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Existing anti-glare or radiative cooling coatings typically either reduce visible transmittance or fail to combine high haze with high infrared emissivity. We have developed a room-temperature-curing FPHS coating composed of polyethoxysiloxane (PEOS), hydroxyl silicone oil, and 3,3,3-(trifluoropropyl)trimethoxysilane (TTMS). Utilizing in-situ nanoparticle formation and microphase separation technology, this coating achieves a visible light transmittance of 90.43%, a haze of 84.64%, and an emissivity of 94.06% within the 8\u201313 \u03bcm atmospheric window. These unique optical properties enable a maximum daytime temperature reduction of 14.6 \u00b0C, while the low-surface-energy surface ensures self-cleaning and dust-repellent properties. When coated onto photovoltaic panels, the FPHS coating reduces operational temperatures of photovoltaic modules, elevates short-circuit current, and improves overall power conversion efficiency. It delivers a scalable, zero-energy strategy to simultaneously realize glare suppression, privacy modulation, and passive radiative cooling for transparent building envelopes and optoelectronic devices.<\/jats:p>","DOI":"10.1021\/acsami.6c15726","type":"journal-article","created":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T23:02:27Z","timestamp":1792018947000},"source":"Crossref","is-referenced-by-count":0,"title":["Highly Transparent and Haze Passive Daytime Radiative Cooling Organosiloxane Coatings via a Controlled Microphase Separation Process"],"prefix":"10.1021","author":[{"given":"Lele","family":"Zhang","sequence":"first","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Weizhen","family":"Zhang","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenqian","family":"He","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qian","family":"Yan","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yu","family":"Cheng","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuhua","family":"Tu","sequence":"additional","affiliation":[{"name":"Westlake University , , ,","place":["Hangzhou, China, 310024"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7228-117X","authenticated-orcid":true,"given":"Jie","family":"Feng","sequence":"additional","affiliation":[{"name":"Zhejiang University of Technology , , ,","place":["Hangzhou, China, 310014"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,15]]},"reference":[{"issue":"52","key":"2026101419022030500_cit1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202510833","article-title":"Colloidal Opaline Composites as Throughput-Scalable, Fully Transparent, and Color-Tunable Radiative Cooling Exterior Films for Outdoor Photovoltaics","volume":"35","author":"Cho","year":"2025","journal-title":"Adv. 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