{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T10:52:48Z","timestamp":1791975168995,"version":"4.4.0"},"reference-count":69,"publisher":"American Chemical Society (ACS)","issue":"40","license":[{"start":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T00:00:00Z","timestamp":1790899200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T00:00:00Z","timestamp":1790899200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T00:00:00Z","timestamp":1790899200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100003704","name":"Korea Research Institute of Chemical Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100003704","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001409","name":"Department of Science and Technology, Ministry of Science and Technology, India","doi-asserted-by":"publisher","award":["IF220469"],"award-info":[{"award-number":["IF220469"]}],"id":[{"id":"10.13039\/501100001409","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Madan Mohan Malaviya University of Technology, Gorakhpur","id":[{"id":"https:\/\/ror.org\/04h1w2j35","id-type":"ROR","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,14]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Integrating heterogeneous photocatalysis with enzymatic redox transformations remains challenging due to inefficient cofactor regeneration and limited charge transport across hybrid interfaces. Herein, we report a sulfur-mediated covalent triazine framework (S\/M-CTF) assembled by the cyclotrimerization of a 1,4,5,8-naphthalene tetracarboxylic dianhydride (NTDA)-derived monomer and in situ cyclotrimerization onto tridoped graphene sheets (G) enriched with boron, selenium, and nitrogen, fabricating a hybrid architecture (S\/M-CTFs@G) with enhanced charge carrier transport and heterogeneous electronic structure. Spatial encapsulation and covalent anchoring afford efficient photoinduced 1,4-NADH regeneration (91.31 \u00b1 0.17%, TON = 14.38, TOF = 14.38 h\u20131, AQY = 4.27% with a rate of 1835.8 \u03bcmol g\u20131h\u20131) and selective methanol production (26.84 \u00b1 0.75 \u03bcM, TON = 4.22, TOF = 4.22 h\u20131, STMe = 0.0054% with a rate of 536.77 \u03bcmol g\u20131h\u20131) driven by Saccharomyces cerevisiae-derived alcohol dehydrogenase (ADH), facilitating enzymatic reduction under mild conditions. Beyond cofactor cycling and enzymatic reduction, the confined system also supports the synthesis of sulfur-containing heterocycles, namely a pharmaceutically relevant oxathiolane scaffolds (98.40 \u00b1 0.02%, TON = 49.0, TOF = 6.12 h\u20131). Collectively, these results establish tridoped graphene-supported, sulfur confined CTFs as a versatile platform for the synergistic photobiocatalytic upgrading of C1 feedstocks.<\/jats:p>","DOI":"10.1021\/acsami.6c06987","type":"journal-article","created":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T23:01:43Z","timestamp":1790982103000},"page":"54734-54751","source":"Crossref","is-referenced-by-count":0,"title":["Dual Covalent and Spatial Sulfur Confinement in NTDA-Derived Graphene Frameworks for Photo\/Biocatalytic Methanol Production and Oxathiolane Synthesis"],"prefix":"10.1021","volume":"18","author":[{"given":"Shaifali","family":"Mishra","sequence":"first","affiliation":[{"name":"Madan Mohan Malaviya University of Technology , , , ,","place":["Gorakhpur, Uttar Pradesh, India, 273010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5320-5259","authenticated-orcid":true,"given":"Rajesh K.","family":"Yadav","sequence":"additional","affiliation":[{"name":"Madan Mohan Malaviya University of Technology , , , ,","place":["Gorakhpur, Uttar Pradesh, India, 