{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T12:53:22Z","timestamp":1791982402048,"version":"4.4.0"},"reference-count":74,"publisher":"American Chemical Society (ACS)","issue":"40","license":[{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T00:00:00Z","timestamp":1790553600000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100004032","name":"Jilin University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004032","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011789","name":"Department of Science and Technology of Jilin Province","doi-asserted-by":"publisher","award":["20230508176RC"],"award-info":[{"award-number":["20230508176RC"]}],"id":[{"id":"10.13039\/501100011789","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,14]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Covalent organic framework (COF)\/graphene hybrids are promising electrode materials for next-generation supercapacitors, yet critical challenges persist: the structure\u2013property relationship of the molecular structure of COFs governing the COF\/graphene interface remains poorly understood. Herein, we employ electrochemically exfoliated graphene (EG) as a soft template that combines high crystalline quality with solution processability to direct the uniform in situ growth of structurally distinct COFs along its two-dimensional (2D) basal plane. This strategy ensures high composite conductivity, promotes efficient charge transfer via \u03c0\u2013\u03c0 interactions between graphene and COF layers, and enhances the accessibility of redox-active sites, which are key aspects for achieving superior electrochemical performance. We synthesized four different COFs: Tp-TAPT, Tp-TAPB, Tb-TAPT, and Tb-TAPB, using 2,4,6-triformylphloroglucinol (Tp) or 1,3,5-triformylbenzene (Tb) with 2,4,6-tris(4-aminophenyl)-1,3,5-triazine (TAPT) or 1,3,5-tris(4-aminophenyl)benzene (TAPB), which are systematically constructed to introduce two structural variables: \u03b2-ketoenamine versus imine linkages and triazine versus non-triazine aromatic units. They were subsequently grown in situ on EG to achieve the corresponding hybrids (denoted Tp-TAPT@G, Tb-TAPT@G, Tp-TAPB@G, and Tb-TAPB@G, respectively). Among them, Tp-TAPT@G, which combines \u03b2-ketoenamine and triazine units, exhibits pronounced multiple redox features, favorable interfacial \u03c0\u2013\u03c0 interactions with EG, and a more uniform and continuous 2D growth morphology. Tp-TAPT@G delivers a volumetric capacitance of 261.31 F\/cm3 at a current density of 0.3 mA\/cm2 and retains 76.38% of this value at 5.0 mA\/cm2, portraying excellent rate capability. Moreover, a planar supercapacitor device assembled from this composite demonstrates outstanding high-rate performance, underscoring its promise for fast-charging applications. This study elucidates how the COF structure regulates interfacial behavior in COF\/graphene composites, providing a foundation for the rational design of high-performance energy storage materials.<\/jats:p>","DOI":"10.1021\/acsami.6c16250","type":"journal-article","created":{"date-parts":[[2026,9,28]],"date-time":"2026-09-28T21:01:58Z","timestamp":1790629318000},"page":"55358-55370","source":"Crossref","is-referenced-by-count":0,"title":["Interfacial Engineering of Redox-Active Covalent Organic Frameworks\/Graphene Hybrids for High-Performance Supercapacitors"],"prefix":"10.1021","volume":"18","author":[{"given":"Jiashu","family":"Li","sequence":"first","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Zhou","sequence":"additional","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Leijing","family":"Liu","sequence":"additional","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhaoyang","family":"Liu","sequence":"additional","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5766-8050","authenticated-orcid":true,"given":"Wenjing","family":"Tian","sequence":"additional","affiliation":[{"name":"Jilin University , , ,","place":["Changchun, China, 130012"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,28]]},"reference":[{"issue":"1","key":"2026101408075160700_cit1","doi-asserted-by":"publisher","first-page":"1475","DOI":"10.1038\/ncomms2446","article-title":"Scalable Fabrication of High-Power Graphene Micro-Supercapacitors for Flexible and On-Chip Energy Storage","volume":"4","author":"El-Kady","year":"2013","journal-title":"Nat. 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