{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T18:48:09Z","timestamp":1787165289339,"version":"build-2736575974"},"reference-count":73,"publisher":"American Chemical Society (ACS)","issue":"11","license":[{"start":{"date-parts":[[2025,11,7]],"date-time":"2025-11-07T00:00:00Z","timestamp":1762473600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100010132","name":"\u00d6sterreichische Nationalstiftung f\u00fcr Forschung, Technologie und Entwicklung","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/100010132","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100006012","name":"Christian Doppler Forschungsgesellschaft","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100006012","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012650","name":"Technische Universit\u00e4t Wien Bibliothek","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/501100012650","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/na","name":"Austrian Federal Ministry of Economy, Energy and Tourism","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/na","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2025,11,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Over the last years, stereolithography has developed to be one of the most promising fabrication techniques in tissue engineering. Posing the possibility of fabricating patient-specific, porous implants, it became especially attractive for scaffold fabrication for the treatment of critical sized bone defects. State-of-the-art photopolymer systems mostly consist of potentially cytotoxic compounds, such as (meth)acrylates, that furthermore show insufficient degradation and lead to acidic degradation products that could induce adverse tissue reactions. Herein, we introduced trifunctional monomers comprising cleavable silyl ether groups for thiol\u2013ene photopolymerization to enlarge the material platform for printed bone grafts. Polymer networks comprising a high number of silyl ether moieties typically tend to be mechanically weak and exhibit low Tg values, especially when combined with thioether bonds, which are a direct result of polymerization via thiol\u2013ene click reaction. To push thermomechanical properties to a level where they are sufficient for bone grafting (Tg &amp;gt; 37 \u00b0C), we introduced rigid bridged alicyclic structures in the form of norbornane-derived motifs into the silyl ether monomers, resulting in a norbornene-containing double bond monomer and a norbornane-derived thiol monomer. Together with noncleavable comonomers, we were able to demonstrate a substantial increase in Tg up to 62 \u00b0C, which is well above the values reported until now for similar thiol\u2013ene networks. Furthermore, in this study, we demonstrated high photoreactivity for some of the monomers and also successfully performed proof-of-concept printing using a DLP setup. Besides excellent thermomechanical behavior, the mechanical strength of the silyl ether-based polymer network was shown to be outstanding. Cleavability of the silyl ethers was displayed with a quasi-linear degradation rate of 6.5% per month with moderate swelling. Additionally, the degradation product of the silyl ether-based network was isolated and shown to exhibit no relevant cytotoxicity to mouse fibroblast cells.<\/jats:p>","DOI":"10.1021\/acsabm.5c01174","type":"journal-article","created":{"date-parts":[[2025,11,7]],"date-time":"2025-11-07T13:25:37Z","timestamp":1762521937000},"page":"9840-9853","source":"Crossref","is-referenced-by-count":1,"title":["Cleavable Silyl Ether\nMonomers with Elevated Thermomechanical Properties for Bone Regeneration"],"prefix":"10.1021","volume":"8","author":[{"given":"Tina","family":"Gurmann","sequence":"first","affiliation":[{"name":"Christian Doppler Laboratory for Advanced Polymers for Biomaterials and 3D Printing , ,","place":["Vienna, Austria, 1060"]},{"name":"Technische Universita\u0308t Wien , , ,","place":["Vienna, Austria, 1060"]},{"name":"Austrian Cluster for Tissue Regeneration , ,","place":["Vienna, Austria, 1200"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Judith","family":"Krau\u00df","sequence":"additional","affiliation":[{"name":"Technische Universita\u0308t Wien , , ,","place":["Vienna, Austria, 1060"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-9889-2316","authenticated-orcid":true,"given":"Theresa","family":"Ammann","sequence":"additional","affiliation":[{"name":"Technische