{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T11:58:19Z","timestamp":1785499099310,"version":"3.56.0"},"reference-count":45,"publisher":"American Chemical Society (ACS)","issue":"11","license":[{"start":{"date-parts":[[2025,10,27]],"date-time":"2025-10-27T00:00:00Z","timestamp":1761523200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2025,10,27]],"date-time":"2025-10-27T00:00:00Z","timestamp":1761523200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2025,10,27]],"date-time":"2025-10-27T00:00:00Z","timestamp":1761523200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100021135","name":"Toshiaki Ogasawara Memorial Foundation","doi-asserted-by":"publisher","award":["NA"],"award-info":[{"award-number":["NA"]}],"id":[{"id":"10.13039\/100021135","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["23H02020"],"award-info":[{"award-number":["23H02020"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["23K13562"],"award-info":[{"award-number":["23K13562"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["25K01524"],"award-info":[{"award-number":["25K01524"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2025,11,17]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A syndiotactic poly(substituted methylene) (st-PM) featuring (2-methoxyethoxy)carbonyl side chains (st-PMECM) exhibited considerably superior antithrombogenicity compared to a typical conventional antithrombogenic polyacrylate comprising the same side chain (i.e., poly(2-methoxyethyl acrylate); PMEA). The number of adherent platelets on the surface of the st-PMECM films was 0.8 \u00d7 103 mm\u20132, which was one-fourth of that on the PMEA films (3.2 \u00d7 103 mm\u20132), and 75% of these platelets were in the lowest activation state. During the platelet adhesion test, the st-PMECM films maintained surface wettability on the substrates, addressing the commonly observed dewetting issue in the practical applications of conventional antithrombogenic polyacrylates. In addition, the st-PMECM films retained their surface structure upon exposure to plasma, as indicated by the unchanged water contact angle over time, unlike in the case of polyacrylates. These characteristics of st-PMECM are attributed to the formation of liquid crystal structure, with the backbone arranged into a two-dimensional lattice and with the side chains stretched at an angle to the backbone axis. Owing to this structure, the methoxy moieties at the ends of the side chains were exposed to the outermost surface and hydrated with water, enabling the st-PMECM films to possess a larger amount of intermediate water on the surface than the PMEA films. The results demonstrate that st-PMs more effectively enhance the functionality of the side chains than polyacrylates featuring the same side chains, enabling st-PMECM to exhibit superior antithrombogenicity attributed to methoxy moieties. To the best of our knowledge, st-PMECM is the first inherently solid-like polymer that simultaneously exhibits outstanding antithrombogenicity.