{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T17:46:29Z","timestamp":1792518389225,"version":"4.5.0"},"reference-count":60,"publisher":"American Chemical Society (ACS)","issue":"37","license":[{"start":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T00:00:00Z","timestamp":1788912000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T00:00:00Z","timestamp":1788912000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T00:00:00Z","timestamp":1788912000000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,23]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Poly(ionic liquid)-grafted UiO-66-NH2 gels are developed as a high-performance and co-catalyst-free platform for efficient CO2 capture and chemical fixation under mild conditions. To address the mass transfer limitations and high energy barriers typical of purely microporous powder materials, a series of hierarchically porous metal\u2013organic framework (MOF)-poly(ionic liquid) hybrid gels (HP-MOF-PILs) were engineered within a structurally adaptive UiO-66-NH2 gel matrix by integrating covalent anchoring with subsequent radical polymerization. Structural characterization reveals that the hybrid catalyst maintains the structural integrity of the MOF gel framework while successfully preserving the well-defined, highly interconnected mesoporous network inherent to the gel skeleton. Although the intensive grafting of PIL segments leads to a reduction in intrinsic microporosity, the gel-derived open mesopores significantly alleviate mass transfer resistance, preventing the active-site burial and heavy aggregation common in bulk polymers or packed powders, thereby ensuring high accessibility to the catalytic centers. The hybrid catalyst achieves over 99% cyclochloroallyl carbonate yield under 0.1 MPa CO2 without any co-catalyst. The high catalytic efficiency stems from a multi-site cooperative effect, wherein coordinatively unsaturated Zr4+ Lewis acid centers assisted by structural Zr\u2212OH groups on the MOF nodes electrophilically activate epoxide C\u2212O bonds, while grafted PIL segments supply hydrogen-bonding donors and nucleophilic Br\u2212 anions for rapid ring-opening. Furthermore, owing to the macrostructural stability and resilient coordination network of the gel matrix, the catalyst exhibits excellent durability over six consecutive cycles. This work provides a promising strategy for designing integrated gel-based composite catalysts with self-supporting pore architectures for sustainable carbon utilization.<\/jats:p>","DOI":"10.1021\/acsami.6c13731","type":"journal-article","created":{"date-parts":[[2026,9,9]],"date-time":"2026-09-09T16:02:19Z","timestamp":1788969739000},"page":"51058-51070","source":"Crossref","is-referenced-by-count":0,"title":["Poly(ionic liquid)-Grafted MOF Gels: A Co-catalyst-free Platform for High-Efficiency CO2 Cycloaddition"],"prefix":"10.1021","volume":"18","author":[{"given":"Dongsheng","family":"Li","sequence":"first","affiliation":[{"name":"Tianjin University , , ,","place":["Tianjin, China, 300350"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Li","sequence":"additional","affiliation":[{"name":"Tianjin University , , ,","place":["Tianjin, China, 300350"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yangyang","family":"Lei","sequence":"additional","affiliation":[{"name":"Tianjin University , , ,","place":["Tianjin, China, 300350"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meilin","family":"Yin","sequence":"additional","affiliation":[{"name":"Tianjin University , , ,","place":["Tianjin, China, 