{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,28]],"date-time":"2026-10-28T08:37:31Z","timestamp":1793176651682,"version":"4.5.0"},"reference-count":54,"publisher":"American Chemical Society (ACS)","issue":"42","license":[{"start":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T00:00:00Z","timestamp":1791849600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100002463","name":"General Motors Corporation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100002463","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Localized high-concentration electrolytes (LHCEs) using a 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE) diluent provide improved performance for high-voltage lithium (Li) metal batteries. However, the performance of LHCEs in high-voltage full cells with graphite anodes remains underexplored. In this regard, we systematically investigated the effect of chemical composition of LHCEs by varying TTE content and employing a lithium difluorophosphate (LiPO2F2) additive on physicochemical properties and electrochemical performances. Raman spectroscopy confirms that TTE dilution preserves anion-dominated solvation structures. Among LHCEs with TTE contents from 0 to 100 vol %, half and full cells with Li- and Mn-rich (LMR) high-voltage cathodes demonstrated optimal cycle life within the 20\u201340 vol % TTE. Adding 1 wt % LiPO2F2 to the LHCE with 30% TTE improves full-cell performance across the entire temperature range investigated (0, 25, and 45 \u00b0C). Postmortem analysis revealed the formation of LiF- and phosphate\/fluorophosphate-rich interphases on both electrodes, originating from LiPF6 and LiPO2F2 decomposition. As a result, the LHCE with 30% TTE and 1 wt % LiPO2F2 additive effectively suppressed the transition-metal (TM) dissolution (mainly Mn and Ni) from LMR cathodes at 50 \u00b0C for 3 weeks. These results demonstrate that coupling LHCE solvation chemistry with LiPO2F2-derived interphase engineering provides a promising pathway for stabilizing high-voltage full-cell performance across wide temperature ranges.<\/jats:p>","DOI":"10.1021\/acsami.6c11434","type":"journal-article","created":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T20:01:58Z","timestamp":1791921718000},"page":"57365-57380","source":"Crossref","is-referenced-by-count":0,"title":["Tailoring Localized High-Concentration Electrolytes for Wide-Temperature Operation of High-Voltage Full Cells with Graphite Anodes"],"prefix":"10.1021","volume":"18","author":[{"given":"Lakshmi Surag","family":"Singavarapu","sequence":"first","affiliation":[{"name":"The Ohio State University , , , ,","place":["Columbus, Ohio, United States, 43212"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ayush","family":"Morchhale","sequence":"additional","affiliation":[{"name":"The Ohio State University , , , ,","place":["Columbus, Ohio, United States, 43212"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Md Faiyaz","family":"Jamil","sequence":"additional","affiliation":[{"name":"The Ohio State University , , , ,","place":["Columbus, Ohio, United States, 43212"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenghuan","family":"Tang","sequence":"additional","affiliation":[{"name":"The Ohio State University , , , ,","place":["Columbus, Ohio, United States, 43212"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5400-7409","authenticated-orcid":true,"given":"Vamakshi","family":"Yadav","sequence":"additional","affiliation":[{"name":"General Motors Global Research and Development , , , ,","place":["Warren, Michigan, United States, 48092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-4035-4726","authenticated-orcid":true,"given":"Lei","family":"Wang","sequence":"additional","affiliation":[{"name":"General Motors Global Research and Development , , , ,","place":["Warren, Michigan, United States, 48092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7564-8766","authenticated-orcid":true,"given":"Devendrasinh","family":"Darbar","sequence":"additional","affiliation":[{"name":"General Motors Global Research and Development , , , ,","place":["Warren, Michigan, United States, 48092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gongshin","family":"Qi","sequence":"additional","affiliation":[{"name":"General Motors Global Research and Development , , , ,","place":["Warren, Michigan, United States, 48092"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jay","family":"Sayre","sequence":"additional","affiliation":[{"name":"The Ohio State University , , , ,","place":["Columbus, Ohio, United States, 43212"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4598-4686","authenticated-orcid":true,"given":"Jung-Hyun","family":"Kim","sequence":"additional","affiliation":[{"name":"The Ohio State University , , , ,","place":["Columbus, Ohio, United States, 43212"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,13]]},"reference":[{"issue":"6","key":"2026102802071384500_cit1","doi-asserted-by":"publisher","first-page":"2019","DOI":"10.1007\/s10008-012-1751-2","article-title":"Rechargeable Batteries: Challenges Old and New","volume":"16","author":"Goodenough","year":"2012","journal-title":"J. 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