<\/jats:p>","DOI":"10.1021\/acsabm.5c01687","type":"journal-article","created":{"date-parts":[[2025,10,27]],"date-time":"2025-10-27T05:22:24Z","timestamp":1761542544000},"page":"10371-10380","source":"Crossref","is-referenced-by-count":0,"title":["Superior Antithrombogenic\nSyndiotactic Poly(Substituted\nMethylene) with Densely Packed Methoxyethyl Ends of Highly Extended\nSide Chains at the Solid Film Surface"],"prefix":"10.1021","volume":"8","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6864-641X","authenticated-orcid":true,"given":"Naruki","family":"Kurokawa","sequence":"first","affiliation":[{"name":"Institute of Science Tokyo , , Ookayama, Meguro-ku , ,","place":["Tokyo, Japan, 152-8550"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4625-3519","authenticated-orcid":true,"given":"Masamichi","family":"Kiyoura","sequence":"additional","affiliation":[{"name":"Institute of Science Tokyo , , Ookayama, Meguro-ku , ,","place":["Tokyo, Japan, 152-8550"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4949-1184","authenticated-orcid":true,"given":"Hidetoshi","family":"Matsumoto","sequence":"additional","affiliation":[{"name":"Institute of Science Tokyo , , Ookayama, Meguro-ku , ,","place":["Tokyo, Japan, 152-8552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4534-7337","authenticated-orcid":true,"given":"Masatoshi","family":"Tokita","sequence":"additional","affiliation":[{"name":"Institute of Science Tokyo , , Ookayama, Meguro-ku , ,","place":["Tokyo, Japan, 152-8550"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2025,10,27]]},"reference":[{"issue":"12","key":"2026073107122969300_cit1","doi-asserted-by":"publisher","first-page":"1543","DOI":"10.1002\/jbm.820261202","article-title":"Hemocompatibility of human whole blood on polymers\nwith a phospholipid polar group and its mechanism","volume":"26","author":"Ishihara","year":"1992","journal-title":"J. Biomed. Mater. Res."},{"key":"2026073107122969300_cit2","doi-asserted-by":"publisher","first-page":"187","DOI":"10.1016\/j.actbio.2019.01.059","article-title":"Micropatterning of a 2-methacryloyloxyethyl\nphosphorylcholine polymer surface by hydrogenated amorphous carbon\nthin films for endothelialization and antithrombogenicity","volume":"87","author":"Bito","year":"2019","journal-title":"Acta Biomater."},{"issue":"12","key":"2026073107122969300_cit3","doi-asserted-by":"publisher","first-page":"3384","DOI":"10.1002\/jbm.a.36201","article-title":"In vitro basic\nfibroblast growth\nfactor (bFGF) delivery using an antithrombogenic 2-methacryloyloxyethyl\nphosphorylcholine (MPC) polymer coated with a micropatterned diamond-like\ncarbon (DLC) film","volume":"105","author":"Bito","year":"2017","journal-title":"J. Biomed. Mater. Res., Part\nA"},{"issue":"35","key":"2026073107122969300_cit4","doi-asserted-by":"publisher","first-page":"5718","DOI":"10.1039\/C4TB00881B","article-title":"Blood compatible\nmaterials: state of the art","volume":"2","author":"Liu","year":"2014","journal-title":"J. Mater. Chem.\nB"},{"key":"2026073107122969300_cit5","doi-asserted-by":"publisher","first-page":"123876","DOI":"10.1016\/j.polymer.2021.123876","article-title":"Antithrombogenic\npoly(2-methoxyethyl acrylate) elastomer via triblock copolymerization\nwith poly(methyl methacrylate)","volume":"228","author":"Kurokawa","year":"2021","journal-title":"Polymer"},{"issue":"12","key":"2026073107122969300_cit6","doi-asserted-by":"publisher","first-page":"4214","DOI":"10.1021\/acs.biomac.7b01247","article-title":"Poly(omega-methoxyalkyl\nacrylate)s: Nonthrombogenic Polymer Family with Tunable Protein Adsorption","volume":"18","author":"Kobayashi","year":"2017","journal-title":"Biomacromolecules"},{"issue":"9","key":"2026073107122969300_cit7","doi-asserted-by":"publisher","first-page":"1296","DOI":"10.1002\/mabi.201500078","article-title":"The Relationship Between\nWater Structure\nand Blood Compatibility in Poly(2-methoxyethyl Acrylate) (PMEA) Analogues","volume":"15","author":"Sato","year":"2015","journal-title":"Macromol. Biosci."