{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T08:53:58Z","timestamp":1790931238842,"version":"4.1.0"},"reference-count":59,"publisher":"American Chemical Society (ACS)","issue":"19","license":[{"start":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T00:00:00Z","timestamp":1789171200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T00:00:00Z","timestamp":1789171200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T00:00:00Z","timestamp":1789171200000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000057","name":"National Institute of General Medical Sciences","doi-asserted-by":"publisher","award":["R35 GM126986"],"award-info":[{"award-number":["R35 GM126986"]}],"id":[{"id":"10.13039\/100000057","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100001082","name":"Camille and Henry Dreyfus Foundation","doi-asserted-by":"publisher","award":["ST-25-030"],"award-info":[{"award-number":["ST-25-030"]}],"id":[{"id":"10.13039\/100001082","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001692","name":"Croucher Foundation","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001692","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,10,2]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Pharmaceutically relevant Suzuki\u2013Miyaura cross-couplings (SMCs) often require designer phosphine ligands and palladium loadings above 1 mol % to couple Lewis basic, sterically congested substrates. Recent work has demonstrated that nickel is an attractive alternative to palladium for facile SMCs, but further ligand development is required for Ni catalysis to rival Pd for more challenging couplings. We applied prior work on monophosphine ligand design for Ni to develop a bisphosphine, DiploPhos, that outperforms state-of-the-art ligands for Ni to achieve sterically hindered Ni SMCs with \u22653 ortho-substituents. Catalyst speciation studies revealed the hemilabile nature of DiploPhos, which improves reactivity relative to stronger chelating ligands but also leads to the formation of less-active DiploPhos-bridged aggregates. Lewis basic functionality (present on substrates or additives) was found to promote the disaggregation of these species and led to increased SMC yields. This observation is contrary to most other systems in which Lewis basic substrates inhibit Ni-catalyzed SMC reactions. Ligand exchange studies demonstrated that despite its hemilability, DiploPhos is more resistant to displacement by heterocycles than similar bisphosphines. Together, these properties led to best-in-class reactivity for sterically hindered, Lewis base-rich Ni SMCs.<\/jats:p>","DOI":"10.1021\/acscatal.6c05422","type":"journal-article","created":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T10:01:40Z","timestamp":1789207300000},"page":"19470-19480","source":"Crossref","is-referenced-by-count":0,"title":["DiploPhos: A Hemilabile Bisphosphine for Sterically Hindered Ni-Catalyzed Suzuki\u2013Miyaura Couplings"],"prefix":"10.1021","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9449-5574","authenticated-orcid":true,"given":"T. Judah","family":"Raab","sequence":"first","affiliation":[{"name":"University of California Los Angeles , , , ,","place":["Los Angeles, California, United States, 90095"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hang Chi","family":"Ho","sequence":"additional","affiliation":[{"name":"University of California Los Angeles , , , ,","place":["Los Angeles, California, United States, 90095"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0369-4883","authenticated-orcid":true,"given":"Tyler","family":"Kerr","sequence":"additional","affiliation":[{"name":"University of California Los Angeles , , , ,","place":["Los Angeles, California, United States, 