{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T03:46:00Z","timestamp":1792122360818,"version":"4.4.0"},"reference-count":56,"publisher":"American Chemical Society (ACS)","license":[{"start":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T00:00:00Z","timestamp":1791763200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T00:00:00Z","timestamp":1791763200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T00:00:00Z","timestamp":1791763200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001412","name":"Council of Scientific and Industrial Research, India","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001412","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001843","name":"Anusandhan National Research Foundation","doi-asserted-by":"publisher","award":["ANRF\/ARG\/2025\/002529\/CS"],"award-info":[{"award-number":["ANRF\/ARG\/2025\/002529\/CS"]}],"id":[{"id":"10.13039\/501100001843","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100018882","name":"Institute for Materials Research, Tohoku University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100018882","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP25K22264"],"award-info":[{"award-number":["JP25K22264"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP26H02280"],"award-info":[{"award-number":["JP26H02280"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP26K01468"],"award-info":[{"award-number":["JP26K01468"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["JP26K22760"],"award-info":[{"award-number":["JP26K22760"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Gas-responsive magnetic response arising from spin-crossover (SCO) phenomena is rare yet highly attractive for molecular sensing and spintronics. However, it remains unclear how gas uptake influences SCO behaviour when the two phenomena occur in separate temperature regimes. Herein, we report a strong influence of CO2 adsorption on the SCO behaviour of a Hofmann clathrate, [FeII(epac)2(PtII(CN)4)]\u00b7nEtOH (1\u00b7nEtOH, n \u2264 2), despite the two effects occurring at different temperatures. Complex (1\u00b72EtOH) exhibits highly cooperative SCO with a hysteresis width \u223c65 K and preserves the framework topology upon desolvation (1). However, hysteresis reduces to 30 K in the guest-free phase (1), underscoring the critical role of lattice solvent in mediating cooperativity. Complex (1) selectively adsorbs CO2 through a gate-opening mechanism at temperatures substantially higher than the SCO region. Despite this mismatch in operating temperatures, increasing CO2 loading progressively stabilizes the low-spin state and shifts the transition temperature (Teq) by \u223c20 K. These findings support a delayed guest-mediated coupling mechanism where CO2 first enters the framework at elevated temperatures and subsequently modifies spin-state energetics only after immobilization within the host lattice at lower temperatures. This study establishes that gas adsorption and SCO need not occur within overlapping temperatures to remain strongly coupled.<\/jats:p>","DOI":"10.1021\/acsami.6c16795","type":"journal-article","created":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T02:01:32Z","timestamp":1791770492000},"source":"Crossref","is-referenced-by-count":0,"title":["Coupling the Spin State Switching and CO2 Adsorption Operating at Different Temperatures in a Breathing Metal\u2013Organic Framework"],"prefix":"10.1021","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-2911-3311","authenticated-orcid":true,"given":"Bhart","family":"Kumar","sequence":"first","affiliation":[{"name":"Indian Institute of Science Education and Research Bhopal , , Bhopal By-Pass Road , , ,","place":["Bhopal, MP, India, 462066"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wataru","family":"Kosaka","sequence":"additional","affiliation":[{"name":"Tohoku University , , 2-1-1 Katahira, Aoba-ku , ,","place":["Sendai, Japan, 