{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T19:04:20Z","timestamp":1789585460563,"version":"build-2803163510"},"reference-count":47,"publisher":"American Chemical Society (ACS)","issue":"36","license":[{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T00:00:00Z","timestamp":1788393600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"name":"Fluorine-19 fund"},{"name":"National Science Foundation (MRI program)"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,9,16]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The development of advanced energetic materials that balance high performance with synthetic accessibility remains a formidable challenge in aerospace and defense applications. Here, we report a simple two-step synthetic strategy to access two distinct yet complementary energetic platforms, a solvent-free sodium-based energetic framework (3) and a hydrazinium-based hypergolic salt (4), from a common precursor. This design leverages an intrinsic fuel\u2013oxidizer motif, integrating gem-dinitro oxidizing units with hydrazine-based fuel fragments to achieve internal redox balance and enhanced energetic output. Compound 3 exhibits a high density of 1.83 g cm\u20133 and good thermal stability (182 \u00b0C), while compound 4 delivers good detonation performance (VOD = 8831 m s\u20131, DP = 31.8 GPa) together with remarkable hypergolic activity toward white fuming nitric acid, achieving an ignition delay of only 18 ms. Hirshfeld surface analysis further reveals that the solid-state architecture of 4 is stabilized by an extensive hydrogen-bonding network, with O\u2013H interactions contributing 70% of the surface contacts, highlighting the role of directed intermolecular packing in its energetic behavior. This work establishes a cost-effective design paradigm that reconciles synthetic simplicity with high-performance energetic metrics, providing a versatile platform for next-generation ignition-responsive energetic materials.<\/jats:p>","DOI":"10.1021\/acsami.6c14655","type":"journal-article","created":{"date-parts":[[2026,9,3]],"date-time":"2026-09-03T21:39:03Z","timestamp":1788471543000},"page":"49261-49271","source":"Crossref","is-referenced-by-count":0,"title":["Two-Step Access to High-Energy Materials via Intrinsic Fuel\u2013Oxidizer Design"],"prefix":"10.1021","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8434-1504","authenticated-orcid":true,"given":"Abhishek Kumar","family":"Yadav","sequence":"first","affiliation":[{"name":"University of Idaho , , , ,","place":["Moscow, Idaho, United States, 83844-2343"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2760-769X","authenticated-orcid":true,"given":"Richard J.","family":"Staples","sequence":"additional","affiliation":[{"name":"Michigan State University , , , ,","place":["East Lansing, Michigan, United States, 48824"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8622-4897","authenticated-orcid":true,"given":"Jean\u2019ne M.","family":"Shreeve","sequence":"additional","affiliation":[{"name":"University of Idaho , , , ,","place":["Moscow, Idaho, United States, 83844-2343"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,3]]},"reference":[{"key":"2026091614065421200_cit1","doi-asserted-by":"publisher","DOI":"10.1515\/9783110739503\/HTML","volume-title":"Chemistry of High Energy Materials","author":"Klap\u00f6tke","edition":"7"},{"issue":"49","key":"2026091614065421200_cit2","doi-asserted-by":"publisher","DOI":"10.1126\/SCIADV.ABB1899","article-title":"Designing High-Performance Hypergolic Propellants Based on Materials Genome","volume":"6","author":"Yuan","year":"2020","journal-title":"Sci. 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