{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T08:51:31Z","timestamp":1791449491455,"version":"4.3.3"},"reference-count":46,"publisher":"American Chemical Society (ACS)","license":[{"start":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T00:00:00Z","timestamp":1791417600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T00:00:00Z","timestamp":1791417600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T00:00:00Z","timestamp":1791417600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100003392","name":"Natural Science Foundation of Fujian Province","doi-asserted-by":"publisher","award":["2025H6025"],"award-info":[{"award-number":["2025H6025"]}],"id":[{"id":"10.13039\/501100003392","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003392","name":"Natural Science Foundation of Fujian Province","doi-asserted-by":"publisher","award":["2025J09036"],"award-info":[{"award-number":["2025J09036"]}],"id":[{"id":"10.13039\/501100003392","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52472150"],"award-info":[{"award-number":["52472150"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["62205063"],"award-info":[{"award-number":["62205063"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>The rapid development of the Internet of Things and artificial intelligence has sharply increased the demand for secure, low-cost, and scalable anticounterfeiting technologies. Physical unclonable functions (PUFs) offer intrinsic protection by converting stochastic material variations into unique identifiers, but their practical implementation is often limited by complex fabrication, toxic luminophores, and low information complexity arising from single-channel readout. Here, we develop a copper(I) iodide cluster\u2013poly(methyl methacrylate) fluorescent PUF through a single ambient coating step. Nonequilibrium solvent evaporation and polymer solidification generate randomly distributed yellow-emissive microdomains together with three-dimensional surface relief, while the cluster and polymer concentrations regulate domain coverage, intensity, and morphology without prescribing their microscopic arrangement. Binary fluorescence keys exhibit a mean interlabel Hamming distance of 0.49935 and an intralabel value of 0.00219. Incorporating discretized surface height further enables multivalued fluorescence\u2013topography encoding. The solution-processable composite is compatible with spin coating, spray coating, transfer printing, and direct writing, allowing stochastic fingerprints to be integrated into planar, flexible, and curved objects for diverse anticounterfeiting scenarios. The fingerprints remain readable after storage, water exposure, thermal treatment, and ultraviolet irradiation. Deep-learning retrieval combined with local-feature matching enables hierarchical identification and physical verification. This work provides a simple, lead-free route to multimodal PUFs for scalable anticounterfeiting and authentication.<\/jats:p>","DOI":"10.1021\/acsami.6c15664","type":"journal-article","created":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T08:01:47Z","timestamp":1791446507000},"source":"Crossref","is-referenced-by-count":0,"title":["One-Step Stochastically-Assembled Copper(I) Iodide Cluster for Multimodal Physically Unclonable Functions"],"prefix":"10.1021","author":[{"given":"Ning","family":"Liu","sequence":"first","affiliation":[{"name":"Fuzhou University of International Studies and Trade , , ,","place":["Fuzhou, China, 350202"]},{"name":"Fujian Normal University , , ,","place":["Fuzhou, China, 350117"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yehan","family":"Zeng","sequence":"additional","affiliation":[{"name":"Fujian Normal University , , ,","place":["Fuzhou, China, 350117"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kejia","family":"You","sequence":"additional","affiliation":[{"name":"Fujian Normal University , , ,","place":["Fuzhou, China, 350117"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yilu","family":"Chen","sequence":"additional","affiliation":[{"name":"Fujian Normal University , , ,","place":["Fuzhou, China, 350117"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guotao","family":"Sun","sequence":"additional","affiliation":[{"name":"Fujian Normal University , , ,","place":["Fuzhou, China, 350117"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiayu","family":"Chen","sequence":"additional","affiliation":[{"name":"Fujian Normal University , , ,","place":["Fuzhou, China, 350117"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shouzhao","family":"Zhan","sequence":"additional","affiliation":[{"name":"Fujian Normal University , , ,","place":["Fuzhou, China, 350117"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuan","family":"Guo","sequence":"additional","affiliation":[{"name":"Fujian Normal University , , ,","place":["Fuzhou, China, 350117"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tailiang","family":"Guo","sequence":"additional","affiliation":[{"name":"Fuzhou University , , ,","place":["Fuzhou, China, 350116"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8809-0845","authenticated-orcid":true,"given":"Yang","family":"Liu","sequence":"additional","affiliation":[{"name":"Fujian Normal University , , ,","place":["Fuzhou, China, 350117"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6074-2490","authenticated-orcid":true,"given":"Fushan","family":"Li","sequence":"additional","affiliation":[{"name":"Fuzhou University , , ,","place":["Fuzhou, China, 350116"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,8]]},"reference":[{"key":"2026100804013989600_cit1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202502059","article-title":"Designing Physical Unclonable Functions From Optically Active Materials","volume":"37","author":"Klausen","year":"2025","journal-title":"Adv. Mater."