980-8577"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0097-6113","authenticated-orcid":true,"given":"Subhadip","family":"Roy","sequence":"additional","affiliation":[{"name":"The ICFAI University Tripura , , Mohanpur, Agartala , , ,","place":["Kamalghat, Tripura, India, 799210"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hitoshi","family":"Miyasaka","sequence":"additional","affiliation":[{"name":"Tohoku University , , 2-1-1 Katahira, Aoba-ku , ,","place":["Sendai, Japan, 980-8577"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1584-6258","authenticated-orcid":true,"given":"Sanjit","family":"Konar","sequence":"additional","affiliation":[{"name":"Indian Institute of Science Education and Research Bhopal , , Bhopal By-Pass Road , , ,","place":["Bhopal, MP, India, 462066"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,10,12]]},"reference":[{"issue":"6","key":"2026101122012482000_cit1","doi-asserted-by":"publisher","first-page":"419","DOI":"10.1039\/b003504l","article-title":"Spin crossover phenomena in Fe (II) complexes","volume":"29","author":"G\u00fctlich","year":"2000","journal-title":"Chem. Soc. Rev."},{"issue":"1","key":"2026101122012482000_cit2","doi-asserted-by":"publisher","first-page":"342","DOI":"10.3762\/bjoc.9.39","article-title":"Spin state switching in iron coordination compounds","volume":"9","author":"G\u00fctlich","year":"2013","journal-title":"Beilstein J. Org. Chem."},{"issue":"10","key":"2026101122012482000_cit3","doi-asserted-by":"publisher","first-page":"2880","DOI":"10.1039\/C4CS00376D","article-title":"Spin crossover with thermal hysteresis: practicalities and lessons learnt","volume":"44","author":"Brooker","year":"2015","journal-title":"Chem. Soc. Rev."},{"issue":"24","key":"2026101122012482000_cit4","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202008141","article-title":"Spin-crossover molecules on surfaces: From isolated molecules to ultrathin films","volume":"33","author":"Kipgen","year":"2021","journal-title":"Adv. Mater."},{"issue":"14","key":"2026101122012482000_cit5","doi-asserted-by":"publisher","first-page":"7502","DOI":"10.1002\/anie.201911256","article-title":"Sublimable spin-crossover complexes: From spin-state switching to molecular devices","volume":"60","author":"Kumar","year":"2021","journal-title":"Angew. Chem. Int. Ed."},{"key":"2026101122012482000_cit6","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2025.216628","article-title":"Optical properties and photonic applications of molecular spin-crossover materials","volume":"535","author":"Ridier","year":"2025","journal-title":"Coord. Chem. Rev."},{"issue":"17","key":"2026101122012482000_cit7","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202000447","article-title":"The Interplay between Surface Plasmon Resonance and Switching Properties in Gold@Spin Crossover Nanocomposites","volume":"30","author":"Palluel","year":"2020","journal-title":"Adv. Funct. Mater."},{"key":"2026101122012482000_cit8","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202522073","article-title":"4D-Printed Spin Crossover Metamaterials with Giant Programmable Positive or Negative Thermal Expansion","volume":"38","author":"Trapali","year":"2026","journal-title":"Adv. Mater."},{"issue":"1","key":"2026101122012482000_cit9","doi-asserted-by":"publisher","first-page":"3611","DOI":"10.1038\/s41467-020-17362-7","article-title":"Unprecedented switching endurance affords for high-resolution surface temperature mapping using a spin-crossover film","volume":"11","author":"Ridier","year":"2020","journal-title":"Nat. Commun."},{"issue":"25","key":"2026101122012482000_cit10","doi-asserted-by":"publisher","first-page":"12830","DOI":"10.1039\/D5TC01390A","article-title":"Spin crossover-driven thermochromic temperature sensor for monitoring heat transfer via image analysis","volume":"13","author":"Kumar","year":"2025","journal-title":"J. Mater. Chem. C"},{"issue":"10","key":"2026101122012482000_cit11","doi-asserted-by":"publisher","DOI":"10.1002\/andp.201900076","article-title":"Molecular spin crossover materials: Review of the lattice dynamical properties","volume":"531","author":"Moln\u00e1r","year":"2019","journal-title":"Ann. Phys."