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Herein, we present an asymmetric dual-responsive MXene\/Viscose-PP (MVP) actuator integrated into a Janus photothermal mask for skin\u2013mask microclimate dynamic humidity\u2013thermal regulation. The MVP actuator switch with asymmetric bending deformation can achieve autonomous on\u2013off switching under temperature and humidity stimulation. The Janus photothermal mask enables unidirectional transport of exhaled breath condensate to the outer hydrophilic layer and enhances evaporation efficiency by 22.5 times. The synergistic integration of the Janus photothermal interface and the MVP actuator switch establishes a closed-loop dynamic humidity\u2013thermal regulation system. The smart switch-based Janus photothermal mask achieves a state of humidity\u2013thermal comfort during prolonged wearing. Such a closed-loop strategy offers a transformative route toward next-generation adaptive personal protective equipment and smart textiles, enabling autonomous human\u2013machine humidity\u2013thermal interaction without external energy consumption.<\/jats:p>","DOI":"10.1021\/acsami.6c09132","type":"journal-article","created":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T22:49:13Z","timestamp":1787352553000},"page":"46927-46938","source":"Crossref","is-referenced-by-count":0,"title":["Asymmetric Dual-Responsive Switch-Based Janus Photothermal Mask for Dynamic Humidity\u2013Thermal Regulation"],"prefix":"10.1021","volume":"18","author":[{"given":"Zhuohang","family":"Ma","sequence":"first","affiliation":[{"name":"Qingdao University , , ,","place":["Qingdao, China, 266071"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongtao","family":"Zhao","sequence":"additional","affiliation":[{"name":"Qingdao University , , ,","place":["Qingdao, China, 266071"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiyan","family":"Wang","sequence":"additional","affiliation":[{"name":"Qingdao University , , ,","place":["Qingdao, China, 266071"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mingzhu","family":"Shao","sequence":"additional","affiliation":[{"name":"Qingdao University , , ,","place":["Qingdao, China, 266071"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7951-7533","authenticated-orcid":true,"given":"Lijun","family":"Qu","sequence":"additional","affiliation":[{"name":"Qingdao University , , ,","place":["Qingdao, China, 266071"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0196-0543","authenticated-orcid":true,"given":"Yongchao","family":"Song","sequence":"additional","affiliation":[{"name":"Qingdao University , , ,","place":["Qingdao, China, 266071"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0035-3821","authenticated-orcid":true,"given":"Xueji","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shenzhen University , , , ,","place":["Shenzhen, Guangdong, China, 518060"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,21]]},"reference":[{"issue":"10","key":"2026090311213056500_cit1","doi-asserted-by":"publisher","first-page":"1388","DOI":"10.1038\/s41565-025-02010-2","article-title":"Wearable biomolecular sensing nanotechnologies in chronic disease management","volume":"20","author":"Tu","year":"2025","journal-title":"Nat. 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