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Among them, the rapid charge-discharge capabilities of ammonium-ion batteries (AIBs) and the high energy density of zinc-ion batteries (ZIBs) complement each other. Although V2O5 holds promise as a key electrode material in both AIBs and ZIBs, it is limited by its slow kinetics and structural instability. Herein, V2O5\u00b70.47H2O (HEVOH) with extended interlayer spacing and an optimized electronic structure is successfully constructed via a high-entropy doping strategy, effectively solving the issues of slow kinetics and structural instability of V2O5, and demonstrating outstanding performance in both AIBs and ZIBs. When used in AIBs, it delivers a capacity of 137.6 mAh g\u20131 at 0.20 A g\u20131, with a capacity retention of 92.7% at 1.00 A g\u20131 after 3000 cycles. When used in ZIBs, it achieves a capacity of 543.6 mAh g\u20131 at 0.10 A g\u20131, maintaining 76.6% capacity at 10.00 A g\u20131 after 7000 cycles. The NH4+ storage mechanism involves interlayer intercalation, hydrogen bond reconstruction, and oxygen vacancy generation. The Zn2+ storage mechanism is interlayer intercalation and reversible deposition of Zn4SO4(OH)6\u00b74H2O to construct a dynamic interface protective layer. This work provides a direction for the universal design of high-performance AESS.<\/jats:p>","DOI":"10.1021\/acsami.6c09981","type":"journal-article","created":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T22:01:22Z","timestamp":1789077682000},"page":"50746-50757","source":"Crossref","is-referenced-by-count":0,"title":["High-Entropy-Doped V2O5 for Efficient NH4+\/Zn2+ Energy Storage"],"prefix":"10.1021","volume":"18","author":[{"given":"Fei","family":"Long","sequence":"first","affiliation":[{"name":"Huazhong University of Science and Technology (HUST) , , ,","place":["Wuhan, China, 430074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7794-1763","authenticated-orcid":true,"given":"Zhi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Huazhong University of Science and Technology (HUST) , , ,","place":["Wuhan, China, 430074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Changwu","family":"Liu","sequence":"additional","affiliation":[{"name":"Huazhong University of Science and Technology (HUST) , , ,","place":["Wuhan, China, 430074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiming","family":"Ma","sequence":"additional","affiliation":[{"name":"Huazhong University of Science and Technology (HUST) , , ,","place":["Wuhan, China, 430074"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1905-9531","authenticated-orcid":true,"given":"Yihua","family":"Gao","sequence":"additional","affiliation":[{"name":"Huazhong University of Science and Technology (HUST) , , ,","place":["Wuhan, China, 430074"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,10]]},"reference":[{"key":"2026100820075678600_cit1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202500261","article-title":"Industrial Scalability of Zinc-Ion Batteries: Enhanced Electrochemical Performance with High Mass Loading Electrodes on Graphene-Coated Metal Current Collectors","volume":"15","author":"Heo","year":"2025","journal-title":"Adv. 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