273010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kanchan","family":"Sharma","sequence":"additional","affiliation":[{"name":"Madan Mohan Malaviya University of Technology , , , ,","place":["Gorakhpur, Uttar Pradesh, India, 273010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Surendra K.","family":"Jaiswal","sequence":"additional","affiliation":[{"name":"Madan Mohan Malaviya University of Technology , , , ,","place":["Gorakhpur, Uttar Pradesh, India, 273010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rehana","family":"Shahin","sequence":"additional","affiliation":[{"name":"Starex University , , ,","place":["Gurugram, India, 122413"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Geeta","family":"Srivastava","sequence":"additional","affiliation":[{"name":"Madan Mohan Malaviya University of Technology , , , ,","place":["Gorakhpur, Uttar Pradesh, India, 273010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Anupma","family":"Yadav","sequence":"additional","affiliation":[{"name":"Madan Mohan Malaviya University of Technology , , , ,","place":["Gorakhpur, Uttar Pradesh, India, 273010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"family":"Mohit","sequence":"additional","affiliation":[{"name":"University of Delhi (North Campus) , , ,","place":["Delhi, India, 110007"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kamlesh","family":"Kumar","sequence":"additional","affiliation":[{"name":"Kirori Mal College, University of Delhi , , ,","place":["Delhi, India, 110007"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0074-4758","authenticated-orcid":true,"given":"Jin Ook","family":"Baeg","sequence":"additional","affiliation":[{"name":"Korea Research Institute of Chemical Technology , ,","place":["Daejeon, South Korea, 34114"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,2]]},"reference":[{"issue":"1","key":"2026101406080814200_cit1","doi-asserted-by":"publisher","first-page":"4479","DOI":"10.1038\/s41467-026-70789-2","article-title":"Ethanol Photosynthesis from CO2 and H2O via a Formate Intermediate Pathway","volume":"17","author":"Liu","year":"2026","journal-title":"Nat. Commun."},{"issue":"23","key":"2026101406080814200_cit2","doi-asserted-by":"publisher","first-page":"11540","DOI":"10.1039\/d4gc03745f","article-title":"Formaldehyde Dehydrogenase SzFaldDH: An Indispensable Bridge for Relaying CO2 Bioactivation and Conversion","volume":"26","author":"Guo","year":"2024","journal-title":"Green Chem."},{"issue":"20","key":"2026101406080814200_cit3","doi-asserted-by":"publisher","first-page":"2983","DOI":"10.1039\/d5qm00594a","article-title":"Advances in Catalyst and Reactor Design for CO2 Electroreduction to Methanol","volume":"9","author":"Chen","year":"2025","journal-title":"Mater. Chem. Front."},{"issue":"9","key":"2026101406080814200_cit4","doi-asserted-by":"publisher","first-page":"2715","DOI":"10.1021\/acssynbio.3c00273","article-title":"Light-Driven CO2 Reduction with a Surface-Displayed Enzyme Cascade--C3N4 Hybrid","volume":"12","author":"Sheng","year":"2023","journal-title":"ACS Synth. Biol."},{"issue":"9","key":"2026101406080814200_cit5","doi-asserted-by":"publisher","first-page":"4967","DOI":"10.1021\/acscatal.0c00471","article-title":"Unraveling and Manipulating of NADH Oxidation by Photogenerated Holes","volume":"10","author":"Zhang","year":"2020","journal-title":"ACS Catal."},{"issue":"4","key":"2026101406080814200_cit6","doi-asserted-by":"publisher","first-page":"720","DOI":"10.1039\/c9nh00663j","article-title":"Rational Integration of Spatial Confinement and Polysulfide Conversion Catalysts for High Sulfur Loading Lithium--Sulfur Batteries","volume":"5","author":"Zhang","year":"2020","journal-title":"Nanoscale Horiz."