},{"issue":"5","key":"2026073107122969300_cit8","doi-asserted-by":"publisher","first-page":"1609","DOI":"10.1021\/acs.biomac.7b00221","article-title":"Synthesis\nand Thrombogenicity Evaluation of Poly(3-methoxypropionic acid vinyl\nester): A Candidate for Blood-Compatible Polymers","volume":"18","author":"Sato","year":"2017","journal-title":"Biomacromolecules"},{"issue":"19","key":"2026073107122969300_cit9","doi-asserted-by":"publisher","first-page":"8570","DOI":"10.1021\/acs.macromol.0c01144","article-title":"Side-Chain\nSpacing\nControl of Derivatives of Poly(2-methoxyethyl acrylate): Impact on\nHydration States and Antithrombogenicity","volume":"53","author":"Sonoda","year":"2020","journal-title":"Macromolecules"},{"issue":"7","key":"2026073107122969300_cit10","doi-asserted-by":"publisher","first-page":"701","DOI":"10.1038\/pj.2012.229","article-title":"The roles\nof water molecules at the\nbiointerface of medical polymers","volume":"45","author":"Tanaka","year":"2013","journal-title":"Polym. J."},{"issue":"4","key":"2026073107122969300_cit11","doi-asserted-by":"publisher","first-page":"684","DOI":"10.1002\/jbm.a.20088","article-title":"Effect of\nwater structure on blood compatibility\u2500\nthermal analysis of water in poly(meth)acrylate","volume":"68A","author":"Tanaka","year":"2004","journal-title":"J. Biomed. Mater. Res., Part A"},{"issue":"12","key":"2026073107122969300_cit12","doi-asserted-by":"publisher","first-page":"1709","DOI":"10.1002\/1097-0126(200012)49:12&lt;1709::AID-PI601&gt;3.0.CO;2-L","article-title":"Cold crystallization of water in\nhydrated poly(2-methoxyethyl acrylate) (PMEA)","volume":"49","author":"Tanaka","year":"2000","journal-title":"Polym. Int."},{"key":"2026073107122969300_cit13","doi-asserted-by":"publisher","first-page":"114310","DOI":"10.1016\/j.addr.2022.114310","article-title":"Roles of interfacial\nwater states\non advanced biomedical material design","volume":"186","author":"Nishida","year":"2022","journal-title":"Adv.\nDrug Delivery Rev."},{"issue":"1","key":"2026073107122969300_cit14","doi-asserted-by":"publisher","first-page":"36","DOI":"10.1021\/bm010072y","article-title":"Study of Blood\nCompatibility with Poly(2-methoxyethyl acrylate). Relationship between\nWater Structure and Platelet Compatibility in Poly(2-methoxyethylacrylate-co-2-hydroxyethylmethacrylate)","volume":"3","author":"Tanaka","year":"2002","journal-title":"Biomacromolecules"},{"issue":"14","key":"2026073107122969300_cit15","doi-asserted-by":"publisher","first-page":"1831","DOI":"10.1163\/092050610X488269","article-title":"On the role\nof water molecules in the interface between biological systems and\npolymers","volume":"21","author":"Tsuruta","year":"2010","journal-title":"J. Biomater. Sci., Polym. Ed."},{"issue":"3","key":"2026073107122969300_cit16","doi-asserted-by":"publisher","first-page":"995","DOI":"10.1016\/j.polymer.2012.12.072","article-title":"Thermotropic\nbehavior of syndiotactic polymethylenes\nwith alkyloxycarbonyl side chains","volume":"54","author":"Tokita","year":"2013","journal-title":"Polymer"},{"issue":"5","key":"2026073107122969300_cit17","doi-asserted-by":"publisher","first-page":"2300353","DOI":"10.1002\/macp.202300353","article-title":"Syndiotactic\nPoly(Substituted Methylene)s with Alkyloxycarbonyl Side Chains: Effects\nof Side Chain Chirality on the Main Chain Helix and Crystallinity","volume":"225","author":"Kiyoura","year":"2024","journal-title":"Macromol. Chem. Phys."