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Here, a flexible, stretchable, and superhydrophobic\/superoleophilic nanofiber composite membrane with excellent photothermal conversion performance is fabricated by decorating carbon nanofibers (CNFs) with a hollow structure onto the polyurethane nanofibers and subsequent polydimethylsiloxane (PDMS) modification. The combination of CNFs and PDMS greatly improves the membrane\u2019s tensile strength and Young\u2019s modulus without sacrificing its stretchability. The dual polymer nanofiber and CNF network are beneficial to the chemical vapor or liquid diffusion into the membrane and thus can be used for high-performance chemical vapor sensing and oil\/water separation. The nanofiber composite is responsive to different organic vapors with a low detection limit and good selectivity. Also, the material can achieve fast oil\/water separation with the oil (dichloromethane) permeate flux as high as 6577.3 L m\u20132 h\u20131. In addition, the separation flux and efficiency remain stable during the 30 separated oil\/water separation tests, exhibiting excellent recyclability.<\/jats:p>","DOI":"10.1021\/acsami.0c15110","type":"journal-article","created":{"date-parts":[[2020,9,29]],"date-time":"2020-09-29T19:46:57Z","timestamp":1601408817000},"page":"47076-47089","source":"Crossref","is-referenced-by-count":73,"title":["Flexible\nand Superhydrophobic Composites with Dual\nPolymer Nanofiber and Carbon Nanofiber Network for High-Performance\nChemical Vapor Sensing and Oil\/Water Separation"],"prefix":"10.1021","volume":"12","author":[{"given":"Shu","family":"Zhang","sequence":"first","affiliation":[{"name":"Yangzhou University , , , ,","place":["Yangzhou, Jiangsu, China, 225002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuewu","family":"Huang","sequence":"additional","affiliation":[{"name":"Yangzhou University , , , ,","place":["Yangzhou, Jiangsu, China, 225002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong","family":"Wang","sequence":"additional","affiliation":[{"name":"Yangzhou University , , , ,","place":["Yangzhou, Jiangsu, China, 225002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wei","family":"Xiao","sequence":"additional","affiliation":[{"name":"Yangzhou University , , , ,","place":["Yangzhou, Jiangsu, China, 225002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liyao","family":"Huo","sequence":"additional","affiliation":[{"name":"Yangzhou University , , , ,","place":["Yangzhou, Jiangsu, China, 225002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Zhao","sequence":"additional","affiliation":[{"name":"Yangzhou University , , , ,","place":["Yangzhou, Jiangsu, China, 225002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ling","family":"Wang","sequence":"additional","affiliation":[{"name":"Yangzhou University , , , ,","place":["Yangzhou, Jiangsu, China, 225002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6038-9770","authenticated-orcid":true,"given":"Jiefeng","family":"Gao","sequence":"additional","affiliation":[{"name":"Yangzhou University , , , ,","place":["Yangzhou, Jiangsu, China, 225002"]},{"name":"Sichuan University , , , ,","place":["Chengdu, Sichuan, P. R. China, 610065"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,9,29]]},"reference":[{"key":"2026081714134009500_cit1","doi-asserted-by":"publisher","first-page":"849","DOI":"10.1016\/j.jhazmat.2017.11.040","article-title":"Superhydrophobic and\nSuperoleophilic Porous Reduced\nGraphene Oxide\/Polycarbonate Monoliths for High-Efficiency Oil\/Water\nSeparation","volume":"344","author":"Wang","year":"2018","journal-title":"J. Hazard. Mater."},{"key":"2026081714134009500_cit2","doi-asserted-by":"publisher","first-page":"2154","DOI":"10.1016\/j.cej.2017.11.054","article-title":"Facile Synthesis\nof Super-hydrophobic, Electrically\nConductive and Mechanically Flexible Functionalized Graphene Nanoribbon\/Polyurethane\nSponge for Efficient Oil\/Water Separation at Static and Dynamic States","volume":"334","author":"Qiang","year":"2018","journal-title":"Chem. Eng. 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Technol."},{"key":"2026081714134009500_cit32","doi-asserted-by":"publisher","first-page":"243","DOI":"10.1016\/j.jiec.2018.10.021","article-title":"Stretchable, Electrically Conductive and Superhydrophobic\/Superoleophilic\nNanofibrous Membrane with a Hierarchical Structure for Efficient Oil\/Water\nSeparation","volume":"70","author":"Huang","year":"2019","journal-title":"J. Ind. Eng. Chem."},{"key":"2026081714134009500_cit33","doi-asserted-by":"publisher","first-page":"14","DOI":"10.1016\/j.seppur.2018.05.035","article-title":"Self-Roughened\nOmniphobic Coatings on Nanofibrous Membrane\nfor Membrane Distillation","volume":"206","author":"Deng","year":"2018","journal-title":"Sep. Purif. 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