},{"key":"2026101406080814200_cit7","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2022.140156","article-title":"A COF-Coated MOF Framework Polysulfide Barrier Design for Enhanced Performance in Lithium-Sulfur Batteries","volume":"412","author":"Lin","year":"2022","journal-title":"Electrochim. Acta"},{"key":"2026101406080814200_cit8","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2022.135823","article-title":"COFs-Confined Multifunctional Sulfur-Host Design towards High-Performance Lithium-Sulfur Batteries","volume":"442","author":"Du","year":"2022","journal-title":"Chem. Eng. J."},{"issue":"33","key":"2026101406080814200_cit9","doi-asserted-by":"publisher","DOI":"10.1002\/adma.201902228","article-title":"Self-Supported and Flexible Sulfur Cathode Enabled via Synergistic Confinement for High-Energy-Density Lithium\u2013Sulfur Batteries","volume":"31","author":"Wang","year":"2019","journal-title":"Adv. Mater."},{"issue":"8","key":"2026101406080814200_cit10","doi-asserted-by":"publisher","first-page":"4045","DOI":"10.1021\/acsenergylett.5c01365","article-title":"Photoassisted Rechargeable Lithium-Based Batteries: Progress, Challenges, and Perspectives","volume":"10","author":"Xu","year":"2025","journal-title":"ACS Energy Lett."},{"issue":"1","key":"2026101406080814200_cit11","doi-asserted-by":"publisher","first-page":"7278","DOI":"10.1038\/ncomms8278","article-title":"Synthesis of Three-Dimensionally Interconnected Sulfur-Rich Polymers for Cathode Materials of High-Rate Lithium--Sulfur Batteries","volume":"6","author":"Kim","year":"2015","journal-title":"Nat. Commun."},{"issue":"11","key":"2026101406080814200_cit12","doi-asserted-by":"publisher","first-page":"3507","DOI":"10.1021\/acssynbio.4c00454","article-title":"Formaldehyde: An Essential Intermediate for C1 Metabolism and Bioconversion","volume":"13","author":"Jia","year":"2024","journal-title":"ACS Synth. Biol."},{"issue":"12","key":"2026101406080814200_cit13","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202422882","article-title":"Hybrid Enzyme-Electrocatalyst Cascade Modified Gas-Diffusion Electrodes for Methanol Formation from Carbon Dioxide","volume":"64","author":"Wang","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"issue":"41","key":"2026101406080814200_cit14","doi-asserted-by":"publisher","first-page":"19551","DOI":"10.1021\/acs.energyfuels.5c03443","article-title":"A Review on Graphene-Based Catalysts for Biodiesel Production","volume":"39","author":"Dong","year":"2025","journal-title":"Energy Fuels"},{"issue":"7","key":"2026101406080814200_cit15","doi-asserted-by":"publisher","first-page":"2779","DOI":"10.1039\/d5su00174a","article-title":"Graphene-Based Catalysts for Electrochemical CO2 Reduction Reaction","volume":"3","author":"Wijewardena","year":"2025","journal-title":"RSC Sustainability"},{"issue":"15","key":"2026101406080814200_cit16","doi-asserted-by":"publisher","first-page":"4240","DOI":"10.1039\/C6GC00924G","article-title":"Eosin Y Catalyzed Difunctionalization of Styrenes Using O2 and CS 2: A Direct Access to 1, 3-Oxathiolane-2-Thiones","volume":"18","author":"Yadav","year":"2016","journal-title":"Green Chem."},{"issue":"7","key":"2026101406080814200_cit17","doi-asserted-by":"publisher","first-page":"4174","DOI":"10.1021\/nn1007429","article-title":"Graphene Nanomesh by ZnO Nanorod Photocatalysts","volume":"4","author":"Akhavan","year":"2010","journal-title":"ACS Nano"},{"issue":"30","key":"2026101406080814200_cit18","doi-asserted-by":"publisher","first-page":"12955","DOI":"10.1021\/jp103472c","article-title":"Photodegradation of Graphene Oxide Sheets by TiO2 Nanoparticles after a Photocatalytic