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However, severe self-corrosion of aluminum anode and parasitic hydrogen evolution reaction (HER) in highly alkaline electrolytes hinder their practical deployment. This work proposes a novel organic\u2013inorganic hybrid corrosion inhibitor comprising sodium 3-mercapto-1-propanesulfonate (MPS) and zinc oxide (ZnO). Combined experimental and computational investigations demonstrate that a dense, robust adsorption\u2013deposition composite protective layer is formed on the anode surface via a \u201cmolecular bridging\u201d synergistic mechanism, delivering a corrosion inhibition efficiency of 72.9%. In alkaline Al-H2O full-cell tests, the battery achieves 77.5% anode utilization, and a specific capacity of 2309 mAh g\u20131 at 20 mA cm\u20132. This work offers valuable guidance for designing high-performance hybrid corrosion inhibitors for Al anodes.<\/jats:p>","DOI":"10.1021\/acsami.6c13420","type":"journal-article","created":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T18:02:35Z","timestamp":1790618555000},"page":"53463-53474","source":"Crossref","is-referenced-by-count":0,"title":["Molecular Bridge Engineering at the Anode\/Electrolyte Interface: Synergistic MPS\/ZnO Hybrid Corrosion Inhibition for High-Utilization Alkaline Al-H2O Batteries"],"prefix":"10.1021","volume":"18","author":[{"given":"Jiayao","family":"Gao","sequence":"first","affiliation":[{"name":"Northeastern University , , ,","place":["Shenyang, People\u2019s Republic of China, 110819"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chen","family":"Chen","sequence":"additional","affiliation":[{"name":"Northeastern University , , ,","place":["Shenyang, People\u2019s Republic of China, 110819"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linshan","family":"Wang","sequence":"additional","affiliation":[{"name":"Quanzhou Vocational and Technical University , , ,","place":["Jinjiang, People\u2019s Republic of China, 362268"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenyu","family":"Wang","sequence":"additional","affiliation":[{"name":"Northeastern University , , ,","place":["Shenyang, People\u2019s Republic of China, 110819"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"You","family":"Fu","sequence":"additional","affiliation":[{"name":"Northeastern University , , ,","place":["Shenyang, People\u2019s Republic of China, 110819"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaxin","family":"Li","sequence":"additional","affiliation":[{"name":"Northeastern University , , ,","place":["Shenyang, People\u2019s Republic of China, 110819"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yinghang","family":"Kou","sequence":"additional","affiliation":[{"name":"Northeastern University , , ,","place":["Shenyang, People\u2019s Republic of China, 110819"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zilong","family":"Liu","sequence":"additional","affiliation":[{"name":"Northeastern University , , ,","place":["Shenyang, People\u2019s Republic of China, 110819"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiming","family":"Wang","sequence":"additional","affiliation":[{"name":"Northeastern University , , ,","place":["Shenyang, People\u2019s Republic of China, 110819"]},{"name":"Tsinghua University , , ,","place":["Beijing, People\u2019s Republic of China, 100084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9007-4091","authenticated-orcid":true,"given":"Hongbin","family":"Sun","sequence":"additional","affiliation":[{"name":"Northeastern University , , ,","place":["Shenyang, People\u2019s Republic of China, 110819"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,28]]},"reference":[{"key":"2026100711093268900_cit1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apenergy.2026.127832","article-title":"Exploring the landscape of electrochemical energy storage technologies: A disruptive innovation perspective","volume":"414","author":"Zhang","year":"2026","journal-title":"Appl. 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