},{"issue":"20","key":"2026073107122969300_cit18","doi-asserted-by":"publisher","first-page":"2400204","DOI":"10.1002\/macp.202400204","article-title":"Correlation Between Side-Chain Arrangement and Main-Chain\nHelix Conformation in Liquid Crystalline Syndiotactic Poly(Substituted\nMethylene)s Bearing Cyanobiphenyl Mesogens","volume":"225","author":"Kiyoura","year":"2024","journal-title":"Macromol. Chem. Phys."},{"issue":"9","key":"2026073107122969300_cit19","doi-asserted-by":"publisher","first-page":"4651","DOI":"10.1039\/D4TC05034G","article-title":"Birefringence inversion in liquid\ncrystalline poly(substituted methylene)s bearing side-on mesogens","volume":"13","author":"Kiyoura","year":"2025","journal-title":"J. Mater. Chem. C"},{"issue":"6","key":"2026073107122969300_cit20","doi-asserted-by":"publisher","first-page":"516","DOI":"10.1246\/cl.230129","article-title":"Ion Conductivity of\nLiquid Crystalline Poly(substituted methylene)s Bearing Ionic Liquid\nMoieties at the Side Chain Ends","volume":"52","author":"Kiyoura","year":"2023","journal-title":"Chem. Lett."},{"issue":"11","key":"2026073107122969300_cit21","doi-asserted-by":"publisher","first-page":"3653","DOI":"10.1021\/acs.macromol.5b00743","article-title":"Thermotropic\nBehavior\nof Syndiotactic Polymethylenes with \u03c9-[4-(trans-4-Pentylcyclohexyl)phenoxy]alkyloxycarbonyl\nSide Chains","volume":"48","author":"Koshimizu","year":"2015","journal-title":"Macromolecules"},{"issue":"17","key":"2026073107122969300_cit22","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202100311","article-title":"Persistent Water Repellency\nof Syndiotactic Polymethylene with Perfluoroethyl Hexyloxycarbonyl\nSide Chains","volume":"42","author":"Yoshitake","year":"2021","journal-title":"Macromol. Rapid Commun."},{"issue":"27","key":"2026073107122969300_cit23","doi-asserted-by":"publisher","first-page":"4525","DOI":"10.1039\/C6PY00818F","article-title":"Synthesis\nof poly(allyl 2-ylidene-acetate)\nand subsequent post-polymerization modification via thiol\u2013ene\nreaction","volume":"7","author":"Krappitz","year":"2016","journal-title":"Polym. Chem."},{"issue":"4","key":"2026073107122969300_cit24","doi-asserted-by":"publisher","first-page":"1415","DOI":"10.1021\/acs.macromol.6b02465","article-title":"Synthesis\nof Poly(glycidyl 2-ylidene-acetate) and Functionalization by Nucleophilic\nRing-Opening Reactions","volume":"50","author":"Krappitz","year":"2017","journal-title":"Macromolecules"},{"issue":"5","key":"2026073107122969300_cit25","doi-asserted-by":"publisher","first-page":"686","DOI":"10.1002\/pola.27891","article-title":"Comparative study on\npost-polymerization modification\nof C1 poly(benzyl 2-ylidene-acetate) and its C2 analog poly(benzyl\nacrylate)","volume":"54","author":"Krappitz","year":"2016","journal-title":"J. Polym. Sci., Part A: Polym. Chem."},{"issue":"6","key":"2026073107122969300_cit26","doi-asserted-by":"publisher","first-page":"785","DOI":"10.1021\/acsmacrolett.2c00212","article-title":"Synthesis of Optically\nActive Helical Polycarbenes\nthrough Helix-Sense-Selective Polymerization Strategy and Their Application\nin Chiral Separation","volume":"11","author":"Gao","year":"2022","journal-title":"ACS Macro Lett."},{"issue":"28","key":"2026073107122969300_cit27","doi-asserted-by":"publisher","first-page":"4201","DOI":"10.1039\/D3CC00237C","article-title":"Facile\npreparation of optically active helical polycarbenes with salicylate\nsubstituents and their postpolymerization modification","volume":"59","author":"Zou","year":"2023","journal-title":"Chem. Commun."