Reduction","volume":"114","author":"Akhavan","year":"2010","journal-title":"J. Phys. Chem. C"},{"issue":"3","key":"2026101406080814200_cit19","doi-asserted-by":"publisher","first-page":"3713","DOI":"10.1021\/acsami.2c15431","article-title":"Controlled Differentiation of Human Neural Progenitor Cells on Molybdenum Disulfide\/Graphene Oxide Heterojunction Scaffolds by Photostimulation","volume":"15","author":"Saadati","year":"2023","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"14","key":"2026101406080814200_cit20","doi-asserted-by":"publisher","first-page":"11622","DOI":"10.1021\/acs.jmedchem.4c01122","article-title":"An Update on the Nitrogen Heterocycle Compositions and Properties of U.S FDA-Approved Pharmaceuticals (2013\u20132023)","volume":"67","author":"Marshall","year":"2013","journal-title":"J. Med. Chem."},{"issue":"1","key":"2026101406080814200_cit21","doi-asserted-by":"publisher","first-page":"19468","DOI":"10.1038\/s41598-024-70239-3","article-title":"Biocatalytic Synthesis of Oxa (Thia) Diazole Aryl Thioethers","volume":"14","author":"Mottaghi Amlashi","year":"2024","journal-title":"Sci. Rep."},{"issue":"8","key":"2026101406080814200_cit22","doi-asserted-by":"publisher","first-page":"2988","DOI":"10.1021\/acs.oprd.4c00186","article-title":"Oxygen-, Nitrogen-, and Sulfur-Containing Heterocycles: Recent Advances in De Novo Synthesis and Prospect","volume":"28","author":"Zheng","year":"2024","journal-title":"Org. Process Res. Dev."},{"issue":"1","key":"2026101406080814200_cit23","doi-asserted-by":"publisher","first-page":"513","DOI":"10.1002\/med.21852","article-title":"Expedition of Sulfur-Containing Heterocyclic Derivatives as Cytotoxic Agents in Medicinal Chemistry: A Decade Update","volume":"42","author":"Laxmikeshav","year":"2022","journal-title":"Med. Res. Rev."},{"issue":"15","key":"2026101406080814200_cit24","doi-asserted-by":"publisher","first-page":"8057","DOI":"10.1021\/ic300185n","article-title":"Photochemical Production of NADH Using Cobaloxime Catalysts and Visible-Light Energy","volume":"51","author":"Kim","year":"2012","journal-title":"Inorg. Chem."},{"issue":"7","key":"2026101406080814200_cit25","doi-asserted-by":"publisher","first-page":"8296","DOI":"10.1021\/acsami.9b21481","article-title":"Synergetic Covalent and Spatial Confinement of Sulfur Species by Phthalazinone-Containing Covalent Triazine Frameworks for Ultrahigh Performance of Li--S Batteries","volume":"12","author":"Guan","year":"2020","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"2026101406080814200_cit26","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2025.114873","article-title":"Multiplexed Dopant-Enhanced Graphene for CO2 Conversion Using Rhodium Complex: Revealing Formic Acid Synthesis and Organic Transformations for Sustainable Catalysis","author":"Mishra","year":"2025","journal-title":"Inorg. Chem. Commun."},{"issue":"4","key":"2026101406080814200_cit27","doi-asserted-by":"publisher","first-page":"1661","DOI":"10.1021\/acsaenm.5c01210","article-title":"Flower-Inspired Chrysanthemum-Structured Photocatalyst Enabling Visible-Light-Driven CO2 Reduction to Formic Acid and the Synthesis of Pyrano-Fused Benzophenazines","volume":"4","author":"Srivastava","year":"2026","journal-title":"ACS Appl. Eng. Mater."},{"issue":"41","key":"2026101406080814200_cit28","doi-asserted-by":"publisher","first-page":"46673","DOI":"10.1021\/acsami.2c13631","article-title":"Fine-Tuning the Electrocatalytic Regeneration of NADH Cofactor Using [Rh(Cp*)(Bpy)Cl] + -Functionalized Metal\u2013Organic Framework Films","volume":"14","author":"Li","year":"2022","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"39","key":"2026101406080814200_cit29","doi-asserted-by":"publisher","first-page":"10514","DOI":"10.1002\/slct.202102221","article-title":"NADH Regeneration Promoted by Solar Light