Universita\u0308t Wien , , ,","place":["Vienna, Austria, 1060"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2801-3113","authenticated-orcid":true,"given":"Thomas","family":"Koch","sequence":"additional","affiliation":[{"name":"Technische Universita\u0308t Wien , , ,","place":["Vienna, Austria, 1060"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Martin","family":"Frauenlob","sequence":"additional","affiliation":[{"name":"Technische Universita\u0308t Wien , , ,","place":["Vienna, Austria, 1060"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7865-1936","authenticated-orcid":true,"given":"Robert","family":"Liska","sequence":"additional","affiliation":[{"name":"Technische Universita\u0308t Wien , , ,","place":["Vienna, Austria, 1060"]},{"name":"Austrian Cluster for Tissue Regeneration , ,","place":["Vienna, Austria, 1200"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5390-0761","authenticated-orcid":true,"given":"Stefan","family":"Baudis","sequence":"additional","affiliation":[{"name":"Christian Doppler Laboratory for Advanced Polymers for Biomaterials and 3D Printing , ,","place":["Vienna, Austria, 1060"]},{"name":"Technische Universita\u0308t Wien , , ,","place":["Vienna, Austria, 1060"]},{"name":"Austrian Cluster for Tissue Regeneration , ,","place":["Vienna, Austria, 1200"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,11,7]]},"reference":[{"issue":"9","key":"2026072914073258600_cit1","doi-asserted-by":"publisher","first-page":"e580","DOI":"10.1016\/S2666-7568(21)00172-0","article-title":"Global, regional, and national burden of bone fractures in 204 countries\nand territories, 1990\u20132019: a systematic analysis from the\nGlobal Burden of Disease Study 2019","volume":"2","author":"GBD 2019 Fracture Collaborators.","year":"2021","journal-title":"Lancet\nHealthy Longev"},{"issue":"3","key":"2026072914073258600_cit2","doi-asserted-by":"publisher","first-page":"569","DOI":"10.1111\/j.1582-4934.2006.tb00421.x","article-title":"The history of tissue engineering","volume":"10","author":"Vacanti","year":"2006","journal-title":"J. Cell. Mol. 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Mater.\nEng."},{"issue":"17","key":"2026072914073258600_cit35","doi-asserted-by":"publisher","first-page":"2881","DOI":"10.1002\/cssc.201801123","article-title":"Renewable Isohexide-Based,\nHydrolytically Degradable Poly(silyl ether)s with High Thermal Stability","volume":"11","author":"Vijjamarri","year":"2018","journal-title":"ChemSusChem"},{"issue":"7","key":"2026072914073258600_cit36","doi-asserted-by":"publisher","first-page":"410","DOI":"10.1524\/zkri.1999.214.7.410","article-title":"Structure of exo, endo, exo, exo-2,3,5,6-tetrabromonorbornane","volume":"214","author":"Celik","year":"1999","journal-title":"Z. Kristallogr.-Cryst. Mater."},{"issue":"2","key":"2026072914073258600_cit37","doi-asserted-by":"publisher","first-page":"256","DOI":"10.1107\/S0108270189006268","article-title":"Stereochemistry of rings. XVII. Norbornane\nderivatives. 1. 2-(p-Methoxyphenyl)-3-phenylbicyclo [2.2. 1] heptane\n(I) and 2-(p-nitrophenyl)-3-phenylbicyclo [2.2. 1] heptane (II)","volume":"46","author":"Bocelli","year":"1990","journal-title":"Acta Crystallogr., Sect. C: Cryst. Struct. Commun."},{"key":"2026072914073258600_cit38","doi-asserted-by":"publisher","first-page":"1733","DOI":"10.3762\/bjoc.10.180","article-title":"Investigations of thiol-modified phenol derivatives\nfor the use in thiol-ene photopolymerizations","volume":"10","author":"Reinelt","year":"2014","journal-title":"Beilstein J. Org. Chem."},{"issue":"14","key":"2026072914073258600_cit39","doi-asserted-by":"publisher","first-page":"1415","DOI":"10.1002\/macp.201400174","article-title":"Synthesis and Photopolymerization of Thiol-Modified\nTriazine-Based Monomers and Oligomers for the Use in Thiol-Ene-Based\nDental Composites","volume":"215","author":"Reinelt","year":"2014","journal-title":"Macromol. Chem. 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Int."},{"issue":"24","key":"2026072914073258600_cit47","doi-asserted-by":"publisher","first-page":"6283","DOI":"10.1002\/pola.20452","article-title":"Influence of the\nalkene structure on the mechanism and kinetics of thiol\u2013alkene\nphotopolymerizations with real-time infrared spectroscopy","volume":"42","author":"Roper","year":"2004","journal-title":"J. Polym. Sci., Part A: Polym. 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