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Microporous materials, particularly metal\u2013organic frameworks and zeolites, present a path toward precision gas therapy by allowing selective adsorption, protection, and controlled release of therapeutic gases such as oxygen, nitric oxide, carbon monoxide, and hydrogen sulfide. Their permanent porosity, tunable pore size, and active metal centers enable the design of materials that respond to biological or external stimuli with high selectivity. This review highlights how structural and chemical control within microporous materials determines gas-storage and -delivery performance, with emphasis on emerging biomedical applications. The discussion includes recent advances in material synthesis, gas loading mechanisms, and biological evaluation, outlining how microporous materials can overcome current barriers in therapeutic gas administration. Future opportunities are presented for translating these frameworks into safe, efficient, and clinically adaptable systems for precision medical treatment.<\/jats:p>","DOI":"10.1021\/acsabm.6c00435","type":"journal-article","created":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T18:01:27Z","timestamp":1790877687000},"page":"9258-9281","source":"Crossref","is-referenced-by-count":0,"title":["Microporous Materials for Therapeutic Gas Delivery: A Focus on Metal\u2013Organic Frameworks"],"prefix":"10.1021","volume":"9","author":[{"given":"Arvin","family":"Eskandari","sequence":"first","affiliation":[{"name":"University of Glasgow , , ,","place":["Glasgow, U.K., G12 8QQ"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6696-4983","authenticated-orcid":true,"given":"Masoud","family":"Aminzare","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Sherbrooke , , , ,","place":["Sherbrooke, Quebec, Canada, J1K 0A5"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,1]]},"reference":[{"issue":"3","key":"2026101904072459200_cit1","doi-asserted-by":"publisher","first-page":"557","DOI":"10.1039\/C8NH00191J","article-title":"Advances in controlled gas-releasing nanomaterials for therapeutic applications","volume":"4","author":"Manoharan","year":"2019","journal-title":"Nanoscale Horiz."},{"issue":"9","key":"2026101904072459200_cit2","doi-asserted-by":"publisher","first-page":"791","DOI":"10.3390\/antiox9090791","article-title":"Nitric Oxide Nano-Delivery Systems for Cancer Therapeutics: Advances and Challenges","volume":"9","author":"Vong","year":"2020","journal-title":"Antioxidants"},{"issue":"10","key":"2026101904072459200_cit3","doi-asserted-by":"publisher","first-page":"1848","DOI":"10.1161\/01.ATV.0000142364.85911.0e","article-title":"Carbon Monoxide Protects Against Cardiac Ischemia\u2014Reperfusion Injury In Vivo via MAPK and Akt\u2014eNOS Pathways","volume":"24","author":"Fujimoto","year":"2004","journal-title":"Arterioscler., Thromb., Vasc. 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