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In this work, a multifunctional CeOx\/TiO2@MXene-reinforced epoxy coating was developed to integrate UV attenuation, radical-chain suppression, and barrier protection for enhanced corrosion resistance. A silane-functionalized CeOx\/TiO2@MXene (SCTM) nanofiller was fabricated through controlled hydrothermal oxidation of MXene, followed by CeOx deposition and silane grafting. The partial oxidation of MXene generated a TiO2-passivated structure while retaining the two-dimensional layered framework, thereby improving the environmental stability of the MXene-derived nanofiller. Meanwhile, low-valence Ti species on the TiO2@MXene surface promoted the formation of Ce3+-rich CeOx nanoparticles with abundant oxygen-vacancy-related surface states, providing active sites for Ce3+\/Ce4+ redox cycling and radical scavenging. The CeOx\/TiO2@MXene nanocomposite displayed broadened optical absorption and enhanced UV attenuation behavior. After 100 h of xenon-lamp aging, the SCTM\/EP composite coating maintained superior mechanical integrity and corrosion resistance. Electrochemical impedance spectroscopy (EIS) results revealed that, after UV aging followed by 100 d of immersion in 3.5 wt % NaCl solution, SCTM\/EP maintained an impedance modulus (|Z|0.01 Hz) of 6.58 \u00d7 109 \u03a9\u00b7cm2, representing a two-order-of-magnitude improvement over pure epoxy (8.09 \u00d7 107 \u03a9\u00b7cm2). The enhanced durability is attributed to the integrated effects of UV attenuation, Ce3+\/Ce4+-mediated radical scavenging, and retention of coating barrier properties, which collectively suppress UV-induced photo-oxidative degradation and delay the ingress of corrosive species. This study provides an effective strategy for enhancing the UV-aging and corrosion protection resistance of epoxy coatings through multifunctional MXene-derived nanocomposites.<\/jats:p>","DOI":"10.1021\/acsami.6c06471","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T13:21:14Z","timestamp":1785849674000},"page":"43017-43033","source":"Crossref","is-referenced-by-count":0,"title":["Multifunctional UV Attenuation and Radical-Chain Suppression in CeO\n                    <i>x<\/i>\n                    \/TiO2@MXene\u2013Epoxy Coatings Toward Durable Corrosion Resistance"],"prefix":"10.1021","volume":"18","author":[{"given":"Yinzheng","family":"Xia","sequence":"first","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiyang","family":"Hong","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peihu","family":"Shen","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9505-4009","authenticated-orcid":true,"given":"Yue","family":"Li","sequence":"additional","affiliation":[{"name":"ZJU-Hangzhou Global Scientific and Technological Innovation Center , ,","place":["Hangzhou, China, 311200"]},{"name":"Institute of Wenzhou, Zhejiang University , ,","place":["Wenzhou, China, 325006"]},{"name":"Zhejiang California International Nanosystems Institute, Zhejiang University , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ji","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute of Wenzhou, Zhejiang University , ,","place":["Wenzhou, China, 325006"]},{"name":"Zhejiang California International Nanosystems Institute, Zhejiang University , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qianhong","family":"Shen","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"ZJU-Hangzhou Global Scientific and Technological Innovation Center , ,","place":["Hangzhou, China, 311200"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui","family":"Yang","sequence":"additional","affiliation":[{"name":"Zhejiang University , , ,","place":["Hangzhou, China, 310058"]},{"name":"ZJU-Hangzhou Global Scientific and Technological Innovation Center , ,","place":["Hangzhou, China, 311200"]},{"name":"Institute of Wenzhou, Zhejiang University , ,","place":["Wenzhou, China, 325006"]},{"name":"Zhejiang California International Nanosystems Institute, Zhejiang University , ,","place":["Hangzhou, China, 310058"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,30]]},"reference":[{"key":"2026081917071715700_cit1","doi-asserted-by":"publisher","DOI":"10.1016\/j.compscitech.2021.109090","article-title":"Designing strong interfacial adhesion between carbon fiber and epoxy resin via dopamine towards excellent protection ability under high hydrostatic pressure and severe erosion corrosion condition","volume":"217","author":"Zhao","year":"2022","journal-title":"Compos. 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