},{"issue":"5347","key":"2026101122012482000_cit12","doi-asserted-by":"publisher","first-page":"44","DOI":"10.1126\/science.279.5347.44","article-title":"Spin-transition polymers: from molecular materials toward memory devices","volume":"279","author":"Kahn","year":"1998","journal-title":"Science"},{"issue":"76","key":"2026101122012482000_cit13","doi-asserted-by":"publisher","first-page":"14701","DOI":"10.1039\/D5CC02871J","article-title":"Dual magnetic bistability with significant coercivity in a photo-responsive 1D Fe2Fe cyanide chain","volume":"61","author":"Kharel","year":"2025","journal-title":"Chem. Commun."},{"issue":"18","key":"2026101122012482000_cit14","doi-asserted-by":"publisher","first-page":"7884","DOI":"10.1039\/D4SC05587J","article-title":"[2 + 2] Photocyclization converts thermally induced spin crossover effect into \u201chidden hysteresis\u201d one","volume":"16","author":"Ka\u017amierczak","year":"2025","journal-title":"Chem. Sci."},{"issue":"34","key":"2026101122012482000_cit15","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202208886","article-title":"Spin-Crossover Tuned Rotation of Pyrazolyl Rings in a 2D Iron (II) Complex towards Synergetic Magnetic and Dielectric Transitions","volume":"61","author":"Wen","year":"2022","journal-title":"Angew. Chem. Int. Ed."},{"issue":"1","key":"2026101122012482000_cit16","doi-asserted-by":"publisher","first-page":"3961","DOI":"10.1038\/s41467-024-48425-8","article-title":"Integrating spin-dependent emission and dielectric switching in FeII catenated metal-organic frameworks","volume":"15","author":"Wu","year":"2024","journal-title":"Nat. Commun."},{"issue":"24","key":"2026101122012482000_cit17","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202202253","article-title":"Concomitant Thermochromic and Phase-Change Effect in a Switchable Spin Crossover Material for Efficient Passive Control of Day and Night Temperature Fluctuations","volume":"9","author":"Resines-Urien","year":"2022","journal-title":"Adv. Sci."},{"issue":"42","key":"2026101122012482000_cit18","doi-asserted-by":"publisher","first-page":"18632","DOI":"10.1002\/anie.202006453","article-title":"Thermochromic Meltable Materials with Reverse Spin Transition Controlled by Chemical Design","volume":"59","author":"Valverde-Mu\u00f1oz","year":"2020","journal-title":"Angew. Chem. Int. Ed."},{"issue":"20","key":"2026101122012482000_cit19","doi-asserted-by":"publisher","first-page":"6750","DOI":"10.1039\/D3TC00064H","article-title":"Competitive electronic and steric effects in the spin-state modulation of a 3D-Hofmann framework and its extension towards the nanoscale","volume":"11","author":"Mondal","year":"2023","journal-title":"J. Mater. Chem. C"},{"issue":"5","key":"2026101122012482000_cit20","doi-asserted-by":"publisher","first-page":"1933","DOI":"10.1039\/D5TC03401A","article-title":"Bifunctional [Fe6Co7] cyanide bridged assemblies: electron transfer coupled spin transition and liquid crystal properties","volume":"14","author":"Yadav","year":"2026","journal-title":"J. Mater. Chem. C"},{"issue":"17","key":"2026101122012482000_cit21","doi-asserted-by":"publisher","first-page":"18044","DOI":"10.1021\/jacs.6c01880","article-title":"Martensitic Transition Associated with Spin-Crossover Enabling Crystal Jumping and Pyroelectric Response","volume":"148","author":"Wang","year":"2026","journal-title":"J. Am. Chem. Soc."},{"issue":"15","key":"2026101122012482000_cit22","doi-asserted-by":"publisher","first-page":"9364","DOI":"10.1021\/acsapm.4c02098","article-title":"Self-Healing Composite Polymers Based on Spin Crossover Materials for Multidirectional Preprogrammed Actuation","volume":"6","author":"Enriquez-Cabrera","year":"2024","journal-title":"ACS Appl. Polym. Mater."