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Here, a hierarchical NiCoMn-NiN electrode was constructed by coupling a porous Ni3N framework with an amorphous Mn-containing Ni-Co hydroxide\/oxyhydroxide-like coating. In 1.0 M KOH, the electrode requires overpotentials of 100 and 315 mV at 100 mA cm\u20132 for HER and OER, respectively. A symmetric NiCoMn-NiN||NiCoMn-NiN electrolyzer delivers 100 mA cm\u20132 at 1.68 V and operates stably for 168 h. In 30 wt % KOH at 80 \u00b0C, the electrode sustains 1000 mA cm\u20132 for more than 358 h with only minor potential variation. Structural analyses indicate a predominantly amorphous coating with short-range metal-oxygen coordination and electrochemically induced surface evolution after operation. Density functional theory (DFT) calculations further suggest that Mn incorporation alters the local electronic environment and adsorption energetics of key intermediates. These results demonstrate the suitability of NiCoMn-NiN for sustained high-current alkaline electrolysis.<\/jats:p>","DOI":"10.1021\/acsami.6c10994","type":"journal-article","created":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T14:02:25Z","timestamp":1790344945000},"page":"53302-53314","source":"Crossref","is-referenced-by-count":0,"title":["Ni3N-Scaffolded Amorphous Ni-Co-Mn Hydroxide\/Oxyhydroxide Interfaces for Durable High-Current Alkaline Water Electrolysis"],"prefix":"10.1021","volume":"18","author":[{"given":"Ding","family":"Ping","sequence":"first","affiliation":[{"name":"Shanghai Advanced Research Institute, Chinese Academy of Sciences , ,","place":["Shanghai, People\u2019s Republic of China, 201210"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, People\u2019s Republic of China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanwen","family":"Tao","sequence":"additional","affiliation":[{"name":"Shanghai Advanced Research Institute, Chinese Academy of Sciences , ,","place":["Shanghai, People\u2019s Republic of China, 201210"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, People\u2019s Republic of China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6459-9057","authenticated-orcid":true,"given":"Gang","family":"Wang","sequence":"additional","affiliation":[{"name":"Shanghai Advanced Research Institute, Chinese Academy of Sciences , ,","place":["Shanghai, People\u2019s Republic of China, 201210"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, People\u2019s Republic of China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuanting","family":"Fan","sequence":"additional","affiliation":[{"name":"Shanghai Advanced Research Institute, Chinese Academy of Sciences , ,","place":["Shanghai, People\u2019s Republic of China, 201210"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, People\u2019s Republic of China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5329-9913","authenticated-orcid":true,"given":"Jie","family":"Zhang","sequence":"additional","affiliation":[{"name":"Shanghai Advanced Research Institute, Chinese Academy of Sciences , ,","place":["Shanghai, People\u2019s Republic of China, 201210"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, People\u2019s Republic of China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6077-7274","authenticated-orcid":true,"given":"Zhiyong","family":"Tang","sequence":"additional","affiliation":[{"name":"Shanghai Advanced Research Institute, Chinese Academy of Sciences , ,","place":["Shanghai, People\u2019s Republic of China, 201210"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, People\u2019s Republic of China, 100049"]},{"name":"University of Science and Technology of China , , , ,","place":["Hefei, Anhui, PR China, 230026"]},{"name":"Anhui Normal University , , ,","place":["Wuhu, PR China, 241000"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,25]]},"reference":[{"key":"2026100711082653700_cit1","doi-asserted-by":"publisher","DOI":"10.1016\/j.susmat.2024.e00991","article-title":"Nickel-Based Coatings as Highly Active Electrocatalysts for Hydrogen Evolution Reaction: A Review on Electroless Plating Cost-Effective Technique","volume":"40","author":"Molaei","year":"2024","journal-title":"Sustainable Mater. 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