Using Gold Nanoparticles\/Layered Double Hydroxides as Novel Photocatalytic Nanoplatforms","volume":"6","author":"Grosu","year":"2021","journal-title":"ChemistrySelect"},{"issue":"10","key":"2026101406080814200_cit30","doi-asserted-by":"publisher","first-page":"2581","DOI":"10.1039\/d2se00454b","article-title":"Visible-Light-Induced Enzymatic Reactions Using an NADH Regeneration System of Water-Soluble Zinc Porphyrin and Homogeneous Colloidal Rhodium Nanoparticles","volume":"6","author":"Katagiri","year":"2022","journal-title":"Sustainable Energy Fuels"},{"issue":"6","key":"2026101406080814200_cit31","doi-asserted-by":"publisher","first-page":"064703","DOI":"10.1063\/5.0016459","article-title":"Photoelectrochemical NADH Regeneration Is Highly Sensitive to the Nature of Electrode Surface","volume":"153","author":"Zhang","year":"2020","journal-title":"J. Chem. Phys."},{"issue":"10","key":"2026101406080814200_cit32","doi-asserted-by":"publisher","first-page":"4078","DOI":"10.1021\/acssuschemeng.4c10134","article-title":"Rh-Functionalized Imino-Pyridine Covalent Organic Framework Assembled on Ti3C2Tx (MXene) for Efficient NADH Regeneration and Photoenzymatic CO2 Reduction","volume":"13","author":"Zheng","year":"2025","journal-title":"ACS Sustainable Chem. Eng."},{"key":"2026101406080814200_cit33","doi-asserted-by":"publisher","first-page":"149","DOI":"10.1016\/j.jphotochem.2015.06.026","article-title":"Effect of Chemical Structure of Bipyridinium Salts as Electron Carrier on the Visible-Light Induced Conversion of CO2 to Formic Acid with the System Consisting of Water-Soluble Zinc Porphyrin and Formate Dehydrogenase","volume":"313","author":"Amao","year":"2015","journal-title":"J. Photochem. Photobiol. A Chem."},{"key":"2026101406080814200_cit34","doi-asserted-by":"publisher","first-page":"11403","DOI":"10.1021\/jacs.6c02157","article-title":"Built-in Electric Field in Multivariate COFs Boosts Photocatalytic NADH Regeneration for Enzymatic Reduction","author":"Zuo","year":"2026","journal-title":"J. Am. Chem. Soc."},{"issue":"37","key":"2026101406080814200_cit35","doi-asserted-by":"publisher","DOI":"10.1002\/slct.202400732","article-title":"Synthesis of a TBA-Based Polymeric Photocatalyst for Boosting the Selective Bio-Reduction of Furfural Under Solar Light Illumination","volume":"9","author":"Singh","year":"2024","journal-title":"ChemistrySelect"},{"issue":"July","key":"2026101406080814200_cit36","doi-asserted-by":"publisher","DOI":"10.1016\/j.diamond.2025.112604","article-title":"Rational Design and Mechanistic Insights of a G@DAA Photocatalyst for CO2-Driven Carboxylation: Sustainable Biomass Valorization and NADH Regeneration in Green Chemistry","volume":"158","author":"Mishra","year":"2025","journal-title":"Diam. Relat. Mater."},{"issue":"5","key":"2026101406080814200_cit37","doi-asserted-by":"publisher","first-page":"1292","DOI":"10.1039\/d5se01252j","article-title":"Solar-Responsive Treble Photocatalytic Action of Sulfur-Bridged-2DRB Framework Composites for Selective 1, 4 NADH Regeneration with Simultaneous Benzyl Alcohol Production and Boronic Acid Conversion","volume":"10","author":"Shahin","year":"2026","journal-title":"Sustainable Energy Fuels"},{"issue":"41","key":"2026101406080814200_cit38","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202504713","article-title":"Metal--Organic Framework and CdS Quantum Dots Coupled Enzyme Catalytic System Enhanced CO2 Reduction and Formate Synthesis","volume":"21","author":"Li","year":"2025","journal-title":"Small"},{"issue":"1","key":"2026101406080814200_cit39","doi-asserted-by":"publisher","first-page":"142","DOI":"10.1039\/d1ma00748c","article-title":"Challenges and Future Prospects of Graphene-Based Hybrids for Solar Fuel Generation: Moving towards next Generation Photocatalysts","volume":"3","author":"Bramhaiah","year":"2022","journal-title":"Mater. Adv."