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Here, we treat bulk Li+ transport, interfacial desolvation, and solid electrolyte interphase (SEI) transport as sequential and coupled kinetic processes with a common molecular origin in the Li+ primary solvation sheath. Anion coordination strength is identified as a unified molecular descriptor linking solvation structure, transport kinetics, interfacial reactions, and SEI evolution. Accordingly, electrolyte strategies, including high-concentration systems, localized high-concentration electrolytes, composition tuning, and anion design, can be viewed as approaches to regulate coordination strength. This perspective provides a descriptor-guided strategy for rational electrolyte design toward safe and high-performance fast charging at low temperatures for graphite-anode lithium-ion batteries with suppressed lithium plating.<\/jats:p>","DOI":"10.1021\/acsami.6c16331","type":"journal-article","created":{"date-parts":[[2026,10,14]],"date-time":"2026-10-14T19:02:06Z","timestamp":1792004526000},"source":"Crossref","is-referenced-by-count":0,"title":["Anion Coordination Strength: A Unified Descriptor for Low-Temperature Fast-Charging Performance of Lithium-Ion Batteries"],"prefix":"10.1021","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-9566-3929","authenticated-orcid":true,"given":"Kezhuo","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory of Electrochemical Energy Safety, Ministry of Emergency Management , ,","place":["Beijing, China, 102402"]},{"name":"XYZ Storage Technology Co., Ltd. , ,","place":["Beijing, China, 102402"]},{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]},{"name":"State Key Laboratory of Chemical Engineering and Low-Carbon Technology , ,","place":["Beijing, China, 100084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Changjian","family":"Li","sequence":"additional","affiliation":[{"name":"Tsinghua University , , ,","place":["Beijing, China, 100084"]},{"name":"State Key Laboratory of Chemical Engineering and Low-Carbon Technology , ,","place":["Beijing, China, 100084"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Sun","sequence":"additional","affiliation":[{"name":"Key Laboratory of Electrochemical Energy Safety, Ministry of Emergency Management , ,","place":["Beijing, China, 102402"]},{"name":"XYZ Storage Technology Co., Ltd. , ,","place":["Beijing, China, 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