},{"issue":"1","key":"2026101122012482000_cit23","doi-asserted-by":"publisher","first-page":"130","DOI":"10.1039\/D4SC05792A","article-title":"Spin state modulation and kinetic control of thermal contraction in a [Fe2Co2] discrete Prussian blue analogue","volume":"16","author":"Yadav","year":"2025","journal-title":"Chem. Sci."},{"issue":"1","key":"2026101122012482000_cit24","doi-asserted-by":"publisher","first-page":"7321","DOI":"10.1038\/s41467-024-51675-1","article-title":"Cooperative spin crossover leading to bistable and multi-inert system states in an iron (III) complex","volume":"15","author":"D\u00fcrrmann","year":"2024","journal-title":"Nat. Commun."},{"issue":"50","key":"2026101122012482000_cit25","doi-asserted-by":"publisher","first-page":"46497","DOI":"10.1021\/jacs.5c16808","article-title":"Pressure-Induced Unexpected Stabilization of the High-Spin State of Iron (II) in a Metal\u2013Organic Framework","volume":"147","author":"Getzner","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026101122012482000_cit26","first-page":"23","article-title":"Pressure effect studies on spin crossover and valence tautomeric systems","author":"Ksenofontov","year":"2004","journal-title":"Spin crossover in transition metal compounds III"},{"issue":"34","key":"2026101122012482000_cit27","doi-asserted-by":"publisher","first-page":"15752","DOI":"10.1021\/acs.inorgchem.4c01675","article-title":"Observation of TLIESST above Liquid Nitrogen Temperature and Disclosure of Hidden Hysteresis in Multiresponsive Hofmann-type Coordination Polymers","volume":"63","author":"Mondal","year":"2024","journal-title":"Inorg. Chem."},{"issue":"9","key":"2026101122012482000_cit28","doi-asserted-by":"publisher","first-page":"5930","DOI":"10.1021\/acs.chemrev.3c00840","article-title":"Optical phenomena in molecule-based magnetic materials","volume":"124","author":"Zakrzewski","year":"2024","journal-title":"Chem. Rev."},{"issue":"1","key":"2026101122012482000_cit29","doi-asserted-by":"publisher","first-page":"938","DOI":"10.1038\/ncomms1940","article-title":"Robust spin crossover and memristance across a single molecule","volume":"3","author":"Miyamachi","year":"2012","journal-title":"Nat. Commun."},{"issue":"9","key":"2026101122012482000_cit30","doi-asserted-by":"publisher","first-page":"6167","DOI":"10.1021\/acs.inorgchem.0c02789","article-title":"Giant Magnetoelectric Coupling and Magnetic-Field-Induced Permanent Switching in a Spin Crossover Mn(III) Complex","volume":"60","author":"Jakobsen","year":"2021","journal-title":"Inorg. Chem."},{"issue":"1","key":"2026101122012482000_cit31","doi-asserted-by":"publisher","first-page":"3510","DOI":"10.1038\/s41467-022-31274-8","article-title":"A spin-crossover framework endowed with pore-adjustable behavior by slow structural dynamics","volume":"13","author":"Xue","year":"2022","journal-title":"Nat. Commun."},{"issue":"10","key":"2026101122012482000_cit32","doi-asserted-by":"publisher","first-page":"4762","DOI":"10.1021\/jacsau.5c00681","article-title":"Engineering Magnetic Bistability: Solvent-Driven Photoresponsive Single-Chain Magnet Behavior in Fe2Co Coordination Polymer","volume":"5","author":"Kharel","year":"2025","journal-title":"JACS Au"},{"issue":"11","key":"2026101122012482000_cit33","doi-asserted-by":"publisher","DOI":"10.1002\/tcr.202200135","article-title":"Spin-State Modulation in FeII-Based Hofmann-Type Coordination Polymers: From Molecules to Materials","volume":"22","author":"Kumar","year":"2022","journal-title":"Chem. Rec."},{"issue":"9","key":"2026101122012482000_cit34","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202411201","article-title":"Decoding Framework Dynamics in a Spin Crossover Flexible Metal\u2013Organic Framework","volume":"21","author":"Martinez-Martinez","year":"2025","journal-title":"Small"},{"issue":"10","key":"2026101122012482000_cit35","doi-asserted-by":"publisher","first-page":"2236","DOI":"10.1002\/chem.201601880","article-title":"Guest-Dependent Spin-Transition Behavior of Porous Coordination Polymers","volume":"23","author":"Ohtani","year":"2017","journal-title":"Chem. Eur. J."