300350"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaoning","family":"Shi","sequence":"additional","affiliation":[{"name":"Tianjin University , , ,","place":["Tianjin, China, 300350"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5481-1680","authenticated-orcid":true,"given":"Shaokun","family":"Tang","sequence":"additional","affiliation":[{"name":"Tianjin University , , ,","place":["Tianjin, China, 300350"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,9]]},"reference":[{"key":"2026102013065745500_cit1","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.130981","article-title":"Application of Ionic Liquids in CO2 Capture and Conversion: A Review","volume":"360","author":"Xing","year":"2025","journal-title":"Sep. Purif. Technol."},{"key":"2026102013065745500_cit2","doi-asserted-by":"publisher","DOI":"10.1016\/j.enconman.2023.116755","article-title":"The Novel Contribution of Non-Noble Metal Catalysts for Intensified Carbon Dioxide Hydrogenation: Recent Challenges and Opportunities","volume":"279","author":"Tawalbeh","year":"2023","journal-title":"Energy Convers. Manag."},{"key":"2026102013065745500_cit3","doi-asserted-by":"publisher","DOI":"10.1016\/j.rser.2024.114297","article-title":"Cyclic Carbonates: Treasure of Fine Chemicals Obtained from Waste Stream CO2 over Carbon-Based Heterogeneous Catalysts","volume":"193","author":"Sahil","year":"2024","journal-title":"Renewable Sustainable Energy Rev."},{"issue":"14","key":"2026102013065745500_cit4","doi-asserted-by":"publisher","first-page":"5195","DOI":"10.1039\/D1GC01312B","article-title":"Noble Metal-Free Cu(\u2160)-Anchored NHC-Based MOF for Highly Recyclable Fixation of CO2 under RT and Atmospheric Pressure Conditions","volume":"23","author":"Das","year":"2021","journal-title":"Green Chem."},{"issue":"2","key":"2026102013065745500_cit5","doi-asserted-by":"publisher","first-page":"353","DOI":"10.1007\/s13738-021-02330-9","article-title":"Cyclic Carbonates Synthesis by Cycloaddition Reaction of CO2 with Epoxides in the Presence of Zinc-Containing and Ionic Liquid Catalysts","volume":"19","author":"Nasirov","year":"2022","journal-title":"J. Iran. Chem. Soc."},{"issue":"8","key":"2026102013065745500_cit6","doi-asserted-by":"publisher","first-page":"825","DOI":"10.3390\/catal10080825","article-title":"Metal Complexes Bearing Sulfur-Containing Ligands as Catalysts in the Reaction of CO2 with Epoxides","volume":"10","author":"Paradiso","year":"2020","journal-title":"Catalysts"},{"issue":"16","key":"2026102013065745500_cit7","doi-asserted-by":"publisher","first-page":"10373","DOI":"10.1021\/acscatal.2c02649","article-title":"Bifunctional {Pb10K2}\u2212Organic Framework for High Catalytic Activity in Cycloaddition of CO2 with Epoxides and Knoevenagel Condensation","volume":"12","author":"Liu","year":"2022","journal-title":"ACS Catal."},{"key":"2026102013065745500_cit8","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.151657","article-title":"Implanting Multi-Functional Ionic Liquids into MOF Nodes for Boosting CO2 Cycloaddition under Solventless and Cocatalyst-Free Conditions","volume":"490","author":"Chen","year":"2024","journal-title":"Chem. Eng. J."},{"key":"2026102013065745500_cit9","doi-asserted-by":"publisher","DOI":"10.1016\/j.jssc.2022.122965","article-title":"Porous Polymeric Metalloporphyrin Obtained through Sonogashira Coupling: Catalytic Performance at CO2 Cycloaddition to Epoxides","volume":"309","author":"He","year":"2022","journal-title":"J. Solid State Chem."