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These donors function by the initial release of carbonyl sulfide (COS), which is quickly hydrolyzed to H2S by carbonic anhydrase (CA). Our investigations demonstrate that o-nitrobenzyl-caged thiocarbamates can serve as a donor platform for the bio-orthogonal stimulated release of COS\/H2S.<\/jats:p>","DOI":"10.1021\/acs.orglett.7b00808","type":"journal-article","created":{"date-parts":[[2017,4,17]],"date-time":"2017-04-17T09:18:12Z","timestamp":1492420692000},"page":"2278-2281","source":"Crossref","is-referenced-by-count":101,"title":["Light-Activated COS\/H2S Donation from Photocaged\nThiocarbamates"],"prefix":"10.1021","volume":"19","author":[{"given":"Yu","family":"Zhao","sequence":"first","affiliation":[{"name":"University of Oregon , , , ,","place":["Eugene, Oregon, United States, 97403"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sarah G.","family":"Bolton","sequence":"additional","affiliation":[{"name":"University of Oregon , , , ,","place":["Eugene, Oregon, United States, 97403"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3604-653X","authenticated-orcid":true,"given":"Michael D.","family":"Pluth","sequence":"additional","affiliation":[{"name":"University of Oregon , , , ,","place":["Eugene, Oregon, United States, 97403"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2017,4,17]]},"reference":[{"key":"2026090222575052100_cit1a","doi-asserted-by":"publisher","first-page":"15560","DOI":"10.1073\/pnas.0705891104","volume":"104","author":"Elrod","year":"2007","journal-title":"Proc. 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