},{"issue":"16","key":"2026101122012482000_cit36","doi-asserted-by":"publisher","first-page":"11338","DOI":"10.1039\/D3CP00670K","article-title":"CO and CO2 adsorption mechanism in Fe(pz)[Pt(CN)4] probed by neutron scattering and density-functional theory calculations","volume":"25","author":"Fern\u00e1ndez-Blanco","year":"2023","journal-title":"Phys. Chem. Chem. Phys."},{"issue":"18","key":"2026101122012482000_cit37","doi-asserted-by":"publisher","first-page":"8090","DOI":"10.1021\/acs.jpcc.2c01030","article-title":"Probing the SO2 Adsorption Mechanism in Hofmann Clathrates via Inelastic Neutron Scattering and Density Functional Theory Calculations","volume":"126","author":"Fern\u00e1ndez-Blanco","year":"2022","journal-title":"J. Phys. Chem. C"},{"issue":"26","key":"2026101122012482000_cit38","doi-asserted-by":"publisher","first-page":"4767","DOI":"10.1002\/anie.200806039","article-title":"Bidirectional chemo-switching of spin state in a microporous framework","volume":"48","author":"Ohba","year":"2009","journal-title":"Angew. Chem. Int. Ed."},{"issue":"31","key":"2026101122012482000_cit39","doi-asserted-by":"publisher","first-page":"10998","DOI":"10.1021\/ja902187d","article-title":"Dynamic interplay between spin-crossover and host\u2013 guest function in a nanoporous metal\u2013 organic framework material","volume":"131","author":"Southon","year":"2009","journal-title":"J. Am. Chem. Soc."},{"issue":"43","key":"2026101122012482000_cit40","doi-asserted-by":"publisher","first-page":"15986","DOI":"10.1021\/ja407135k","article-title":"Spin-Crossover Modification through Selective CO2 Sorption","volume":"135","author":"Coronado","year":"2013","journal-title":"J. Am. Chem. Soc."},{"issue":"34","key":"2026101122012482000_cit41","doi-asserted-by":"publisher","first-page":"4262","DOI":"10.1039\/C8CC00678D","article-title":"Three-dimensional iron(II) porous coordination polymer exhibiting carbon dioxide-dependent spin crossover","volume":"54","author":"Shin","year":"2018","journal-title":"Chem. Commun."},{"issue":"26","key":"2026101122012482000_cit42","doi-asserted-by":"publisher","first-page":"10658","DOI":"10.1002\/anie.202003811","article-title":"CO2-Induced Spin-State Switching at Room Temperature in a Monomeric Cobalt(II) Complex with the Porous Nature","volume":"59","author":"Nakaya","year":"2020","journal-title":"Angew. Chem. Int. Ed."},{"issue":"18","key":"2026101122012482000_cit43","doi-asserted-by":"publisher","first-page":"2334","DOI":"10.1002\/anie.200300610","article-title":"Functional porous coordination polymers","volume":"43","author":"Kitagawa","year":"2004","journal-title":"Angew. Chem. Int. Ed."},{"issue":"36","key":"2026101122012482000_cit44","doi-asserted-by":"publisher","first-page":"15325","DOI":"10.1002\/anie.202004535","article-title":"Chemistry of Soft Porous Crystals: Structural Dynamics and Gas Adsorption Properties","volume":"59","author":"Krause","year":"2020","journal-title":"Angew. Chem. Int. Ed."},{"issue":"36","key":"2026101122012482000_cit45","doi-asserted-by":"publisher","first-page":"9651","DOI":"10.1039\/d3sc03255h","article-title":"Guest-induced pore breathing controls the spin state in a cyanido-bridged framework","volume":"14","author":"Magott","year":"2023","journal-title":"Chem. Sci."},{"issue":"38","key":"2026101122012482000_cit46","doi-asserted-by":"publisher","first-page":"15610","DOI":"10.1039\/D4SC04266B","article-title":"CO2-actuated spin transition tuning in an interdigitated Hofmann-type coordination polymer","volume":"15","author":"Paul","year":"2024","journal-title":"Chem. Sci."},{"issue":"8","key":"2026101122012482000_cit47","doi-asserted-by":"publisher","first-page":"2695","DOI":"10.1002\/chem.201203267","article-title":"Guest-Triggered Supramolecular Isomerism in a Pillared-Layer Structure with Unusual Isomers of Paddle-Wheel Secondary Building Units by Reversible Single-Crystal-to-Single-Crystal Transformation","volume":"19","author":"Park","year":"2013","journal-title":"Chem. Eur. J."