},{"issue":"44","key":"2026102013065745500_cit10","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202206991","article-title":"Strong Electronic Metal\u2212Support Interaction between Iridium Single Atoms and a WO3 Support Promotes Highly Efficient and Robust CO2 Cycloaddition","volume":"34","author":"Xu","year":"2022","journal-title":"Adv. Mater."},{"issue":"1","key":"2026102013065745500_cit11","doi-asserted-by":"publisher","first-page":"57","DOI":"10.1021\/acscatal.5c06316","article-title":"Advances and Mechanistic Insights into Covalent Organic Framework-Mediated Photocatalysis for Organic Transformations","volume":"16","author":"Lin","year":"2026","journal-title":"ACS Catal."},{"issue":"1","key":"2026102013065745500_cit12","doi-asserted-by":"publisher","first-page":"10818","DOI":"10.1038\/s41467-025-66469-2","article-title":"Straightforward Construction of Functionalized \u03b3-Lactams via Conjugated-Engineered Covalent Organic Framework Photocatalysed Cascade Reactions","volume":"16","author":"Lin","year":"2025","journal-title":"Nat. Commun."},{"key":"2026102013065745500_cit13","doi-asserted-by":"publisher","DOI":"10.1016\/j.molliq.2022.118556","article-title":"Diverse Applications of Ionic Liquids: A Comprehensive Review","volume":"351","author":"Kaur","year":"2022","journal-title":"J. Mol. Liq."},{"key":"2026102013065745500_cit14","doi-asserted-by":"publisher","DOI":"10.1016\/j.cogsc.2022.100599","article-title":"Task-Specific Ionic Liquids for Carbon Dioxide Absorption and Conversion into Value-Added Products","volume":"34","author":"Qu","year":"2022","journal-title":"Curr. Opin. Green Sustainable Chem."},{"issue":"47","key":"2026102013065745500_cit15","doi-asserted-by":"publisher","first-page":"26554","DOI":"10.1039\/C8RA03952F","article-title":"Catalytic Conversion of CO2 into Propylene Carbonate in a Continuous Fixed Bed Reactor by Immobilized Ionic Liquids","volume":"8","author":"Guo","year":"2018","journal-title":"RSC Adv."},{"issue":"6","key":"2026102013065745500_cit16","doi-asserted-by":"publisher","DOI":"10.1016\/j.jece.2025.120398","article-title":"Poly(Ionic Liquid)s-Loaded Metal-Organic Framework Gel for CO2 Capture and Cycloaddition Catalytic Conversion","volume":"13","author":"Li","year":"2025","journal-title":"J. Environ. Chem. Eng."},{"issue":"8","key":"2026102013065745500_cit17","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.202200234","article-title":"In-situ Synthesis of Ionic Liquids on B-doped Mesoporous SiO2 Catalyst for epoxide-CO2 Cycloaddition","volume":"11","author":"Ye","year":"2022","journal-title":"Asian J. Org. Chem."},{"issue":"43","key":"2026102013065745500_cit18","doi-asserted-by":"publisher","first-page":"8824","DOI":"10.1039\/D2TB01787C","article-title":"Current Status and Future Prospects of Nanoscale Metal\u2212Organic Frameworks in Bioimaging","volume":"10","author":"Nazari","year":"2022","journal-title":"J. Mater. Chem. B"},{"key":"2026102013065745500_cit19","doi-asserted-by":"publisher","DOI":"10.1016\/j.jhazmat.2022.130127","article-title":"Recent Advances in Application of Metal-Organic Frameworks (MOFs) as Adsorbent and Catalyst in Removal of Persistent Organic Pollutants (POPs)","volume":"442","author":"Naghdi","year":"2023","journal-title":"J. Hazard. Mater."},{"issue":"9","key":"2026102013065745500_cit20","doi-asserted-by":"publisher","first-page":"5227","DOI":"10.1021\/acs.chemrev.3c00379","article-title":"Ionic Liquids in Metal, Photo-, Electro-, and (Bio) Catalysis","volume":"124","author":"Dupont","year":"2024","journal-title":"Chem. Rev."},{"key":"2026102013065745500_cit21","doi-asserted-by":"publisher","DOI":"10.1016\/j.seppur.2024.128794","article-title":"Aerogel-Based Carbon Capture Materials: Research Progress and Application Prospects","volume":"354","author":"Cui","year":"2025","journal-title":"Sep. Purif. Technol."