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In this work, lead-free double perovskite Cs2AgBiBr6 memristors were fabricated on ITO\/glass substrates with thermally evaporated Ag top electrodes and systematically investigated for their resistive switching (RS) and neuromorphic functionalities. The devices exhibit stable, low-voltage (+0.239 \u00b1 0.018 V) volatile resistive switching with good cycle-to-cycle reproducibility. A maximum ON\/OFF ratio exceeding 105 is maintained for 24 cycles, while values above 102 persist for 1100 cycles. Electrical analysis reveals that the switching behavior is governed by ion migration-induced filament formation, primarily involving mobile Br\u2013 ions, VBr+ vacancies, and Ag+ ions injected from the electrode. A detailed conduction model is proposed based on space charge-limited conduction and ion-induced electric field screening. Furthermore, the volatile RS characteristics enable biologically inspired synaptic functions, including spike amplitude-dependent plasticity (SADP), spike number-dependent plasticity (SNDP), and paired-pulse facilitation (PPF) with a maximum facilitation index of 169%, benchmarking competitively among perovskite memristive synapses. Based on experimentally extracted synaptic weight-update rules, an artificial neural network simulation achieved a peak recognition accuracy of 98%.<\/jats:p>","DOI":"10.1021\/acsami.6c03660","type":"journal-article","created":{"date-parts":[[2026,7,19]],"date-time":"2026-07-19T17:52:24Z","timestamp":1784483544000},"page":"39812-39822","source":"Crossref","is-referenced-by-count":3,"title":["Low-Voltage Resistive\nSwitching and Synaptic Plasticity\nin Cs2AgBiBr6 Memristors"],"prefix":"10.1021","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0009-0002-7656-4825","authenticated-orcid":true,"given":"Zhuang","family":"Miao","sequence":"first","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ahmed","family":"Kadid","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-2756-7500","authenticated-orcid":true,"given":"Alexander","family":"Lo\u0308wen","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Naveen","family":"Kolluru","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2249-8914","authenticated-orcid":true,"given":"Christian","family":"Tu\u0308ckmantel","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Timo","family":"Maschwitz","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cedric","family":"Kreusel","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jamal","family":"Aziz","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefan","family":"Janicke","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Boqi","family":"Wu","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9666-1422","authenticated-orcid":true,"given":"Pang","family":"Wang","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1084-316X","authenticated-orcid":true,"given":"Thomas","family":"Riedl","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel","family":"Neumaier","sequence":"additional","affiliation":[{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"University of Wuppertal , , ,","place":["Wuppertal, Germany, 42119"]},{"name":"AMO GmbH , , ,","place":["Aachen, Germany, 52074"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,19]]},"reference":[{"key":"2026072908061132700_cit1","unstructured":"Kaplan, J.; McCandlish, S.; Henighan, T.; Brown, T. 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