},{"issue":"7","key":"2026101122012482000_cit48","doi-asserted-by":"publisher","first-page":"3751","DOI":"10.1021\/acs.chemrev.0c01049","article-title":"Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications","volume":"121","author":"Chakraborty","year":"2021","journal-title":"Chem. Rev."},{"issue":"15","key":"2026101122012482000_cit49","doi-asserted-by":"publisher","first-page":"10038","DOI":"10.1021\/acs.inorgchem.9b01189","article-title":"Influence of Host\u2013Guest and Host\u2013Host Interactions on the Spin-Crossover 3D Hofmann-type Clathrates {FeII(pina)[MI(CN)2]2}\u00b7xMeOH (MI = Ag, Au)","volume":"58","author":"Valverde-Mu\u00f1oz","year":"2019","journal-title":"Inorg. Chem."},{"issue":"8","key":"2026101122012482000_cit50","doi-asserted-by":"publisher","first-page":"4039","DOI":"10.1021\/ic403069d","article-title":"Guest-effected spin-crossover in a novel three-dimensional self-penetrating coordination polymer with permanent porosity","volume":"53","author":"Li","year":"2014","journal-title":"Inorg. Chem."},{"issue":"41","key":"2026101122012482000_cit51","doi-asserted-by":"publisher","first-page":"11224","DOI":"10.1039\/D0SC04246C","article-title":"Reversible guest-induced gate-opening with multiplex spin crossover responses in two-dimensional Hofmann clathrates","volume":"11","author":"Turo-Cort\u00e9s","year":"2020","journal-title":"Chem. Sci."},{"issue":"3","key":"2026101122012482000_cit52","doi-asserted-by":"publisher","first-page":"1330","DOI":"10.1021\/jacs.6b12465","article-title":"Guest programmable multistep spin crossover in a porous 2-D Hofmann-type material","volume":"139","author":"Murphy","year":"2017","journal-title":"J. Am. Chem. Soc."},{"issue":"2","key":"2026101122012482000_cit53","doi-asserted-by":"publisher","first-page":"724","DOI":"10.1021\/cr2003272","article-title":"Carbon dioxide capture in metal\u2013organic frameworks","volume":"112","author":"Sumida","year":"2012","journal-title":"Chem. Rev."},{"issue":"15-16","key":"2026101122012482000_cit54","doi-asserted-by":"publisher","first-page":"1791","DOI":"10.1016\/j.ccr.2011.02.012","article-title":"Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks","volume":"255","author":"Li","year":"2011","journal-title":"Coord. Chem. Rev."},{"issue":"2","key":"2026101122012482000_cit55","doi-asserted-by":"publisher","first-page":"339","DOI":"10.1107\/S0021889808042726","article-title":"OLEX2: a complete structure solution, refinement and analysis program","volume":"42","author":"Dolomanov","year":"2009","journal-title":"Appl. Crystallogr."},{"issue":"48","key":"2026101122012482000_cit56","doi-asserted-by":"publisher","first-page":"26179","DOI":"10.1021\/jacs.3c08583","article-title":"CO2-Sensitive Porous Magnet: Antiferromagnet Creation from a Paramagnetic Charge-Transfer Layered Metal\u2013Organic Framework","volume":"145","author":"Zhang","year":"2023","journal-title":"J. Am. Chem. Soc."}],"container-title":["ACS Applied Materials &amp; Interfaces"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsami.6c16795","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/aamick\/article-pdf\/doi\/10.1021\/acsami.6c16795\/68813316\/am-2026-167953.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/aamick\/article-pdf\/doi\/10.1021\/acsami.6c16795\/68813316\/am-2026-167953.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T03:22:37Z","timestamp":1792120957000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/aamick\/article\/doi\/10.1021\/acsami.6c16795\/5448629\/Coupling-the-Spin-State-Switching-and-CO2"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,12]]},"references-count":56,"URL":"https:\/\/doi.org\/10.1021\/acsami.6c16795","relation":{},"ISSN":["1944-8244","1944-8252"],"issn-type":[{"value":"1944-8244","type":"print"},{"value":"1944-8252","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,12]]}}}