},{"issue":"2","key":"2026102013065745500_cit22","doi-asserted-by":"publisher","first-page":"1455","DOI":"10.1021\/acsanm.0c02984","article-title":"Cu(II)-Based Nanofibrous Metallogel for Phenoxazinone Synthase-like Activity","volume":"4","author":"Sarkar","year":"2021","journal-title":"ACS Appl. Nano Mater."},{"issue":"37","key":"2026102013065745500_cit23","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202505407","article-title":"Lead Halide Perovskite Nanocrystals in Metal-organic Frameworks: Synthesis, Properties, and Applications","volume":"12","author":"Fang","year":"2025","journal-title":"Adv. Sci."},{"issue":"10","key":"2026102013065745500_cit24","doi-asserted-by":"publisher","first-page":"6866","DOI":"10.1039\/D4TA06000H","article-title":"The Synergistic Effect of MOF and Biomass Achieving Dual Breakthroughs in Material Structure and Performance","volume":"13","author":"Li","year":"2025","journal-title":"J. Mater. Chem. A"},{"issue":"1\u22122","key":"2026102013065745500_cit25","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/j.apcata.2009.10.008","article-title":"Ionic Liquids and Catalysis: Recent Progress from Knowledge to Applications","volume":"373","author":"Olivier-Bourbigou","year":"2010","journal-title":"Appl. Catal., A"},{"issue":"10","key":"2026102013065745500_cit26","doi-asserted-by":"publisher","first-page":"6755","DOI":"10.1021\/acs.chemrev.6b00509","article-title":"Nanoconfined Ionic Liquids","volume":"117","author":"Zhang","year":"2017","journal-title":"Chem. Rev."},{"issue":"32","key":"2026102013065745500_cit27","doi-asserted-by":"publisher","first-page":"27124","DOI":"10.1021\/acsami.8b08914","article-title":"Facile Approach to Graft Ionic Liquid into MOF for Improving the Efficiency of CO2 Chemical Fixation","volume":"10","author":"Sun","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"6","key":"2026102013065745500_cit28","doi-asserted-by":"publisher","first-page":"7364","DOI":"10.1021\/acsami.3c18885","article-title":"A Hierarchical Metal\u2212Organic Framework Composite Aerogel Catalyst Containing Integrated Acid, Base, and Metal Sites for the One-Pot Catalytic Synthesis of Cyclic Carbonates","volume":"16","author":"Zhao","year":"2024","journal-title":"ACS Appl. Mater. Interfaces"},{"issue":"49","key":"2026102013065745500_cit29","doi-asserted-by":"publisher","first-page":"20528","DOI":"10.1021\/acs.inorgchem.3c03923","article-title":"Hierarchical Amino-Functionalized Ionic liquids@MOF Composite Gel for Catalytic Conversion of CO2","volume":"62","author":"Dong","year":"2023","journal-title":"Inorg. Chem."},{"issue":"2","key":"2026102013065745500_cit30","doi-asserted-by":"publisher","first-page":"219","DOI":"10.1039\/C7QM00416H","article-title":"Hybridization of Metal\u2212Organic Frameworks and Task-Specific Ionic Liquids: Fundamentals and Challenges","volume":"2","author":"Luo","year":"2018","journal-title":"Mater. Chem. Front."},{"issue":"4","key":"2026102013065745500_cit31","doi-asserted-by":"publisher","first-page":"3194","DOI":"10.1021\/acscatal.7b03404","article-title":"Incorporation of Imidazolium-Based Poly(Ionic Liquid)s into a Metal\u2212Organic Framework for CO2 Capture and Conversion","volume":"8","author":"Ding","year":"2018","journal-title":"ACS Catal."},{"issue":"82","key":"2026102013065745500_cit32","doi-asserted-by":"publisher","first-page":"9449","DOI":"10.1039\/c3cc46105j","article-title":"A Facile Synthesis of UiO-66, UiO-67 and Their Derivatives","volume":"49","author":"Katz","year":"2013","journal-title":"Chem. Commun."