90095"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nari","family":"Tao","sequence":"additional","affiliation":[{"name":"University of California Los Angeles , , , ,","place":["Los Angeles, California, United States, 90095"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1903-5380","authenticated-orcid":true,"given":"Shashank","family":"Shekhar","sequence":"additional","affiliation":[{"name":"AbbVie Inc. , , ,","place":["North Chicago, Illinois, United States, 60064"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rafal","family":"Swiatowiec","sequence":"additional","affiliation":[{"name":"AbbVie Inc. , , ,","place":["North Chicago, Illinois, United States, 60064"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8383-5633","authenticated-orcid":true,"given":"Michael C.","family":"Haibach","sequence":"additional","affiliation":[{"name":"AbbVie Inc. , , ,","place":["North Chicago, Illinois, United States, 60064"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6641-0833","authenticated-orcid":true,"given":"Abigail G.","family":"Doyle","sequence":"additional","affiliation":[{"name":"University of California Los Angeles , , , ,","place":["Los Angeles, California, United States, 90095"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,12]]},"reference":[{"key":"2026100204062551100_cit1","doi-asserted-by":"publisher","first-page":"1461","DOI":"10.1021\/ar800036s","article-title":"Palladium-Catalyzed Suzuki\u2013Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands","volume":"41","author":"Martin","year":"2008","journal-title":"Acc. Chem. Res."},{"key":"2026100204062551100_cit2","doi-asserted-by":"publisher","first-page":"4176","DOI":"10.1002\/1521-3773(20021115)41:22&lt;4176::aid-anie4176&gt;3.0.co;2-u","article-title":"Palladium-Catalyzed Coupling Reactions of Aryl Chlorides","volume":"41","author":"Littke","year":"2002","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026100204062551100_cit3","doi-asserted-by":"publisher","first-page":"2177","DOI":"10.1021\/cr100346g","article-title":"Large-Scale Applications of Transition Metal-Catalyzed Couplings for the Synthesis of Pharmaceuticals","volume":"111","author":"Magano","year":"2011","journal-title":"Chem. Rev."},{"key":"2026100204062551100_cit4","doi-asserted-by":"publisher","first-page":"4443","DOI":"10.1021\/acs.jmedchem.5b01409","article-title":"Analysis of Past and Present Synthetic Methodologies on Medicinal Chemistry: Where Have All the New Reactions Gone?","volume":"59","author":"Brown","year":"2016","journal-title":"J. Med. Chem."},{"key":"2026100204062551100_cit5","doi-asserted-by":"publisher","first-page":"1269","DOI":"10.1021\/acs.organomet.2c00197","article-title":"Nickel-Catalyzed Suzuki\u2013Miyaura Cross-Coupling Facilitated by a Weak Amine Base with Water as a Cosolvent","volume":"41","author":"Guo","year":"2022","journal-title":"Organometallics"},{"key":"2026100204062551100_cit6","doi-asserted-by":"publisher","first-page":"6360","DOI":"10.1021\/jacs.4c00370","article-title":"ProPhos: A Ligand for Promoting Nickel-Catalyzed Suzuki-Miyaura Coupling Inspired by Mechanistic Insights into Transmetalation","volume":"146","author":"Yang","year":"2024","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit7","doi-asserted-by":"publisher","first-page":"19302","DOI":"10.1021\/acscatal.5c07157","article-title":"Process-Ready Nickel-Catalyzed Suzuki\u2013Miyaura Coupling Enabled by tri-ProPhos","volume":"15","author":"Yang","year":"2025","journal-title":"ACS Catal."},{"key":"2026100204062551100_cit8","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.202200440","article-title":"Nickel Bromide Catalyzed Ligand-Free and Activator-less Suzuki Coupling Reactions","volume":"14","author":"Islam","year":"2022","journal-title":"ChemCatChem"},{"key":"2026100204062551100_cit9","doi-asserted-by":"publisher","first-page":"4009","DOI":"10.1016\/s0040-4039(02)00716-5","article-title":"Suzuki Cross-Coupling of Aryl Halides with Aryl Boronic Acids Catalyzed by Phosphine-Free NiCl2\u00b76H2O","volume":"43","author":"Zim","year":"2002","journal-title":"Tetrahedron Lett."