},{"key":"2026101406080814200_cit40","doi-asserted-by":"publisher","DOI":"10.1016\/j.diamond.2024.111140","article-title":"Crafting in Situ Boron and Selenium-Doped Carbon Nitride Nanosheets for Turbocharged Benzaldehyde to Benzyl Alcohol under Solar Spectrum","volume":"146","author":"Gautam","year":"2024","journal-title":"Diam. Relat. Mater."},{"key":"2026101406080814200_cit41","doi-asserted-by":"publisher","first-page":"46650","DOI":"10.1021\/acsami.1c13167","article-title":"Photoenzymatic Catalytic Cascade System of a Pyromellitic Diimide\/g-C3N4 Heterojunction to Efficiently Regenerate NADH for Highly Selective CO2 Reduction toward Formic Acid","volume":"13","author":"Zhang","year":"2021","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"55","key":"2026101406080814200_cit42","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202201430","article-title":"Bioinspired Photocatalytic NADH Regeneration by Covalently Metalated Carbon Nitride for Enhanced CO2 Reduction","volume":"28","author":"Zhang","year":"2022","journal-title":"Chem. \u2013 Eur. J."},{"issue":"8","key":"2026101406080814200_cit43","doi-asserted-by":"publisher","first-page":"1231","DOI":"10.1039\/c9cc07805c","article-title":"A Facile Analytical Method for Reliable Selectivity Examination in Cofactor NADH Regeneration","volume":"56","author":"Saba","year":"2020","journal-title":"Chem. Commun."},{"issue":"1","key":"2026101406080814200_cit44","doi-asserted-by":"publisher","first-page":"37","DOI":"10.1021\/acssuschemeng.3c04115","article-title":"Efficient and Recyclable Photobiocatalytic System via Cofactor Regeneration for Chiral Aryl Alcohol Synthesis","volume":"12","author":"Cai","year":"2023","journal-title":"ACS Sustainable Chem. Eng."},{"issue":"5","key":"2026101406080814200_cit45","doi-asserted-by":"publisher","first-page":"247","DOI":"10.1039\/d2ya00054g","article-title":"Bioelectrocatalytic Methanol Production with Alcohol Dehydrogenase Using Methylviologen as an Electron Mediator","volume":"1","author":"Katagiri","year":"2022","journal-title":"Energy Adv."},{"key":"2026101406080814200_cit46","doi-asserted-by":"publisher","first-page":"11503","DOI":"10.1021\/acssuschemeng.1c03737","article-title":"Development of an Ionic Porphyrin-Based Platform as a Biomimetic Light-Harvesting Agent for High-Performance Photoenzymatic Synthesis of Methanol from CO2","volume":"9","author":"Zhang","year":"2021","journal-title":"ACS Sustainable Chem. Eng."},{"issue":"69","key":"2026101406080814200_cit47","doi-asserted-by":"publisher","first-page":"42354","DOI":"10.1039\/d0ra08594d","article-title":"Visible-Light-Driven CO2 reduction to Formate with a System of Water-Soluble Zinc Porphyrin and Formate Dehydrogenase in Ionic Liquid\/Aqueous Media","volume":"10","author":"Secundo","year":"2020","journal-title":"RSC Adv."},{"issue":"30","key":"2026101406080814200_cit48","doi-asserted-by":"publisher","first-page":"11002","DOI":"10.1021\/acssuschemeng.3c00361","article-title":"Dual-Defect Abundant Graphitic Carbon Nitride for Efficient Photocatalytic Nicotinamide Cofactor Regeneration","volume":"11","author":"Xie","year":"2023","journal-title":"ACS Sustainable Chem. Eng."},{"issue":"11","key":"2026101406080814200_cit49","doi-asserted-by":"publisher","first-page":"3199","DOI":"10.1039\/d1na00115a","article-title":"1, 4, 5, 8-Naphthalenetetracarboxylic Dianhydride Grafted Phthalocyanine Macromolecules as an Anode Material for Lithium Ion Batteries","volume":"3","author":"Tao","year":"2021","journal-title":"Nanoscale Adv."