},{"issue":"8","key":"2026102013065745500_cit33","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.6777","article-title":"Improving Proton Conductivity of Metal Organic Framework Materials by Reducing Crystallinity","volume":"36","author":"Tang","year":"2022","journal-title":"Appl. Organomet. Chem."},{"issue":"83","key":"2026102013065745500_cit34","doi-asserted-by":"publisher","first-page":"11817","DOI":"10.1039\/C8CC05895D","article-title":"Hierarchically Porous UiO-66: Facile Synthesis, Characterization and Application","volume":"54","author":"Hao","year":"2018","journal-title":"Chem. Commun."},{"issue":"4","key":"2026102013065745500_cit35","doi-asserted-by":"publisher","first-page":"1301","DOI":"10.1039\/D2MH01202B","article-title":"MOF\/Polymer Hybrids through in Situ Free Radical Polymerization in Metal-Organic Frameworks","volume":"10","author":"Pander","year":"2023","journal-title":"Mater. Horiz."},{"key":"2026102013065745500_cit36","doi-asserted-by":"publisher","first-page":"209","DOI":"10.1016\/j.jssc.2014.12.033","article-title":"Structural Study of Ni- or Mg-Based Complexes Incorporated within UiO-66-NH2 Framework and Their Impact on Hydrogen Sorption Properties","volume":"225","author":"\u017dunkovi\u010d","year":"2015","journal-title":"J. Solid State Chem."},{"issue":"1","key":"2026102013065745500_cit37","doi-asserted-by":"publisher","first-page":"268","DOI":"10.2136\/sssaj2007.0045","article-title":"Comparison of Solid-state Carbon-13 Nuclear Magnetic Resonance and Organic Matter Biomarkers for Assessing Soil Organic Matter Degradation","volume":"72","author":"Simpson","year":"2008","journal-title":"Soil Sci. Soc. Am. J."},{"key":"2026102013065745500_cit38","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2023.136377","article-title":"8-Benzimidazolyl Coumarin-3-Oxadiazoles \u2212 Synthesis, Docking Studies and Anti-Proliferative Evaluation against Breast Cancer","volume":"1294","author":"Patagar","year":"2023","journal-title":"J. Mol. Struct."},{"issue":"46","key":"2026102013065745500_cit39","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202515034","article-title":"Synergistic Effect of Dual-functional Groups in MOF-modified Separators for Efficient Lithium-ion Transport and Polysulfide Management of Lithium-sulfur Batteries","volume":"12","author":"Liu","year":"2025","journal-title":"Adv. Sci."},{"issue":"1","key":"2026102013065745500_cit40","doi-asserted-by":"publisher","first-page":"153","DOI":"10.1007\/s40820-021-00677-5","article-title":"Interface Engineered Microcellular Magnetic Conductive Polyurethane Nanocomposite Foams for Electromagnetic Interference Shielding","volume":"13","author":"Sang","year":"2021","journal-title":"Nano Micro Lett."},{"issue":"2","key":"2026102013065745500_cit41","doi-asserted-by":"publisher","first-page":"10","DOI":"10.1007\/s44307-025-00061-z","article-title":"Electrostatic Charge at the Biomaterial-Pathogen Interface Influences Antibiotic Efficacy","volume":"3","author":"Hayles","year":"2025","journal-title":"Adv. Biotechnol."},{"issue":"9","key":"2026102013065745500_cit42","doi-asserted-by":"publisher","first-page":"2013","DOI":"10.1021\/acsaom.5c00225","article-title":"Electronic Redistribution-Mediated Fluorescence Response to SO2 in Hybrid NiCo-Layered Double Hydroxide-(3-Chloropropyl)Trimethoxysilane\/UiO-66-NH2 Systems","volume":"3","author":"Flores-Aguilar","year":"2025","journal-title":"ACS Appl. Opt. Mater."