{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T10:50:45Z","timestamp":1791975045365,"version":"4.4.0"},"reference-count":40,"publisher":"American Chemical Society (ACS)","issue":"40","license":[{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T00:00:00Z","timestamp":1790726400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100022963","name":"Key Research and Development Program of Zhejiang Province","doi-asserted-by":"publisher","award":["2024SSYS0050"],"award-info":[{"award-number":["2024SSYS0050"]}],"id":[{"id":"10.13039\/100022963","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004731","name":"Natural Science Foundation of Zhejiang Province","doi-asserted-by":"publisher","award":["LQ24B030015"],"award-info":[{"award-number":["LQ24B030015"]}],"id":[{"id":"10.13039\/501100004731","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,14]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Silicon-based all-solid-state batteries (ASSBs) promise high energy density for next-generation energy storage systems. However, the poor solid\u2212solid contact between silicon (Si) and the solid-state electrolyte (SSE), coupled with interfacial instability during cycling, leads to lithium trapping and parasitic reactions, resulting in a low initial coulombic efficiency (ICE). Herein, we report a solution-assisted in situ polymerization and prelithiation strategy to construct a highly ion-conductive interphase via reductive passivation for Si anodes. Lithium biphenyl replenishes active lithium while inducing the in situ formation of a highly stable hybrid interphase composed of polybiphenyl, lithium bis(trifluoromethanesulfonimide) (LiTFSI), and reductively passivated lithium fluoride. The electrochemically stable and ion-conductive interphase minimizes interfacial ion-transport resistance while suppressing SSE decomposition. The engineered anode delivers an ICE of 100.6% with a high electrode-level reversible capacity of 3215 mAh g\u22121 at the electrode level, enabling an ICE of 96.4% in LiCoO2 full cells (6.2 mAh cm\u22122) with 96.6% capacity retention after 300 cycles at 1 C. The all-solid-state pouch cell demonstrates a high energy density of 313 Wh kg\u22121 with 92.7% capacity retention after 100 cycles. This work underscores the critical role of stable ion-conductive interphase design at Si anodes and provides a viable strategy toward practical high-energy-density ASSBs.<\/jats:p>","DOI":"10.1021\/acsami.6c13954","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T17:02:26Z","timestamp":1790787746000},"page":"54860-54871","source":"Crossref","is-referenced-by-count":0,"title":["Reductively Passivated Ion-Conductive Interphase Enables High-Capacity Silicon Anodes for High-Energy-Density All-Solid-State Batteries"],"prefix":"10.1021","volume":"18","author":[{"given":"Yaru","family":"Li","sequence":"first","affiliation":[{"name":"Yongjiang Laboratory , , ,","place":["Ningbo, Zhejiang, China, 315201"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengjie","family":"Xia","sequence":"additional","affiliation":[{"name":"Eastern Institute of Technology , , ,","place":["Ningbo, China, 315200"]},{"name":"Ningbo Key Laboratory of All-Solid-State Battery , , ,","place":["Ningbo, China, 315200"]},{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, P. R. China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haosheng","family":"Li","sequence":"additional","affiliation":[{"name":"Yongjiang Laboratory , , ,","place":["Ningbo, Zhejiang, China, 315201"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Qian","sequence":"additional","affiliation":[{"name":"Yongjiang Laboratory , , ,","place":["Ningbo, Zhejiang, China, 315201"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiqi","family":"Zhao","sequence":"additional","affiliation":[{"name":"Yongjiang Laboratory , , ,","place":["Ningbo, Zhejiang, China, 315201"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xicheng","family":"Gao","sequence":"additional","affiliation":[{"name":"Yongjiang Laboratory , , ,","place":["Ningbo, Zhejiang, China, 315201"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaming","family":"Zhang","sequence":"additional","affiliation":[{"name":"Xiamen University , , ,","place":["Xiamen, China, 361005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3584-5201","authenticated-orcid":true,"given":"Qiaobao","family":"Zhang","sequence":"additional","affiliation":[{"name":"Xiamen University , , ,","place":["Xiamen, China, 361005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4201-0130","authenticated-orcid":true,"given":"Changhong","family":"Wang","sequence":"additional","affiliation":[{"name":"Eastern Institute of Technology , , ,","place":["Ningbo, China, 315200"]},{"name":"Ningbo Key Laboratory of All-Solid-State Battery , , ,","place":["Ningbo, China, 315200"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8029-5595","authenticated-orcid":true,"given":"Ning","family":"Lin","sequence":"additional","affiliation":[{"name":"Yongjiang Laboratory , , ,","place":["Ningbo, Zhejiang, China, 315201"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,30]]},"reference":[{"issue":"4","key":"2026101406071370200_cit1","doi-asserted-by":"publisher","first-page":"2009","DOI":"10.1021\/acs.chemrev.4c00584","article-title":"Characterizing Electrode Materials and Interfaces in Solid-State Batteries","volume":"125","author":"Alsa\u00e7","year":"2025","journal-title":"Chem. 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