},{"issue":"9","key":"2026073107122969300_cit28","doi-asserted-by":"publisher","first-page":"2100455","DOI":"10.1002\/macp.202100455","article-title":"Poly(pentafluorobenzyl\n2-ylidene-acetate): Polymerization and Postpolymerization Modification","volume":"223","author":"Li","year":"2022","journal-title":"Macromol. Chem. Phys."},{"key":"2026073107122969300_cit29","doi-asserted-by":"publisher","first-page":"110564","DOI":"10.1016\/j.eurpolymj.2021.110564","article-title":"Synthesis\nand post-polymerization modification of poly(propargyl 2-ylidene-acetate)","volume":"156","author":"Li","year":"2021","journal-title":"Eur. Polym. J."},{"issue":"21","key":"2026073107122969300_cit30","doi-asserted-by":"publisher","first-page":"5157","DOI":"10.1002\/anie.201200069","article-title":"Stereospecific carbene polymerization\nwith oxygenated Rh(diene) species","volume":"51","author":"Walters","year":"2012","journal-title":"Angew. Chem.,\nInt. Ed."},{"issue":"5","key":"2026073107122969300_cit31","doi-asserted-by":"publisher","first-page":"1094","DOI":"10.1021\/om1011209","article-title":"Role of \u03b2-H Elimination in\nRhodium-Mediated Carbene Insertion Polymerization","volume":"30","author":"Finger","year":"2011","journal-title":"Organometallics"},{"issue":"30","key":"2026073107122969300_cit32","doi-asserted-by":"publisher","first-page":"9746","DOI":"10.1021\/ja058722j","article-title":"Rhodium-Mediated Stereoselective\nPolymerization of \u201cCarbenes\u201d","volume":"128","author":"Hetterscheid","year":"2006","journal-title":"J. Am. Chem. Soc."},{"issue":"22","key":"2026073107122969300_cit33","doi-asserted-by":"publisher","first-page":"8608","DOI":"10.1021\/ma901857s","article-title":"N-Heterocyclic Carbene)Pd\/Borate Initiating Systems for Polymerization\nof Ethyl Diazoacetate","volume":"42","author":"Ihara","year":"2009","journal-title":"Macromolecules"},{"issue":"11","key":"2026073107122969300_cit34","doi-asserted-by":"publisher","first-page":"4928","DOI":"10.1039\/c0cp02101f","article-title":"Surface segregation\nof poly(2-methoxyethyl acrylate) in a mixture with poly(methyl methacrylate)","volume":"13","author":"Hirata","year":"2011","journal-title":"Phys. Chem. Chem. Phys."},{"issue":"26","key":"2026073107122969300_cit35","doi-asserted-by":"publisher","first-page":"17399","DOI":"10.1039\/C5CP01972A","article-title":"Effect of interfacial structure on bioinert properties\nof poly(2-methoxyethyl acrylate)\/poly(methyl methacrylate) blend films\nin water","volume":"17","author":"Hirata","year":"2015","journal-title":"Phys. Chem. Chem. Phys."},{"issue":"41","key":"2026073107122969300_cit36","doi-asserted-by":"publisher","first-page":"46621","DOI":"10.1021\/acsami.0c11416","article-title":"Tough and Three-Dimensional-Printable\nPoly(2-methoxyethyl acrylate)-Silica Composite Elastomer with Antiplatelet\nAdhesion Property","volume":"12","author":"Asai","year":"2020","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"9","key":"2026073107122969300_cit37","doi-asserted-by":"publisher","first-page":"4615","DOI":"10.1021\/acs.macromol.4c03082","article-title":"Control of\nJ-Shaped Stress\u2013Strain\nBehavior of Poly(2-methoxyethyl acrylate) Elastomer, a Biocompatible\nPolymer Composed of Silica Particles, by Silane Coupling Agents","volume":"58","author":"Sakamoto","year":"2025","journal-title":"Macromolecules"},{"issue":"7","key":"2026073107122969300_cit38","doi-asserted-by":"publisher","first-page":"2808","DOI":"10.1021\/acs.langmuir.8b02971","article-title":"Effect of the Molecular Weight of