},{"issue":"1","key":"2026102013065745500_cit43","doi-asserted-by":"publisher","first-page":"3317","DOI":"10.1038\/s41467-023-39089-x","article-title":"A Porous Metal-Organic Cage Liquid for Sustainable CO2 Conversion Reactions","volume":"14","author":"He","year":"2023","journal-title":"Nat. Commun."},{"issue":"3","key":"2026102013065745500_cit44","doi-asserted-by":"publisher","first-page":"1404","DOI":"10.1039\/D4SU00661E","article-title":"Spaced Functionalization of Poly(Ionic Liquid)s for Boosting the Catalytic Conversion of CO2 into Cyclic Carbonates","volume":"3","author":"Zhao","year":"2025","journal-title":"RSC Sustainability"},{"issue":"4","key":"2026102013065745500_cit45","doi-asserted-by":"publisher","first-page":"421","DOI":"10.1007\/s12209-025-00447-z","article-title":"MOF-Derived Oxygen-Vacancy-Rich ZrO2\/UiO-66-NH2 for Efficient Visible-Light-Driven Oxidation of Benzyl Alcohol","volume":"31","author":"Song","year":"2025","journal-title":"Trans. Tianjin Univ."},{"key":"2026102013065745500_cit46","doi-asserted-by":"publisher","first-page":"275","DOI":"10.1016\/j.polymer.2017.01.056","article-title":"Nanoporous Triptycene Based Network Polyamides (TBPs) for Selective CO2 Uptake","volume":"111","author":"Bera","year":"2017","journal-title":"Polymer"},{"key":"2026102013065745500_cit47","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2020.110578","article-title":"Imidazolium Ionic Liquid Functionalized UiO-66-NH2 as Highly Efficient Catalysts for Chemical Fixation of CO2 into Cyclic Carbonates","volume":"310","author":"Wu","year":"2021","journal-title":"Microporous Mesoporous Mater."},{"key":"2026102013065745500_cit48","doi-asserted-by":"publisher","first-page":"1000","DOI":"10.1016\/j.jcis.2024.02.048","article-title":"Synergistic Effects of Core\u2212Shell Poly(Ionic Liquids)@ZIF-8 Nanocomposites for Enhancing Additive-Free CO2 Conversion","volume":"661","author":"Dong","year":"2024","journal-title":"J. Colloid Interface Sci."},{"issue":"10","key":"2026102013065745500_cit49","doi-asserted-by":"publisher","first-page":"6241","DOI":"10.1007\/s10570-019-02531-9","article-title":"Enhanced Removal of Prometryn Using Copper Modified Microcrystalline Cellulose (Cu-MCC): Optimization, Isotherm, Kinetics and Regeneration Studies","volume":"26","author":"Garba","year":"2019","journal-title":"Cellulose"},{"key":"2026102013065745500_cit50","doi-asserted-by":"publisher","first-page":"397","DOI":"10.1016\/j.molliq.2018.01.152","article-title":"The Curious Effect of Potassium Fluoride on Glycerol Carbonate How Salts Can Influence the Structuredness of Organic Solvents","volume":"255","author":"Sarri","year":"2018","journal-title":"J. Mol. Liq."},{"key":"2026102013065745500_cit51","doi-asserted-by":"publisher","first-page":"42431","DOI":"10.1039\/D6RA04608H","article-title":"Regeneration of Deactivated Activated Carbon Honeycomb Catalysts for VOC Removal: Structural Evolution and Activity Recovery Mechanisms","author":"Huang","year":"2026","journal-title":"RSC Adv."},{"issue":"32","key":"2026102013065745500_cit52","doi-asserted-by":"publisher","first-page":"10264","DOI":"10.1002\/ange.201803081","article-title":"Lower Activation Energy for Catalytic Reactions through Host\u2212Guest Cooperation within Metal\u2212Organic Frameworks","volume":"130","author":"Aguila","year":"2018","journal-title":"Angew. Chem., Int. Ed."},{"issue":"11","key":"2026102013065745500_cit53","doi-asserted-by":"publisher","DOI":"10.1002\/aoc.7640","article-title":"Dicationic Ionic Liquid-grafted UiO-66 as Efficient Catalyst for CO2 Conversion into Cyclocarbonate under Cocatalyst-free and Solventless Conditions","volume":"38","author":"Li","year":"2024","journal-title":"Appl. Organomet. Chem."