{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T16:54:34Z","timestamp":1791478474542,"version":"4.3.4"},"reference-count":52,"publisher":"American Chemical Society (ACS)","license":[{"start":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T00:00:00Z","timestamp":1791417600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100000165","name":"Division of Chemistry","doi-asserted-by":"publisher","award":["1531834"],"award-info":[{"award-number":["1531834"]}],"id":[{"id":"10.13039\/100000165","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000078","name":"Division of Materials Research","doi-asserted-by":"publisher","award":["2411680"],"award-info":[{"award-number":["2411680"]}],"id":[{"id":"10.13039\/100000078","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Implementing the advantages of preceramic polymers in modern ultra-high temperature ceramic (UHTC) manufacturing remains a significant challenge due to the limited preceramic polymer chemistry, which often is not fully amenable to ceramic processing conditions. Here, we present a solvent-activated, zirconocene dichloride-mediated ring-opening of poly(glycidyl methacrylate) that generates a zirconium-rich crosslinked network (X-mPGMA), allowing the metallopolymer to function both as a ZrC nanoparticle precursor and a colloidal processing gelcasting system. We utilize this metallopolymer gel chemistry to cast and consolidate near-net-shape ZrB2 green bodies. After carbothermal reduction and sintering, the crosslinked preceramic network yields a distinct ZrC phase that conformally coats the ZrB2 particles. Owing to the conformal ZrC interphase formed in situ, a finer ZrB2 microstructure was revealed, even under high-temperature sintering conditions. We further employed two gelcasting variants to near-net-shape and consolidate ZrB2 with and without added ZrC nanoparticles. Compared with the X-mPGMA-derived ZrB2 composites, these variants showed significant grain growth of ZrB2 after sintering, underscoring the effectiveness of in situ ZrC formation. This work highlights a powerful chemical processing strategy for effectively implementing multi-purpose, topologically distinct preceramic polymer-derived interphases in modern UHTC processing.<\/jats:p>","DOI":"10.1021\/acsami.6c15224","type":"journal-article","created":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T16:02:52Z","timestamp":1791475372000},"source":"Crossref","is-referenced-by-count":0,"title":["Conformal ZrC Interphase for ZrB2 Ceramics from a Solvent-Activated Metallopolymer"],"prefix":"10.1021","author":[{"given":"Brendan","family":"Whitfield","sequence":"first","affiliation":[{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]},{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui-Chun June","family":"Yu","sequence":"additional","affiliation":[{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]},{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]},{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Allie","family":"Ahn","sequence":"additional","affiliation":[{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]},{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Carolina","family":"Tallon","sequence":"additional","affiliation":[{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]},{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]},{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6778-0625","authenticated-orcid":true,"given":"Guoliang","family":"Liu","sequence":"additional","affiliation":[{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]},{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]},{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]},{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]},{"name":"Virginia Tech , , , ,","place":["Blacksburg, Virginia, United States, 24061"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,8]]},"reference":[{"key":"2026100812022137200_cit1","doi-asserted-by":"publisher","first-page":"94","DOI":"10.1016\/j.scriptamat.2016.10.018","article-title":"Ultra-high temperature ceramics: Materials for extreme environments","volume":"129","author":"Fahrenholtz","year":"2017","journal-title":"Scr. 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