},{"key":"2026100204062551100_cit10","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202424051","article-title":"\u201cNaked Nickel\u201d-Catalyzed Heteroaryl\u2013Heteroaryl Suzuki\u2013Miyaura Coupling","volume":"64","author":"Saeb","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026100204062551100_cit11","doi-asserted-by":"publisher","first-page":"4039","DOI":"10.1021\/acs.oprd.4c00327","article-title":"Advancing Base-Metal Catalysis: Developing Nickel Catalysis for the Direct Telescope of Miyaura Borylation and Suzuki\u2013Miyaura Cross-Coupling Reactions","volume":"28","author":"Esteves","year":"2024","journal-title":"Org. Process Res. Dev."},{"key":"2026100204062551100_cit12","doi-asserted-by":"publisher","first-page":"4797","DOI":"10.1021\/acs.orglett.0c01600","article-title":"Activator-Promoted Aryl Halide-Dependent Chemoselective Buchwald\u2013Hartwig and Suzuki\u2013Miyaura Type Cross-Coupling Reactions","volume":"22","author":"Dhital","year":"2020","journal-title":"Org. Lett."},{"key":"2026100204062551100_cit13","doi-asserted-by":"publisher","first-page":"3115","DOI":"10.1021\/acs.oprd.2c00249","article-title":"Development of a Commercial Manufacturing Process for Sotorasib, a First-in-Class KRASG12C Inhibitor","volume":"26","author":"Zhang","year":"2022","journal-title":"Org. Process Res. Dev."},{"key":"2026100204062551100_cit14","doi-asserted-by":"publisher","first-page":"9346","DOI":"10.1002\/chem.200600616","article-title":"Efficient Synthesis of Chiral 1,1\u2032-Binaphthalenes by the Asymmetric Suzuki\u2013Miyaura Reaction: Dramatic Synthetic Improvement by Simple Purification of Naphthylboronic Acids","volume":"12","author":"Genov","year":"2006","journal-title":"Chem. \u2013 Eur. J."},{"key":"2026100204062551100_cit15","doi-asserted-by":"publisher","first-page":"15318","DOI":"10.1021\/jacs.5c00838","article-title":"Transfer Learning-Enabled Ligand Prediction for Ni-Catalyzed Atroposelective Suzuki\u2013Miyaura Cross-Coupling Based on Mechanistic Similarity: Leveraging Pd Knowledge for Ni Discovery","volume":"147","author":"Xu","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit16","doi-asserted-by":"publisher","first-page":"299","DOI":"10.1038\/nature13274","article-title":"Recent Advances in Homogeneous Nickel Catalysis","volume":"509","author":"Tasker","year":"2014","journal-title":"Nature"},{"key":"2026100204062551100_cit17","doi-asserted-by":"publisher","first-page":"301","DOI":"10.1126\/science.abj4213","article-title":"Univariate Classification of Phosphine Ligation State and Reactivity in Cross-Coupling Catalysis","volume":"374","author":"Newman-Stonebraker","year":"2021","journal-title":"Science"},{"key":"2026100204062551100_cit18","doi-asserted-by":"publisher","first-page":"7966","DOI":"10.1021\/acscatal.3c01331","article-title":"Comparison of Monophosphine and Bisphosphine Precatalysts for Ni-Catalyzed Suzuki\u2013Miyaura Cross-Coupling: Understanding the Role of the Ligation State in Catalysis","volume":"13","author":"Borowski","year":"2023","journal-title":"ACS Catal."