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For comparison, a ternary inclusion complex (DPV2+@\u03b2-CD2) was also prepared using a conjugation-extended viologen (DPV\u00b7Cl2). In the solid state, TPV3+@\u03b2-CD3 exhibited fast-response, high-contrast, and reversible photochromic behavior, with a coloration saturation time of only 90 s. Moreover, owing to the macrocyclic confinement effect that effectively suppresses aggregation-caused quenching (ACQ), TPV3+@\u03b2-CD3 displayed strong yellow fluorescence under UV light (\u03bbex = 365 nm) with a quantum yield of 15.71%, whereas the free guest TPV\u00b7Cl3 showed no detectable emission. Electron spin resonance (ESR) spectra and density functional theory (DFT) calculations revealed that the photochromism originates from photoinduced electron transfer from \u03b2-CD to the pyridinium units, generating free radicals. Notably, the fluorescence intensity of the inclusion complex can be dynamically modulated upon light irradiation, with up to 59.8% quenching upon reaching the colored state. Benefiting from these dual photoresponsive properties, TPV3+@\u03b2-CD3 was successfully applied as a colorimetric sensor for UV radiation dosage, as well as for multiple anti-counterfeiting and multilevel information encryption.<\/jats:p>","DOI":"10.1021\/acsami.6c13816","type":"journal-article","created":{"date-parts":[[2026,9,7]],"date-time":"2026-09-07T20:01:43Z","timestamp":1788811303000},"page":"50172-50182","source":"Crossref","is-referenced-by-count":0,"title":["A Quaternary\n                    <b>\u03b2<\/b>\n                    -Cyclodextrin\u2013Viologen Inclusion Complex with Fast Photochromism and Strong Fluorescence for UV Dosimetry and Information Encryption"],"prefix":"10.1021","volume":"18","author":[{"given":"An-Qi","family":"Deng","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Anhui University of Technology , ,","place":["Maanshan, China, 243002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Fang","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Anhui University of Technology , ,","place":["Maanshan, China, 243002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Chen","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Anhui University of Technology , ,","place":["Maanshan, China, 243002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui-Lian","family":"Lin","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Anhui University of Technology , ,","place":["Maanshan, China, 243002"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4787-4701","authenticated-orcid":true,"given":"Jing-Xin","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Anhui University of Technology , ,","place":["Maanshan, China, 243002"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,7]]},"reference":[{"key":"2026092323300419100_cit1","doi-asserted-by":"publisher","first-page":"3350","DOI":"10.1039\/d3cs00698k","article-title":"Recent Advances in Super-Resolution Optical Imaging Based on Aggregation-Induced Emission","volume":"53","author":"Zhu","year":"2024","journal-title":"Chem. 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