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Yet precise control over their nanoscale growth and dispersion remains a fundamental challenge. Herein, we report a biomolecule-driven supramolecular templating strategy for the generation of amorphous coordination polymer nanodot-embedded hydrogel. A guanosine monophosphate-based G-quadruplex supramolecular architecture, co-assembled with gallic acid, serves as an active template that spatially confines metal\u2013polyphenol coordination. Upon Fe3+ incorporation, this supramolecular scaffold directs the formation of ultrasmall, uniformly dispersed coordination polymer nanodots, in contrast to the uncontrolled aggregation observed in non-templated systems. Spectroscopic and electrochemical analyses reveal that supramolecular confinement stabilizes mixed-valence Fe2+\/Fe3+ species and enhances ligand-to-metal charge transfer, imparting efficient photothermal conversion under visible-light irradiation. As a proof-of-concept, the resulting hybrid material is shown to be an effective photothermal catalyst for solvent-free cycloaddition of CO2 to epoxides under ambient pressure, delivering cyclic carbonates with high efficiency. This work establishes G-quadruplex assembly as a versatile platform for regulating size-controlled growth of coordination polymers and highlights the functional advantages of biomolecular confinement for sustainable catalytic transformations.<\/jats:p>","DOI":"10.1021\/acsami.6c08251","type":"journal-article","created":{"date-parts":[[2026,8,4]],"date-time":"2026-08-04T18:02:50Z","timestamp":1785866570000},"page":"44288-44301","source":"Crossref","is-referenced-by-count":0,"title":["Supramolecular G-Quadruplex Templating Enables Controlled Growth of Amorphous Coordination Polymer Nanodots for Photothermal CO2 Cycloaddition"],"prefix":"10.1021","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-9023-0700","authenticated-orcid":true,"given":"Tarun Kumar","family":"Sahu","sequence":"first","affiliation":[{"name":"Indian Institute of Technology Indore , , , ,","place":["Indore, Madhya Pradesh, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaurya","family":"Aneja","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , , ,","place":["Indore, Madhya Pradesh, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ravindra","family":"Vishwakarma","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , , ,","place":["Indore, Madhya Pradesh, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aditya","family":"Prasun","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , , ,","place":["Indore, Madhya Pradesh, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yoshita","family":"Chakravarty","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , , ,","place":["Indore, Madhya Pradesh, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-1836-3256","authenticated-orcid":true,"given":"Suryakamal","family":"Sarma","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , , ,","place":["Indore, Madhya Pradesh, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5168-6327","authenticated-orcid":true,"given":"Tridib K.","family":"Sarma","sequence":"additional","affiliation":[{"name":"Indian Institute of Technology Indore , , , ,","place":["Indore, Madhya Pradesh, India, 453552"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,4]]},"reference":[{"issue":"18","key":"2026081905143912800_cit1","doi-asserted-by":"publisher","first-page":"2334","DOI":"10.1002\/anie.200300610","article-title":"Functional Porous Coordination Polymers","volume":"43","author":"Kitagawa","year":"2004","journal-title":"Angew. 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