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Here, we present a tap-to-detect sensing platform that couples digitally printed gold nanoparticle nanoelectronics with a battery-free near-field communication (NFC) potentiostat. Single-pass digital materials deposition enables direct fabrication of ready-to-use AuNP working\/counter electrodes and AgNP reference electrodes on a flexible polyimide substrate, producing mechanically robust and electrochemically reliable devices. The NFC potentiostat provides smartphone-based wireless voltammetric readout with performance comparable to a commercial potentiostat. As proof of versatility, the printed AuNP electrode is applied to two distinct sensing modes: the thiol-mediated aptamer functionalization enables label-free HER2 biosensing with a detection limit of 4.87 pg mL\u20131 and successful analysis in spiked human serum, while the intrinsic Au\u2013As interaction enables direct As(III) detection with a detection limit of 42.5 ng mL\u20131, without additional electrode modification. This digitally printed, smartphone-readable gold nanoelectronic platform provides a scalable pathway toward portable electrochemical sensing for healthcare and environmental applications.<\/jats:p>","DOI":"10.1021\/acsami.6c12360","type":"journal-article","created":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T18:01:22Z","timestamp":1792519282000},"page":"58802-58813","source":"Crossref","is-referenced-by-count":0,"title":["Digitally Printed Gold Nanoelectronics for Tap-to-Detect Electrochemical Biosensing and Chemical Sensing"],"prefix":"10.1021","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8392-5492","authenticated-orcid":true,"given":"Abdulhadee","family":"Yakoh","sequence":"first","affiliation":[{"name":"Chulalongkorn University , , ,","place":["Bangkok, Thailand, 10330"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kingkan","family":"Pungjunan","sequence":"additional","affiliation":[{"name":"Silicon Craft Technology Public Company Limited , , ,","place":["Bangkok, Thailand, 10900"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pierre","family":"Guermonprez","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Paris Cit\u00e9, ITODYS, CNRS , ,","place":["Paris, France, F-75006"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Beno\u00eet","family":"Piro","sequence":"additional","affiliation":[{"name":"Universit\u00e9 Paris Cit\u00e9, ITODYS, CNRS , ,","place":["Paris, France, F-75006"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,20]]},"reference":[{"issue":"16","key":"2026111014064692500_cit1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202213744","article-title":"Advances in Printing and Electronics: From Engagement to Commitment","volume":"33","author":"Martins","year":"2023","journal-title":"Adv. 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