},{"issue":"8","key":"2026101406080814200_cit50","doi-asserted-by":"publisher","DOI":"10.1002\/solr.202000132","article-title":"2D\/2D Heterostructured Photocatalysts: An Emerging Platform for Artificial Photosynthesis","volume":"4","author":"Ong","year":"2020","journal-title":"Sol. Rrl"},{"issue":"11","key":"2026101406080814200_cit51","doi-asserted-by":"publisher","first-page":"11323","DOI":"10.1021\/acsanm.1c01014","article-title":"Review of Hybrid 1D\/2D Photocatalysts for Light-Harvesting Applications","volume":"4","author":"Nawaz","year":"2021","journal-title":"ACS Appl. Nano Mater."},{"issue":"4","key":"2026101406080814200_cit52","doi-asserted-by":"publisher","DOI":"10.3390\/molecules28041735","article-title":"Acid Ethyl Esters\u2014Potential Anticancer Agents","volume":"28","author":"Ostasz","year":"2023","journal-title":"Molecules"},{"issue":"4","key":"2026101406080814200_cit53","doi-asserted-by":"publisher","first-page":"594","DOI":"10.1021\/acs.accounts.5b00471","article-title":"The Development and Application of Two-Chamber Reactors and Carbon Monoxide Precursors for Safe Carbonylation Reactions","volume":"49","author":"Friis","year":"2016","journal-title":"Acc. Chem. Res."},{"issue":"47","key":"2026101406080814200_cit54","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202312095","article-title":"Synthesizing Interpenetrated Triazine-Based Covalent Organic Frameworks from CO2","volume":"62","author":"Zhang","year":"2023","journal-title":"Angew. Chem., Int. Ed."},{"issue":"39","key":"2026101406080814200_cit55","doi-asserted-by":"publisher","first-page":"23024","DOI":"10.1039\/d0ra03421e","article-title":"Real Roles of Perylene Diimides for Improving Photocatalytic Activity","volume":"10","author":"Zhang","year":"2020","journal-title":"RSC Adv."},{"issue":"50","key":"2026101406080814200_cit56","doi-asserted-by":"publisher","first-page":"21418","DOI":"10.1021\/acssuschemeng.5c06912","article-title":"Construction of PEI-Based Sulfur-Containing Polymers Molecular Framework with Enhanced Lithium Diffusion and Long-Term Stability for High-Performance Lithium--Sulfur Batteries","volume":"13","author":"Lu","year":"2025","journal-title":"ACS Sustainable Chem. Eng."},{"key":"2026101406080814200_cit57","article-title":"Preparation and Physical Characterization of Sulfur\/Carbon Black Composite Cathode Material for Li-s Battery","volume":"3","author":"Rajkumar","year":"2017","journal-title":"Int. Res. J. Eng. Technol."},{"issue":"15","key":"2026101406080814200_cit58","doi-asserted-by":"publisher","DOI":"10.3390\/molecules30153110","article-title":"Synthesis and Characterization of Covalent Triazine Frameworks Based on 4, 4-(Phenazine-5, 10-Diyl) Dibenzonitrile and Its Application in CO2\/CH4 Separation","volume":"30","author":"Othman","year":"2025","journal-title":"Molecules"},{"issue":"44","key":"2026101406080814200_cit59","doi-asserted-by":"publisher","first-page":"23146","DOI":"10.1021\/acs.langmuir.4c01042","article-title":"Development and Application of an Advanced Percolation Model for Pore Network Characterization by Physical Adsorption","volume":"40","author":"S\u00f6llner","year":"2024","journal-title":"Langmuir"},{"issue":"8","key":"2026101406080814200_cit60","doi-asserted-by":"publisher","first-page":"3418","DOI":"10.1021\/acsaelm.1c00396","article-title":"All-Carbon Negative Differential Resistance Nanodevice Using a Single Flake of Nanoporous Graphene","volume":"3","author":"Rahighi","year":"2021","journal-title":"ACS Appl. Electron. Mater."},{"issue":"4","key":"2026101406080814200_cit61","doi-asserted-by":"publisher","first-page":"1871","DOI":"10.1021\/acsenergylett.4c00266","article-title":"Tafel Slope Plot as a Tool to Analyze Electrocatalytic Reactions","volume":"9","author":"van der Heijden","year":"2024","journal-title":"ACS Energy Lett."