},{"key":"2026100204062551100_cit19","doi-asserted-by":"publisher","first-page":"12837","DOI":"10.1002\/anie.201207428","article-title":"Highly Reactive, Single-Component Nickel Catalyst Precursor for Suzuki\u2013Miyuara Cross-Coupling of Heteroaryl Boronic Acids with Heteroaryl Halides","volume":"51","author":"Ge","year":"2012","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026100204062551100_cit20","doi-asserted-by":"publisher","first-page":"16967","DOI":"10.1021\/ja3079362","article-title":"Mechanistic Investigation of the Nickel-Catalyzed Suzuki Reaction of N,O-Acetals: Evidence for Boronic Acid Assisted Oxidative Addition and an Iminium Activation Pathway","volume":"134","author":"Sylvester","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit21","doi-asserted-by":"publisher","first-page":"799","DOI":"10.1055\/s-0036-1591523","article-title":"(DPEPhos)Ni(Mesityl)Br: An Air-Stable Pre-Catalyst for Challenging Suzuki\u2013Miyaura Cross-Couplings Leading to Unsymmetrical Biheteroaryls","volume":"29","author":"Sawatzky","year":"2018","journal-title":"Synlett"},{"key":"2026100204062551100_cit22"},{"key":"2026100204062551100_cit23","doi-asserted-by":"publisher","first-page":"2063","DOI":"10.1021\/ol800567q","article-title":"Biphenylene-Substituted Ruthenocenylphosphine for Suzuki\u2013Miyaura Coupling of Aryl Chlorides","volume":"10","author":"Hoshi","year":"2008","journal-title":"Org. Lett."},{"key":"2026100204062551100_cit24","doi-asserted-by":"publisher","first-page":"1004","DOI":"10.1021\/ol1000186","article-title":"Tetra-Ortho-Substituted Biaryls through Palladium-Catalyzed Suzuki\u2013Miyaura Couplings with a Diaminochlorophosphine Ligand","volume":"12","author":"Ackermann","year":"2010","journal-title":"Org. Lett."},{"key":"2026100204062551100_cit25","doi-asserted-by":"publisher","first-page":"1907","DOI":"10.1002\/ange.200353615","article-title":"A Rationally Designed Universal Catalyst for Suzuki\u2013Miyaura Coupling Processes","volume":"116","author":"Walker","year":"2004","journal-title":"Angew. Chem. Int. Ed."},{"key":"2026100204062551100_cit26","doi-asserted-by":"publisher","first-page":"3690","DOI":"10.1002\/anie.200351325","article-title":"An N-Heterocyclic Carbene Ligand with Flexible Steric Bulk Allows Suzuki Cross-Coupling of Sterically Hindered Aryl Chlorides at Room Temperature","volume":"42","author":"Altenhoff","year":"2003","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026100204062551100_cit27","doi-asserted-by":"publisher","first-page":"14814","DOI":"10.1021\/jacs.1c06863","article-title":"Protodeboronation of (Hetero)Arylboronic Esters: Direct versus Prehydrolytic Pathways and Self-\/Auto-Catalysis","volume":"143","author":"Hayes","year":"2021","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit28","doi-asserted-by":"publisher","first-page":"9145","DOI":"10.1021\/jacs.6b03283","article-title":"Protodeboronation of Heteroaromatic, Vinyl, and Cyclopropyl Boronic Acids: pH\u2013Rate Profiles, Autocatalysis, and Disproportionation","volume":"138","author":"Cox","year":"2016","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit29","doi-asserted-by":"publisher","first-page":"38237","DOI":"10.1021\/jacs.5c10835","article-title":"The Boroxine\u2013Boronic Acid Equilibrium","volume":"147","author":"Li","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit30","doi-asserted-by":"publisher","first-page":"12906","DOI":"10.1039\/d2sc03877c","article-title":"Enabling Suzuki\u2013Miyaura Coupling of Lewis-Basic Arylboronic Esters with a Nonprecious Metal Catalyst","volume":"13","author":"Haibach","year":"2022","journal-title":"Chem. Sci."},{"key":"2026100204062551100_cit31","doi-asserted-by":"publisher","first-page":"4812","DOI":"10.1021\/acscatal.8b00933","article-title":"Taming Nickel-Catalyzed Suzuki-Miyaura Coupling: A Mechanistic Focus on Boron-to-Nickel Transmetalation","volume":"8","author":"Payard","year":"2018","journal-title":"ACS Catal."},{"key":"2026100204062551100_cit32","doi-asserted-by":"publisher","first-page":"1510","DOI":"10.1246\/bcsj.20210023","article-title":"Development of Effective Bidentate Diphosphine Ligands of Ruthenium Catalysts toward Practical Hydrogenation of Carboxylic Acids","volume":"94","author":"Yoshioka","year":"2021","journal-title":"Bull. Chem. Soc. Jpn."