{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T16:57:31Z","timestamp":1791565051143,"version":"4.3.4"},"reference-count":41,"publisher":"American Chemical Society (ACS)","issue":"40","license":[{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100010023","name":"Natural Science Research of Jiangsu Higher Education Institutions of China","doi-asserted-by":"publisher","award":["25KJB180002"],"award-info":[{"award-number":["25KJB180002"]}],"id":[{"id":"10.13039\/501100010023","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20251106"],"award-info":[{"award-number":["BK20251106"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22171197"],"award-info":[{"award-number":["22171197"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22508138"],"award-info":[{"award-number":["22508138"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22678232"],"award-info":[{"award-number":["22678232"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Bromotrifluoromethane (CF3Br, Halon-1301) is a potent greenhouse gas and ozone-depleting substance. Here, we report the use of CF3Br as a trifluoromethyl source for the photocatalytic C\u2013H trifluoromethylation of (hetero)arenes. The reaction proceeds at ambient temperature and pressure without an external oxidant, affords products in yields of up to 89%, and accommodates bioactive molecules, including nucleosides, providing a route for the value-added utilization of Halon-1301.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c03909","type":"journal-article","created":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T16:05:58Z","timestamp":1790611558000},"page":"12825-12830","source":"Crossref","is-referenced-by-count":0,"title":["Photocatalytic\nC\u2013H Trifluoromethylation of\n(Hetero)arenes with Halon-1301"],"prefix":"10.1021","volume":"28","author":[{"given":"Kehan","family":"Zhou","sequence":"first","affiliation":[{"name":"Huaiyin Normal University , , , ,","place":["Huai\u2019an, Jiangsu, China, 223300"]},{"name":"Soochow University , , , ,","place":["Suzhou, Jiangsu, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junrui","family":"Wang","sequence":"additional","affiliation":[{"name":"Soochow University , , , ,","place":["Suzhou, Jiangsu, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0536-7381","authenticated-orcid":true,"given":"Tao","family":"Wu","sequence":"additional","affiliation":[{"name":"Huaiyin Normal University , , , ,","place":["Huai\u2019an, Jiangsu, China, 223300"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-3720-4912","authenticated-orcid":true,"given":"Aiyong","family":"He","sequence":"additional","affiliation":[{"name":"Huaiyin Normal University , , , ,","place":["Huai\u2019an, Jiangsu, China, 223300"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhi-bin","family":"Huang","sequence":"additional","affiliation":[{"name":"Soochow University , , , ,","place":["Suzhou, Jiangsu, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9112-5161","authenticated-orcid":true,"given":"Jiaxing","family":"Xu","sequence":"additional","affiliation":[{"name":"Huaiyin Normal University , , , ,","place":["Huai\u2019an, Jiangsu, China, 223300"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6142-7839","authenticated-orcid":true,"given":"Yingsheng","family":"Zhao","sequence":"additional","affiliation":[{"name":"Soochow University , , , ,","place":["Suzhou, Jiangsu, China, 215123"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,28]]},"reference":[{"key":"2026100910145025800_cit1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1002\/14356007.a11_349.pub2","article-title":"Fluorine Compounds, Organic","volume-title":"Ullmann\u2019s Encyclopedia of Industrial Chemistry","author":"Siegemund","year":"2016"},{"key":"2026100910145025800_cit2","doi-asserted-by":"publisher","first-page":"13","DOI":"10.1016\/j.jphotochem.2015.03.012","article-title":"CBrF3 (Halon-1301): UV\nabsorption spectrum between 210 and 320\nK, atmospheric lifetime, and ozone depletion potential","volume":"306","author":"Bernard","year":"2015","journal-title":"J. Photochem. Photobiol. A Chem."