyclo[1.1.0]butane\nCarboxamides to Azabicyclo[3.1.0]hexan-2-ones via a Pd(II)\u2013Carbene\nIntermediate"],"prefix":"10.1021","volume":"28","author":[{"given":"Mohammad","family":"Saleem","sequence":"first","affiliation":[{"name":"Indian Institute of Technology Roorkee , , , ,","place":["Roorkee, Uttarakhand, India, 247667"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sandeep Singh","family":"Bisht","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Roorkee , , , ,","place":["Roorkee, Uttarakhand, India, 247667"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ankit K.","family":"Nakum","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Roorkee , , , ,","place":["Roorkee, Uttarakhand, India, 247667"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8305-3519","authenticated-orcid":true,"given":"Dongari","family":"Yadagiri","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Roorkee , , , ,","place":["Roorkee, Uttarakhand, India, 247667"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,22]]},"reference":[{"key":"2026100208380088200_cit1a","unstructured":"(a)\n          \n            \n              Armstrong, M. 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