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However, conventional elastomers suffer from cryogenic brittleness and high-temperature degradation. Herein, we report a polyurethane, FPPU6-Zn2, with exceptional mechanical strength and toughness across a broad window from \u2013100 to 100 \u00b0C, by integrating two soft segments with multiple hydrogen bonds and metal\u2013ligand coordination. At room temperature, it delivers a tensile strength of 42 MPa and toughness of 191 MJ\/m3; it retains considerable strength at 100 \u00b0C; and at \u2013100 \u00b0C, it achieves a high strength of 62 MPa and toughness of 102 MJ\/m3, together with excellent flexibility even after immersion in liquid nitrogen. The synergy of hydrogen bonding and metal coordination promotes a favorable microphase\u2011separated structure, which underpins the wide\u2011temperature stability and also confers high stress retention and outstanding fatigue resistance under cyclic loading at 200% strain. This work offers a viable design strategy for elastomers that maintain mechanical integrity under harsh conditions, with promising implications for sealing applications in extreme environments.<\/jats:p>","DOI":"10.1021\/acsami.6c13907","type":"journal-article","created":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T20:04:23Z","timestamp":1790366663000},"page":"53994-54005","source":"Crossref","is-referenced-by-count":0,"title":["Polyurethane Elastomers with Superior Mechanical Stability across a Wide Temperature Range"],"prefix":"10.1021","volume":"18","author":[{"given":"Chongyang","family":"Cai","sequence":"first","affiliation":[{"name":"Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences , , ,","place":["Lanzhou, China, 730000"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, China, 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,","place":["Beijing, China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuanbin","family":"Mao","sequence":"additional","affiliation":[{"name":"Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences , , ,","place":["Lanzhou, China, 730000"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, China, 100049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-8252-722X","authenticated-orcid":true,"given":"Jing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences , , ,","place":["Lanzhou, China, 730000"]},{"name":"University of Chinese Academy of Sciences , , ,","place":["Beijing, China, 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