},{"key":"2026102013065745500_cit54","doi-asserted-by":"publisher","first-page":"22","DOI":"10.1016\/j.jcis.2022.03.038","article-title":"Hydrogen Bond Donor Functionalized Poly(Ionic Liquids)@MIL-101 for the CO2 Capture and Improving the Catalytic CO2 Conversion with Epoxide","volume":"618","author":"Jiang","year":"2022","journal-title":"J. Colloid Interface Sci."},{"issue":"5","key":"2026102013065745500_cit55","doi-asserted-by":"publisher","first-page":"1033","DOI":"10.1002\/cssc.201802838","article-title":"Ionic-liquid-functionalized UiO-66 Framework: An Experimental and Theoretical Study on the Cycloaddition of CO2 and Epoxides","volume":"12","author":"Kurisingal","year":"2019","journal-title":"ChemSusChem"},{"issue":"4","key":"2026102013065745500_cit56","doi-asserted-by":"publisher","first-page":"3962","DOI":"10.1021\/acssuschemeng.8b05226","article-title":"Task-Specific Ionic Liquid Functionalized\u2212MIL\u2212101(Cr) as a Heterogeneous and Efficient Catalyst for the Cycloaddition of CO2 with Epoxides under Solvent Free Conditions","volume":"7","author":"Bahadori","year":"2019","journal-title":"ACS Sustainable Chem. Eng."},{"key":"2026102013065745500_cit57","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2022.126191","article-title":"One-Step Supramolecular Construction of Lewis Pair Poly(Ionic Liquids) for Atmospheric CO2 Conversion to Cyclic Carbonates","volume":"332","author":"Zhang","year":"2023","journal-title":"Fuel"},{"issue":"2","key":"2026102013065745500_cit58","doi-asserted-by":"publisher","first-page":"1570","DOI":"10.1039\/C6SC04357G","article-title":"Postsynthetic Ionization of an Imidazole-Containing Metal\u2212Organic Framework for the Cycloaddition of Carbon Dioxide and Epoxides","volume":"8","author":"Liang","year":"2017","journal-title":"Chem. Sci."},{"issue":"3","key":"2026102013065745500_cit59","doi-asserted-by":"publisher","first-page":"2005","DOI":"10.1039\/D0CP06041K","article-title":"Hydrogen Bond Donor Functionalized Poly(Ionic Liquid)s for Efficient Synergistic Conversion of CO2 to Cyclic Carbonates","volume":"23","author":"Gou","year":"2021","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026102013065745500_cit60","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2026.140117","article-title":"A Novel Imidazolium Ionic Liquid-Functionalized UiO-66-NH2 Catalyst for Efficient Conversion of CO2 into Cyclic Carbonates under Both Solvent-\/Cocatalyst-Free Conditions","volume":"427","author":"Wang","year":"2027","journal-title":"Fuel"}],"container-title":["ACS Applied Materials &amp; Interfaces"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsami.6c13731","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/aamick\/article-pdf\/18\/37\/51058\/68462909\/am-2026-137313.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/aamick\/article-pdf\/18\/37\/51058\/68462909\/am-2026-137313.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,20]],"date-time":"2026-10-20T17:29:13Z","timestamp":1792517353000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/aamick\/article\/18\/37\/51058\/5427173\/Poly-ionic-liquid-Grafted-MOF-Gels-A-Co-catalyst"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,9]]},"references-count":60,"journal-issue":{"issue":"37","published-online":{"date-parts":[[2026,9,9]]},"published-print":{"date-parts":[[2026,9,23]]}},"URL":"https:\/\/doi.org\/10.1021\/acsami.6c13731","relation":{},"ISSN":["1944-8244","1944-8252"],"issn-type":[{"value":"1944-8244","type":"print"},{"value":"1944-8252","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,9]]}}}