},{"key":"2026100910145025800_cit3","doi-asserted-by":"crossref","first-page":"3663","DOI":"10.1002\/2015JD024488","article-title":"Atmospheric\nhistories and global emissions of halons H-1211 (CBrClF2), H-1301 (CBrF3), and H-2402 (CBrF2CBrF2)","volume":"121","author":"Vollmer","year":"2016","journal-title":"J. Geophys. Res."},{"key":"2026100910145025800_cit4","volume-title":"Chemistry of atmospheres","author":"Wayne","year":"1991"},{"key":"2026100910145025800_cit5a","doi-asserted-by":"publisher","first-page":"1036","DOI":"10.1021\/acs.accounts.5c00039","article-title":"Single-Electron-Transfer-Mediated\nCarbonylation Reactions","volume":"58","author":"Wang","year":"2025","journal-title":"Acc. Chem. Res."},{"key":"2026100910145025800_cit5b","doi-asserted-by":"publisher","first-page":"6726","DOI":"10.1039\/D5CS00181A","article-title":"Navigating the functionalization of unactivated alkenes via visible\nlight photocatalysis","volume":"54","author":"Cao","year":"2025","journal-title":"Chem. Soc. Rev."},{"key":"2026100910145025800_cit5c","doi-asserted-by":"publisher","first-page":"832","DOI":"10.1038\/s41929-022-00841-z","article-title":"Visible-light\nphotocatalytic di- and hydro-carboxylation of unactivated alkenes\nwith CO2","volume":"5","author":"Song","year":"2022","journal-title":"Nature Catal."},{"key":"2026100910145025800_cit5d","doi-asserted-by":"publisher","first-page":"14864","DOI":"10.1021\/jacs.4c04211","article-title":"Enantioselective\nNickel-Electrocatalyzed Reductive Propargylic Carboxylation with CO2","volume":"146","author":"Hu","year":"2024","journal-title":"J. Am. Chem. 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Soc."},{"key":"2026100910145025800_cit12a","doi-asserted-by":"publisher","first-page":"984","DOI":"10.1021\/jo00003a017","article-title":"Preparation\nof trifluoromethyl and other perfluoroalkyl compounds with (perfluoroalkyl)trimethylsilanes","volume":"56","author":"Krishnamurti","year":"1991","journal-title":"J. Org. Chem."},{"key":"2026100910145025800_cit12b","doi-asserted-by":"publisher","first-page":"2452","DOI":"10.1021\/jo00271a041","article-title":"Reactions\nof bromotrifluoromethane and related halides. 8. Condensations with\ndithionite and hydroxymethanesulfinate salts","volume":"54","author":"Tordeux","year":"1989","journal-title":"J. Org. Chem."},{"key":"2026100910145025800_cit12c","doi-asserted-by":"publisher","first-page":"22570","DOI":"10.1002\/anie.202009844","article-title":"Solid-State\nRadical C\u2013H Trifluoromethylation Reactions Using Ball Milling\nand Piezoelectric Materials","volume":"59","author":"Pang","year":"2020","journal-title":"Angew. 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Ed."},{"key":"2026100910145025800_cit16","doi-asserted-by":"publisher","first-page":"224","DOI":"10.1038\/nature10647","article-title":"Trifluoromethylation\nof arenes and heteroarenes by\nmeans of photoredox catalysis","volume":"480","author":"Nagib","year":"2011","journal-title":"Nature"},{"key":"2026100910145025800_cit17","doi-asserted-by":"publisher","first-page":"3712","DOI":"10.1002\/anie.201410954","article-title":"Condensed-Phase,\nHalogen-Bonded CF3I and C2F5I Adducts\nfor Perfluoroalkylation Reactions","volume":"54","author":"Sladojevich","year":"2015","journal-title":"Angew. Chem.,\nInt. Ed."},{"key":"2026100910145025800_cit18a","doi-asserted-by":"publisher","first-page":"6926","DOI":"10.1002\/anie.201803566","article-title":"Trifluoromethanesulfonic\nAnhydride as a Low-Cost and Versatile Trifluoromethylation Reagent","volume":"57","author":"Ouyang","year":"2018","journal-title":"Angew. Chem., Int. 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