Poly(2-methoxyethyl\nacrylate) on Interfacial Structure and Blood Compatibility","volume":"35","author":"Murakami","year":"2019","journal-title":"Langmuir"},{"key":"2026073107122969300_cit39","doi-asserted-by":"publisher","first-page":"586","DOI":"10.1016\/j.colsurfb.2016.05.057","article-title":"Blood-compatible poly(2-methoxyethyl\nacrylate) for the adhesion and proliferation of endothelial and smooth\nmuscle cells","volume":"145","author":"Sato","year":"2016","journal-title":"Colloids Surf., B"},{"issue":"7","key":"2026073107122969300_cit40","doi-asserted-by":"publisher","first-page":"3750","DOI":"10.1021\/la0625998","article-title":"Time-Resolved\nIn Situ ATR-IR Observations\nof the Process of Sorption of Water into a Poly(2-methoxyethyl acrylate)\nFilm","volume":"23","author":"Morita","year":"2007","journal-title":"Langmuir"},{"issue":"11","key":"2026073107122969300_cit41","doi-asserted-by":"publisher","first-page":"4638","DOI":"10.1021\/ma3002559","article-title":"Dynamics of Water-Induced\nSurface Reorganization in Poly(methyl methacrylate) Films","volume":"45","author":"Horinouchi","year":"2012","journal-title":"Macromolecules"},{"issue":"6","key":"2026073107122969300_cit42","doi-asserted-by":"publisher","first-page":"2718","DOI":"10.1021\/acs.biomac.1c00411","article-title":"Poly(tertiary amide\nacrylate) Copolymers Inspired by Poly(2-oxazoline)s: Their Blood Compatibility\nand Hydration States","volume":"22","author":"Liu","year":"2021","journal-title":"Biomacromolecules"},{"issue":"21","key":"2026073107122969300_cit43","doi-asserted-by":"publisher","first-page":"8892","DOI":"10.1021\/ma101792v","article-title":"Rhodium-Mediated Stereospecific\nCarbene Polymerization: From Homopolymers to Random and Block Copolymers","volume":"43","author":"Jellema","year":"2010","journal-title":"Macromolecules"},{"issue":"12","key":"2026073107122969300_cit44","doi-asserted-by":"publisher","first-page":"2823","DOI":"10.1021\/om100226d","article-title":"Ligand Design in Rh(diene)-Mediated \u201cCarbene\u201d\nPolymerization; Efficient Synthesis of High-Mass, Highly Stereoregular,\nand Fully Functionalized Carbon-Chain Polymers","volume":"29","author":"Jellema","year":"2010","journal-title":"Organometallics"},{"issue":"2","key":"2026073107122969300_cit45","doi-asserted-by":"publisher","first-page":"246","DOI":"10.1021\/cs200607s","article-title":"Rh-Mediated Carbene\nPolymerization: from Multistep Catalyst Activation to Alcohol-Mediated\nChain-Transfer","volume":"2","author":"Walters","year":"2012","journal-title":"ACS Catal."}],"container-title":["ACS Applied Bio Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsabm.5c01687","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/aabmcb\/article-pdf\/8\/11\/10371\/66331803\/acsabm.5c01687.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/aabmcb\/article-pdf\/8\/11\/10371\/66331803\/acsabm.5c01687.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,31]],"date-time":"2026-07-31T11:12:35Z","timestamp":1785496355000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/aabmcb\/article\/8\/11\/10371\/5236841\/Superior-Antithrombogenic-Syndiotactic-Poly"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,10,27]]},"references-count":45,"journal-issue":{"issue":"11","published-online":{"date-parts":[[2025,10,27]]},"published-print":{"date-parts":[[2025,11,17]]}},"URL":"https:\/\/doi.org\/10.1021\/acsabm.5c01687","relation":{},"ISSN":["2576-6422"],"issn-type":[{"value":"2576-6422","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,10,27]]}}}