},{"key":"2026101406080814200_cit62","doi-asserted-by":"publisher","first-page":"313","DOI":"10.1016\/j.colsurfb.2014.12.027","article-title":"Near Infrared Laser Stimulation of Human Neural Stem Cells into Neurons on Graphene Nanomesh Semiconductors","volume":"126","author":"Akhavan","year":"2015","journal-title":"Colloids Surf., B"},{"issue":"1","key":"2026101406080814200_cit63","doi-asserted-by":"publisher","first-page":"71","DOI":"10.1007\/s10856-026-07035-0","article-title":"Degradable Biophotonic Scaffolds of Mesoporous Graphene for Regenerating Neural Pathways","volume":"37","author":"Akhavan","year":"2026","journal-title":"J. Mater. Sci.: Mater. Med."},{"issue":"68","key":"2026101406080814200_cit64","doi-asserted-by":"publisher","first-page":"9704","DOI":"10.1039\/c4cc03330b","article-title":"Sensitive Detection of MicroRNA by Chronocoulometry and Rolling Circle Amplification on a Gold Electrode","volume":"50","author":"Yao","year":"2014","journal-title":"Chem. Commun."},{"issue":"9","key":"2026101406080814200_cit65","doi-asserted-by":"publisher","first-page":"5242","DOI":"10.1021\/jacs.2c12617","article-title":"Nanoscale Electron Transfer Variations at Electrocatalyst--Electrolyte Interfaces Resolved by in Situ Conductive Atomic Force Microscopy","volume":"145","author":"Munz","year":"2023","journal-title":"J. Am. Chem. Soc."},{"issue":"13","key":"2026101406080814200_cit66","doi-asserted-by":"publisher","first-page":"2461","DOI":"10.1016\/S0008-6223(02)00152-5","article-title":"Surface Properties of Oxyfluorinated PAN-Based Carbon Fibers","volume":"40","author":"Lee","year":"2002","journal-title":"Carbon N. Y."},{"issue":"1","key":"2026101406080814200_cit67","doi-asserted-by":"publisher","first-page":"25","DOI":"10.1002\/cbdv.201100036","article-title":"New Insights into the Characterization of \u2018insoluble Black HCN Polymers\u2019","volume":"9","author":"Ruiz-Bermejo","year":"2012","journal-title":"Chem. Biodivers."},{"key":"2026101406080814200_cit68","doi-asserted-by":"publisher","first-page":"197","DOI":"10.1016\/j.catcom.2013.12.019","article-title":"Preparation and Characterization of Poly-Hydrogen Cyanide Nanofibers with High Visible Light Photocatalytic Activity","volume":"46","author":"Zhou","year":"2014","journal-title":"Catal. Commun."},{"issue":"9","key":"2026101406080814200_cit69","doi-asserted-by":"publisher","first-page":"738","DOI":"10.1557\/mrs.2020.226","article-title":"In Situ Electrochemical Scanning\/Transmission Electron Microscopy of Electrode--Electrolyte Interfaces","volume":"45","author":"Unocic","year":"2020","journal-title":"MRS Bull."}],"container-title":["ACS Applied Materials &amp; Interfaces"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsami.6c06987","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/aamick\/article-pdf\/18\/40\/54734\/68738632\/am-2026-069877.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/aamick\/article-pdf\/18\/40\/54734\/68738632\/am-2026-069877.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T10:29:08Z","timestamp":1791973748000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/aamick\/article\/18\/40\/54734\/5444146\/Dual-Covalent-and-Spatial-Sulfur-Confinement-in"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,2]]},"references-count":69,"journal-issue":{"issue":"40","published-online":{"date-parts":[[2026,10,2]]},"published-print":{"date-parts":[[2026,10,14]]}},"URL":"https:\/\/doi.org\/10.1021\/acsami.6c06987","relation":{},"ISSN":["1944-8244","1944-8252"],"issn-type":[{"value":"1944-8244","type":"print"},{"value":"1944-8252","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,2]]}}}