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However, sustainable photoinitiating systems that operate efficiently under visible light remain limited. Here, a sustainable two-component strategy is reported by combining bio-derived oxime esters with natural or bio-inspired photosensitizers for 405 nm curing. Among the systems investigated, the synthesized oxime ester (OXE1) and menadione (MD, vitamin K3) pair show the best performance, enabling rapid photopolymerization of TMPTA with good formulation homogeneity, low coloration, and good storage stability. Electrochemical analysis and excited-state energetics indicate that direct single-electron transfer between MD and OXE1 is thermodynamically unfavorable. In contrast, steady-state photolysis, laser flash photolysis, CO2 evolution, and ESR spin trapping support a triplet\u2013triplet energy transfer pathway, followed by N\u2013O bond cleavage and decarboxylation, to generate initiating radicals. This work establishes a simple sensitization principle for converting UV-responsive bio-derived oxime esters into visible-light photoinitiators and provides a sustainable design strategy for photopolymerization and 3D microfabrication.<\/jats:p>","DOI":"10.1021\/acsami.6c13183","type":"journal-article","created":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T16:13:05Z","timestamp":1784823185000},"page":"41869-41880","source":"Crossref","is-referenced-by-count":0,"title":["Sustainable Visible-Light Photoinitiation Enabled by a Bio-Based Photosensitizer\/Oxime Ester Combination via Triplet\u2013Triplet Energy Transfer"],"prefix":"10.1021","volume":"18","author":[{"given":"Kaidan","family":"Yang","sequence":"first","affiliation":[{"name":"Universit\u00e9 de Haute-Alsace, CNRS, IS2M UMR7361 , ,","place":["Mulhouse, France, F-68100"]},{"name":"Universit\u00e9 de Strasbourg , 4 Rue Blaise Pascal , ,","place":["Strasbourg, France, F-67081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Margot","family":"Manivel","sequence":"additional","affiliation":[{"name":"Aix Marseille Universit\u00e9, CNRS, ICR UMR7273 , ,","place":["Marseille Cedex 20, France, 13397"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-6972-8995","authenticated-orcid":true,"given":"Coralie","family":"Ohl","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Haute-Alsace, CNRS, IS2M UMR7361 , ,","place":["Mulhouse, France, F-68100"]},{"name":"Universit\u00e9 de Strasbourg , 4 Rue Blaise Pascal , ,","place":["Strasbourg, France, F-67081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"C\u00e9line","family":"Dietlin","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Haute-Alsace, CNRS, IS2M UMR7361 , ,","place":["Mulhouse, France, F-68100"]},{"name":"Universit\u00e9 de Strasbourg , 4 Rue Blaise Pascal , ,","place":["Strasbourg, France, F-67081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fabrice","family":"Morlet-Savary","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Haute-Alsace, CNRS, IS2M UMR7361 , ,","place":["Mulhouse, France, F-68100"]},{"name":"Universit\u00e9 de Strasbourg , 4 Rue Blaise Pascal , ,","place":["Strasbourg, France, F-67081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Schmitt","sequence":"additional","affiliation":[{"name":"Universit\u00e9 de Haute-Alsace, CNRS, IS2M UMR7361 , ,","place":["Mulhouse, France, F-68100"]},{"name":"Universit\u00e9 de Strasbourg , 4 Rue Blaise Pascal , ,","place":["Strasbourg, France, F-67081"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jean-Patrick","family":"Joly","sequence":"additional","affiliation":[{"name":"Aix Marseille Universit\u00e9, CNRS, ICR UMR7273 , ,","place":["Marseille Cedex 20, France, 13397"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Future Industries Institute, Adelaide University , , ,","place":["Mawson Lakes, South Australia, Australia, 5095"]},{"name":", , ,","place":["Adelaide, SA, Australia, 5005"],"department":["School of Chemical Engineering, Adelaide University"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Pu","family":"Xiao","sequence":"additional","affiliation":[{"name":"Shanghai Institute of Ceramics, Chinese Academy of Sciences , , ,","place":["Shanghai, P. 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