{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T13:52:03Z","timestamp":1792158723914,"version":"4.4.0"},"reference-count":35,"publisher":"American Chemical Society (ACS)","issue":"41","license":[{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100004735","name":"Natural Science Foundation of Hunan Province","doi-asserted-by":"publisher","award":["2024JJ5416"],"award-info":[{"award-number":["2024JJ5416"]}],"id":[{"id":"10.13039\/501100004735","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004735","name":"Natural Science Foundation of Hunan Province","doi-asserted-by":"publisher","award":["2026JJ60012"],"award-info":[{"award-number":["2026JJ60012"]}],"id":[{"id":"10.13039\/501100004735","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22378432"],"award-info":[{"award-number":["22378432"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22478446"],"award-info":[{"award-number":["22478446"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Xiangjiang Laboratory","award":["25XJ02006"],"award-info":[{"award-number":["25XJ02006"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,16]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A visible light-induced, energy transfer-mediated strategy for the carboamination of alkenes was developed using a rationally designed enyl oxime ester-based bifunctional reagent, enabling the efficient construction of structurally diverse \u03b3-amino-1,3-dicarbonyl compounds. The novel bifunctional reagent can be facilely prepared from readily available feedstock chemicals, and the rationale of this structural design relies on the resonance-driven spin center shift (SCS) to generate the key carbon-centered radical. A wide range of alkenes participated in this transformation smoothly, affording the desired products in moderate to good yields with excellent functional group tolerance and high regioselectivity (&amp;gt;20:1). This work not only provides a new strategy for the efficient construction of \u03b3-amino-1,3-dicarbonyl scaffolds but also demonstrates the potential of innovative bifunctional reagent design in expanding the synthetic utility of energy transfer catalysis.<\/jats:p>","DOI":"10.1021\/acs.orglett.6c04244","type":"journal-article","created":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T07:02:29Z","timestamp":1791183749000},"page":"13123-13128","source":"Crossref","is-referenced-by-count":0,"title":["Energy Transfer-Mediated\nCarboamination of Alkenes\nto Access \u03b3-Amino-1,3-dicarbonyl Scaffolds"],"prefix":"10.1021","volume":"28","author":[{"given":"Cong","family":"Huang","sequence":"first","affiliation":[{"name":"Central South University , , ,","place":["Changsha, P. R. China, 410083"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qian","family":"Zhang","sequence":"additional","affiliation":[{"name":"Central South University , , ,","place":["Changsha, P. R. China, 410083"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mei","family":"Xiang","sequence":"additional","affiliation":[{"name":"Central South University , , ,","place":["Changsha, P. R. China, 410083"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jie","family":"Gao","sequence":"additional","affiliation":[{"name":"Central South University , , ,","place":["Changsha, P. R. China, 410083"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1012-0383","authenticated-orcid":true,"given":"Kai","family":"Chen","sequence":"additional","affiliation":[{"name":"Central South University , , ,","place":["Changsha, P. R. China, 410083"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Zheng","sequence":"additional","affiliation":[{"name":"Central South University , , ,","place":["Changsha, P. R. China, 410083"]},{"name":"Xiangjiang Laboratory , ,","place":["Changsha, P. R. China, 410205"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5518-5255","authenticated-orcid":true,"given":"Hua","family":"Yang","sequence":"additional","affiliation":[{"name":"Central South University , , ,","place":["Changsha, P. R. China, 410083"]},{"name":"Xiangjiang Laboratory , ,","place":["Changsha, P. R. 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Chem."},{"key":"2026101608465240900_cit3","doi-asserted-by":"publisher","first-page":"3236","DOI":"10.1039\/D5CS01300C","article-title":"Innovative approaches to the synthesis of five-membered heteroaromatics\nwith emerging synthetic methodologies","volume":"55","author":"Zhang","year":"2026","journal-title":"Chem.\nSoc. Rev."},{"key":"2026101608465240900_cit4a","doi-asserted-by":"publisher","first-page":"5297","DOI":"10.1021\/jacs.7b01115","article-title":"Development of Chiral,\nBifunctional Thiosquaramides:\nEnantioselective Michael Additions of Barbituric Acids to Nitroalkenes","volume":"139","author":"Rombola","year":"2017","journal-title":"J. Am. Chem. Soc."},{"key":"2026101608465240900_cit4b","doi-asserted-by":"publisher","first-page":"9910","DOI":"10.1039\/D1OB01313K","article-title":"Low catalyst loading\nenabled organocatalytic synthesis of chiral bis-heterocyclic frameworks\ncontaining pyrazole and isoxazole","volume":"19","author":"Kaur","year":"2021","journal-title":"Org. 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