{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T16:44:22Z","timestamp":1792601062923,"version":"4.5.0"},"reference-count":35,"publisher":"American Chemical Society (ACS)","license":[{"start":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T00:00:00Z","timestamp":1792540800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T00:00:00Z","timestamp":1792540800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T00:00:00Z","timestamp":1792540800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100016350","name":"Sichuan Provincial Administration of Traditional Chinese Medicine","doi-asserted-by":"publisher","award":["Q115723S02001"],"award-info":[{"award-number":["Q115723S02001"]}],"id":[{"id":"10.13039\/501100016350","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["2682023ZTPY064"],"award-info":[{"award-number":["2682023ZTPY064"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","award":["2682025CX002"],"award-info":[{"award-number":["2682025CX002"]}],"id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22605300"],"award-info":[{"award-number":["22605300"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Covalent organic frameworks (COFs) have attracted much attention for their potential in photocatalytic hydrogen peroxide (H2O2) production. However, traditional COFs often suffer from sluggish charge transfer kinetics and a lack of highly electron-localized sites for O2 adsorption, leading to inefficient photocatalytic activity. Herein, we report a pore-channel electronic engineering strategy that introduces highly electron-localized cores into the pore channels of COFs by the regulation of heterocyclic pendants. The cores located in the channel of COFs acted as electron-rich active sites, enabling enhanced charge separation for photocatalytic H2O2 production. The polar furan groups were introduced onto the cores, further forming a powerful built-in electric field and hydrogen bond network within the channels, thereby accelerating the transport of electrons and protons. The furan-grafted COF (O-COF) showed a photocatalytic H2O2 production rate of 15,378 \u00b5mol h\u20131 g\u20131, with a yield 1.5\u20132.4 times higher than that of its counterparts. This work provides a valuable reference for the precise electronic regulation of pore channels in COFs to enhance photocatalytic performances.<\/jats:p>","DOI":"10.1021\/acsami.6c15070","type":"journal-article","created":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T16:02:22Z","timestamp":1792598542000},"source":"Crossref","is-referenced-by-count":0,"title":["Pendant Engineering of Covalent Organic Frameworks for Photocatalytic Hydroperoxide Production"],"prefix":"10.1021","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9349-9562","authenticated-orcid":true,"given":"Zhu","family":"Gao","sequence":"first","affiliation":[{"name":"Southwest Jiaotong University , , , ,","place":["Chengdu, Sichuan, China, 610031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhenglin","family":"Li","sequence":"additional","affiliation":[{"name":"Southwest Jiaotong University , , , ,","place":["Chengdu, Sichuan, China, 610031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zeyu","family":"Sun","sequence":"additional","affiliation":[{"name":"Southwest Jiaotong University , , , ,","place":["Chengdu, Sichuan, China, 610031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan","family":"Xu","sequence":"additional","affiliation":[{"name":"Southwest Jiaotong University , , , ,","place":["Chengdu, Sichuan, China, 610031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Zhang","sequence":"additional","affiliation":[{"name":"Southwest Jiaotong University , , , ,","place":["Chengdu, Sichuan, China, 610031"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8712-0512","authenticated-orcid":true,"given":"Guipeng","family":"Yu","sequence":"additional","affiliation":[{"name":"Central South University , , , ,","place":["Changsha, Hunan, China, 410083"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8031-0532","authenticated-orcid":true,"given":"Cuijuan","family":"Wang","sequence":"additional","affiliation":[{"name":"Southwest Jiaotong University , , , ,","place":["Chengdu, Sichuan, China, 610031"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,21]]},"reference":[{"issue":"4","key":"2026102112021158300_cit1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202416879","article-title":"Hydroxyl Radical Mediated Heterogeneous Photocatalytic Baeyer\u2013Villiger Oxidation over Covalent Triazine\/Heptazine-Based Frameworks","volume":"64","author":"Tang","year":"2025","journal-title":"Angew. 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