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In this study, composite ink of graphene oxide (GO), tannic acid (TA), and cellulose nanofiber (CNF) is direct-write printed into a GO\/TA\/CNF porous structure (PS) with a freeze-dried process. With the negative charge of hydroxyl (-OH), carboxyl (-COOH), and phenolic hydroxyl (Ar-OH), the GO\/TA\/CNF PS of 3 cm length, 3 cm width, and 7 \u03bcm thickness realizes a maximum potential of 0.13 V and a maximum current density of 26.7 A\/m2 in KCl solution with a 1000-fold salinity gradient. Meanwhile, an energy conversion efficiency of 36.98% and different cation transportation are realized. A hydrogen bond network of GO\/TA\/CNF PS is formed by intermolecular interaction among -OH and -COOH of GO, TA, and CNF, which could absorb external force and recover into the original structure through the elastic modulus of the hydrogen bond. With a stretching force of 152.7 MPa, a constant output current is exhibited with structural integrity. After 104 cycles bending at a 0.2 mm\u20131 curvature, output power density is only changed by 0.9%. Meanwhile, unchanged current is demonstrated after 35 h immersion in acidic or neutral solution, and changed current within 6% is obtained after 35 h immersion in alkaline solution. Furthermore, the flexible ion channel is used in wearable electronics as a wearable energy device or body fluid electrolyte monitor.<\/jats:p>","DOI":"10.1021\/acsami.6c10835","type":"journal-article","created":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T15:23:06Z","timestamp":1787412186000},"page":"46974-46984","source":"Crossref","is-referenced-by-count":1,"title":["Direct-Write Printing Flexible Ion Channels with Graphene Oxide\/Tannic Acid\/Cellulose Nanofibers"],"prefix":"10.1021","volume":"18","author":[{"given":"Daoxin","family":"Wang","sequence":"first","affiliation":[{"name":"Qilu University of Technology (Shandong Academy of Sciences) , , ,","place":["Jinan, China, 250353"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenxi","family":"Li","sequence":"additional","affiliation":[{"name":"Qilu University of Technology (Shandong Academy of Sciences) , , ,","place":["Jinan, China, 250353"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qianqian","family":"Cui","sequence":"additional","affiliation":[{"name":"Shandong Institute for Product Quality Inspection , ,","place":["Jinan, China, 250102"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Huijuan","family":"Ni","sequence":"additional","affiliation":[{"name":"Qilu University of Technology (Shandong Academy of Sciences) , , ,","place":["Jinan, China, 250353"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0267-3917","authenticated-orcid":true,"given":"Yanlin","family":"Song","sequence":"additional","affiliation":[{"name":"Institute of Chemistry Chinese Academy of Sciences , , ,","place":["Beijing, China, 100190"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0213-9079","authenticated-orcid":true,"given":"Jiazhen","family":"Sun","sequence":"additional","affiliation":[{"name":"Qilu University of Technology (Shandong Academy of Sciences) , , ,","place":["Jinan, China, 250353"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,8,21]]},"reference":[{"key":"2026090311212584700_cit1","doi-asserted-by":"publisher","first-page":"470","DOI":"10.1038\/s41560-026-01976-0","article-title":"Charge and Slip-Length Optimization in Lipid-Bilayer-Coated Nanofluidics for Enhanced Osmotic Energy Harvesting","volume":"11","author":"Teng","year":"2026","journal-title":"Nat. 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