{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T22:03:55Z","timestamp":1790114635820,"version":"4.0.1"},"reference-count":59,"publisher":"American Chemical Society (ACS)","issue":"35","license":[{"start":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T00:00:00Z","timestamp":1787788800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T00:00:00Z","timestamp":1787788800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T00:00:00Z","timestamp":1787788800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,9]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>A series of phenothiazine-modified diarylethene derivatives (1z\u20136z) were designed via molecular engineering to achieve multi-stimuli responsive photochromic materials. By precisely modulating donor linkage and conjugated bridge length, the absorption wavelengths of closed-ring isomers were effectively tuned, enabling broad color variation from yellow to deep purple. Notably, 3z and 4z, featuring a single benzene bridge, exhibit superior multi-stimuli responsive performance. Beyond retaining intrinsic reversible photochromism and fluorescence switching, they display a distinctive \u201cphoto\u2212oxidation\u201d synergistic mechanism. UV-induced closed-ring isomers reconstruct the electron delocalization pathway of oxidized products through a strong D\u2212\u03c0\u2212A architecture, inducing a precise red shift to the mid-visible region and enabling high-contrast color transitions (red\/purple to blue) independent of stimulus sequence. Electrochemical investigations further reveal that modulation of the oxidation potential via a photoinduced conformational gating effect serves as the fundamental basis for this synergistic behavior. Leveraging their solid-state responsiveness, gel-based electrochromic devices were fabricated, and a multi-component dynamic information encryption system was constructed, demonstrating multilevel anti-counterfeiting and information concealment. This work presents tunable, multi-responsive photochromic materials and a referable molecular engineering strategy for designing photo\u2212electro\u2212chemical synergistic triad systems.<\/jats:p>","DOI":"10.1021\/acsami.6c12196","type":"journal-article","created":{"date-parts":[[2026,9,2]],"date-time":"2026-09-02T00:07:11Z","timestamp":1788307631000},"page":"47916-47928","source":"Crossref","is-referenced-by-count":0,"title":["Photo-Programmable Synergistic Responses of Phenothiazine-Diarylethene Hybrids: From Molecular Engineering to Electrochromism and Information Encryption"],"prefix":"10.1021","volume":"18","author":[{"given":"Yan","family":"Zeng","sequence":"first","affiliation":[{"name":"East China University of Science & Technology , , ,","place":["Shanghai, P. R. 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