{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T05:19:22Z","timestamp":1788412762067,"version":"build-2803163510"},"reference-count":45,"publisher":"American Chemical Society (ACS)","issue":"26","license":[{"start":{"date-parts":[[2020,6,16]],"date-time":"2020-06-16T00:00:00Z","timestamp":1592265600000},"content-version":"vor","delay-in-days":18,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_ccby_termsofuse.html"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2020,7,1]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Electrodeposition of metals is relevant to much of materials research including catalysis, batteries, antifouling, and anticorrosion coatings. The sacrificial characteristics of zinc used as a protection for ferrous substrates is a central corrosion protection strategy used in automotive, aviation, and DIY industries. Zinc layers are often used for protection by application to a base metal in a hot dip galvanizing step; however, there is a significant interest in less energy and material intense electroplating strategies for zinc. At present, large-scale electroplating is mostly done from acidic zinc solutions, which contain potentially toxic and harmful additives. Alkaline electroplating of zinc offers a route to using environment-friendly green additives. Within the scope of this study an electrolyte containing soluble zinc hydroxide compound and a polyquarternium polymer as additive were studied during zinc deposition on gold model surfaces. Cyclic voltammetry experiments and in-situ electrochemical quartz crystal microbalance with dissipation (QCM-D) measurements were combined to provide a detailed understanding of fundamental steps that occur during polymer-mediated alkaline zinc electroplating. Data indicate that a zincate-loaded polymer can adsorb within the inner sphere of the electric double layer, which lowers the electrostatic penalty of the zincate approach to a negatively charged surface. X-ray photoelectron spectroscopy also supports the assertion that the zincate-loaded polymer is brought tightly to the surface. We also find an initial polymer depletion followed by an active deposition moderation via control of the zincate diffusion through the adsorbed polymer.<\/jats:p>","DOI":"10.1021\/acsami.0c04263","type":"journal-article","created":{"date-parts":[[2020,5,29]],"date-time":"2020-05-29T15:25:06Z","timestamp":1590765906000},"page":"29928-29936","source":"Crossref","is-referenced-by-count":6,"title":["Adsorption\nand Diffusion Moderated by Polycationic\nPolymers during Electrodeposition\nof Zinc"],"prefix":"10.1021","volume":"12","author":[{"given":"Gastelle F.","family":"Tie\u0301tcha","sequence":"first","affiliation":[{"name":"Vienna University of Technology , , Wiedner Hauptstrasse 8-10 , ,","place":["Vienna, Austria, A-1040"]},{"name":"Do\u0308rken MKS-Systeme GmbH & Co. KG , Wetterstra\u00dfe 58 , ,","place":["Herdecke, Germany, D-58313"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7558-9399","authenticated-orcid":true,"given":"Laura L. E.","family":"Mears","sequence":"additional","affiliation":[{"name":"Vienna University of Technology , , Wiedner Hauptstrasse 8-10 , ,","place":["Vienna, Austria, A-1040"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dominik","family":"Dworschak","sequence":"additional","affiliation":[{"name":"Vienna University of Technology , , Wiedner Hauptstrasse 8-10 , ,","place":["Vienna, Austria, A-1040"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marcel","family":"Roth","sequence":"additional","affiliation":[{"name":"Do\u0308rken MKS-Systeme GmbH & Co. KG , Wetterstra\u00dfe 58 , ,","place":["Herdecke, Germany, D-58313"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ingo","family":"Klu\u0308ppel","sequence":"additional","affiliation":[{"name":"Do\u0308rken MKS-Systeme GmbH & Co. KG , Wetterstra\u00dfe 58 , ,","place":["Herdecke, Germany, D-58313"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5410-1067","authenticated-orcid":true,"given":"Markus","family":"Valtiner","sequence":"additional","affiliation":[{"name":"Vienna University of Technology , , Wiedner Hauptstrasse 8-10 , ,","place":["Vienna, Austria, A-1040"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,5,29]]},"reference":[{"key":"2026090301065266200_cit1","doi-asserted-by":"publisher","first-page":"24","DOI":"10.9790\/5736-0632432","article-title":"Investigation of the Anodic Dissolution of Zinc in\nSodium Chloride Electrolyte \u2013 a Green Process","volume":"6","author":"Ismail","year":"2013","journal-title":"IOSR J. Appl. 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Acta"},{"issue":"8","key":"2026090301065266200_cit4","first-page":"17","article-title":"A Study\nof Process Parameters for Zinc Electrodeposition from a Sulphate Bath","volume":"2","author":"Tuaweri","year":"2013","journal-title":"IJESI"},{"issue":"24","key":"2026090301065266200_cit5","doi-asserted-by":"publisher","first-page":"5817","DOI":"10.1016\/j.surfcoat.2008.05.058","article-title":"Effect of Electrodeposition Conditions on the Composition,\nMicrostructure, and Corrosion Resistance of Zn\u2013Ni Alloy Coatings","volume":"202","author":"Byk","year":"2008","journal-title":"Surf. Coat. Technol."},{"issue":"2","key":"2026090301065266200_cit6","doi-asserted-by":"publisher","first-page":"164","DOI":"10.1016\/S0257-8972(99)00455-7","article-title":"Corrosion Behaviour of Zinc\u2013Nickel\nCoatings, Electrodeposited on Steel","volume":"123","author":"Gavrila","year":"2000","journal-title":"Surf. 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Electrochem."},{"issue":"3","key":"2026090301065266200_cit28","doi-asserted-by":"publisher","first-page":"315","DOI":"10.1007\/s10800-005-9076-9","article-title":"Role of Additives\nin Bright Zinc Deposition from Cyanide Free Alkaline Baths","volume":"36","author":"Pushpavanam","year":"2006","journal-title":"J. Appl. Electrochem."},{"key":"2026090301065266200_cit29","doi-asserted-by":"publisher","first-page":"67","DOI":"10.1007\/s10800-014-0777-9","article-title":"Electrodeposition of\nZinc in the Presence of Quaternary Ammonium Compounds from Alkaline\nChloride Bath","volume":"45","author":"Ortiz-Aparicio","year":"2015","journal-title":"J. Appl. Electrochem."},{"issue":"12","key":"2026090301065266200_cit30","doi-asserted-by":"publisher","first-page":"1649","DOI":"10.1149\/1.2404065","article-title":"The Inhibition\nof the Dendritic Electrocrystallization of Zinc from Doped Alkaline\nZincate Solutions","volume":"119","author":"Diggle","year":"1972","journal-title":"J. Electrochem. 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Chem."},{"issue":"9","key":"2026090301065266200_cit34","doi-asserted-by":"publisher","first-page":"642","DOI":"10.1002\/(SICI)1096-9918(199808)26:9&lt;642::AID-SIA408&gt;3.0.CO;2-3","article-title":"Xps: Binding\nEnergy Calibration of Electron Spectrometers 5?Re-Evaluation of the\nReference Energies","volume":"26","author":"Seah","year":"1998","journal-title":"Surf. Interface Anal."},{"issue":"37","key":"2026090301065266200_cit35","doi-asserted-by":"publisher","first-page":"11467","DOI":"10.1039\/c004532b","article-title":"Optical and Electronic\nProperties of Native Zinc Oxide Films on Polycrystalline Zn","volume":"12","author":"Zuo","year":"2010","journal-title":"Phys. Chem. Chem. 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