},{"key":"2026100804013989600_cit2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-017-0031","article-title":"Physical Unclonable Functions Generated Through Chemical Methods for Anti-Counterfeiting","volume":"1","author":"Arppe","year":"2017","journal-title":"Nat. Rev. Chem."},{"issue":"1","key":"2026100804013989600_cit3","doi-asserted-by":"publisher","DOI":"10.1016\/j.nantod.2021.101324","article-title":"Triple-layer Unclonable Anti-counterfeiting Enabled by Huge-Encoding Capacity Algorithm and Artificial Intelligence Authentication","volume":"41","author":"Wang","year":"2021","journal-title":"Nano Today"},{"issue":"1","key":"2026100804013989600_cit4","doi-asserted-by":"publisher","first-page":"77","DOI":"10.1021\/acsmaterialslett.9b00039","article-title":"Pattern Memory Surface (PMS) with Dynamic Wrinkles for Unclonable Anticounterfeiting","volume":"1","author":"Xie","year":"2019","journal-title":"ACS Mater. Lett."},{"issue":"1","key":"2026100804013989600_cit5","doi-asserted-by":"publisher","first-page":"2185","DOI":"10.1038\/s41467-023-37588-5","article-title":"Random fractal-enabled physical unclonable functions with dynamic AI authentication","volume":"14","author":"Sun","year":"2023","journal-title":"Nat. Commun."},{"issue":"1","key":"2026100804013989600_cit6","doi-asserted-by":"publisher","first-page":"2409","DOI":"10.1038\/s41467-019-10406-7","article-title":"Inkjet-printed unclonable quantum dot fluorescent anti-counterfeiting labels with artificial intelligence authentication","volume":"10","author":"Liu","year":"2019","journal-title":"Nat. Commun."},{"issue":"20","key":"2026100804013989600_cit7","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202305876","article-title":"Fine Optimization of Colloidal Photonic Crystal Structural Color for Physically Unclonable Multiplex Encryption and Anti-Counterfeiting","volume":"11","author":"Gao","year":"2024","journal-title":"Adv. Sci."},{"key":"2026100804013989600_cit8","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202102542","article-title":"Chaotic Organic Crystal Phosphorescent Patterns for Physical Unclonable Functions","volume":"33","author":"Im","year":"2021","journal-title":"Adv. Mater."},{"issue":"9","key":"2026100804013989600_cit9","doi-asserted-by":"publisher","first-page":"1027","DOI":"10.1038\/s41565-023-01405-3","article-title":"An all-in-one Nanoprinting Approach for the Synthesis of a Nanofilm Library for Unclonable Anti-Counterfeiting Applications","volume":"18","author":"Zhang","year":"2023","journal-title":"Nat. Nanotechnol."},{"issue":"1","key":"2026100804013989600_cit10","doi-asserted-by":"publisher","first-page":"7592","DOI":"10.1038\/s41467-024-51756-1","article-title":"Random laser ablated tags for anticounterfeiting purposes and towards physically unclonable functions","volume":"15","author":"Gandla","year":"2024","journal-title":"Nat. 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J."},{"issue":"1","key":"2026100804013989600_cit14","doi-asserted-by":"publisher","first-page":"502","DOI":"10.1038\/s41467-024-55646-4","article-title":"Bright and Stable Anti-counterfeiting Devices with Independent Stochastic Processes Covering Multiple Length Scales","volume":"16","author":"Zhang","year":"2025","journal-title":"Nat. Commun."},{"issue":"1","key":"2026100804013989600_cit15","doi-asserted-by":"publisher","first-page":"245","DOI":"10.1038\/s41377-023-01285-1","article-title":"Voxelated opto-Physically Unclonable Functions via Irreplicable Wrinkles","volume":"12","author":"Kim","year":"2023","journal-title":"Light Sci. Appl."},{"issue":"6","key":"2026100804013989600_cit16","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202208151","article-title":"Synthesis of MAPbBr3-Polymer Composite Films by Photolysis of DMF: Toward Transparent and Flexible Optical Physical Unclonable Functions (PUFs) with Hierarchical Multilevel Complexity","volume":"35","author":"Minh","year":"2023","journal-title":"Adv. Mater."},{"issue":"3","key":"2026100804013989600_cit17","doi-asserted-by":"publisher","first-page":"5254","DOI":"10.1021\/acsami.4c20440","article-title":"Biomimetic Fingerprint-like Unclonable Optical Anticounterfeiting System with Selectively In Situ-Synthesized Perovskite Quantum Dots Embedded in Spontaneous-Phase-Separated Polymers","volume":"17","author":"You","year":"2025","journal-title":"ACS Appl. Mater. 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