},{"key":"2026100204062551100_cit33","doi-asserted-by":"publisher","first-page":"89","DOI":"10.1038\/s41586-021-03213-y","article-title":"Bayesian Reaction Optimization as a Tool for Chemical Synthesis","volume":"590","author":"Shields","year":"2021","journal-title":"Nature"},{"key":"2026100204062551100_cit34","doi-asserted-by":"publisher","first-page":"19999","DOI":"10.1021\/jacs.2c08592","article-title":"A Multi-Objective Active Learning Platform and Web App for Reaction Optimization","volume":"144","author":"Torres","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit35","doi-asserted-by":"publisher","first-page":"3120","DOI":"10.1021\/acscatal.5b00498","article-title":"Development of an Air-Stable, Broadly Applicable Nickel Source for Nickel-Catalyzed Cross-Coupling","volume":"5","author":"Magano","year":"2015","journal-title":"ACS Catal."},{"key":"2026100204062551100_cit36","doi-asserted-by":"publisher","first-page":"2166","DOI":"10.1021\/acs.orglett.5b00766","article-title":"A Modular, Air-Stable Nickel Precatalyst","volume":"17","author":"Shields","year":"2015","journal-title":"Org. Lett."},{"key":"2026100204062551100_cit37","doi-asserted-by":"publisher","first-page":"1162","DOI":"10.1021\/ja017082r","article-title":"A Highly Active Suzuki Catalyst for the Synthesis of Sterically Hindered Biaryls: Novel Ligand Coordination","volume":"124","author":"Yin","year":"2002","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit38","doi-asserted-by":"publisher","first-page":"12877","DOI":"10.1021\/ja4064469","article-title":"Suzuki-Miyaura Cross-Coupling of Unprotected, Nitrogen-Rich Heterocycles: Substrate Scope and Mechanistic Investigation","volume":"135","author":"D\u00fcfert","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit39","doi-asserted-by":"publisher","first-page":"597","DOI":"10.1038\/nchem.1669","article-title":"A Robustness Screen for the Rapid Assessment of Chemical Reactions","volume":"5","author":"Collins","year":"2013","journal-title":"Nat. Chem."},{"key":"2026100204062551100_cit40","doi-asserted-by":"publisher","first-page":"9902","DOI":"10.1021\/jacs.0c02673","article-title":"Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Chlorides with Primary Alkyl Chlorides","volume":"142","author":"Kim","year":"2020","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit41","doi-asserted-by":"publisher","first-page":"393","DOI":"10.1016\/S0022-328X(00)90632-6","article-title":"Reaktionen von Heteroolefinen an Zentralmetallen in Niedrigen Oxidationsstufen: Stabile Aldehydkomplexe Des Nickel(O) Und Verwandte Verbindungen","volume":"190","author":"Walther","year":"1980","journal-title":"J. Organomet. Chem."},{"key":"2026100204062551100_cit42","doi-asserted-by":"publisher","first-page":"10717","DOI":"10.1021\/acscatal.0c02514","article-title":"Unexpected Nickel Complex Speciation Unlocks Alternative Pathways for the Reactions of Alkyl Halides with Dppf-Nickel(0)","volume":"10","author":"Greaves","year":"2020","journal-title":"ACS Catal."},{"key":"2026100204062551100_cit43","doi-asserted-by":"publisher","first-page":"3259","DOI":"10.1021\/acs.organomet.8b00438","article-title":"Comprehensive Study of the Reactions Between Chelating Phosphines and Ni(Cod)2","volume":"37","author":"Clevenger","year":"2018","journal-title":"Organometallics"},{"key":"2026100204062551100_cit44","author":"Jacot-Descombes","journal-title":"Morfeus"},{"key":"2026100204062551100_cit45","doi-asserted-by":"publisher","first-page":"15577","DOI":"10.1039\/c4cc07590k","article-title":"Synthesis, Mechanism of Formation, and Catalytic Activity of Xantphos Nickel \u03c0-Complexes","volume":"50","author":"Staudaher","year":"2014","journal-title":"Chem. Commun."},{"key":"2026100204062551100_cit46","doi-asserted-by":"publisher","first-page":"4164","DOI":"10.1021\/jacs.5b00538","article-title":"Fundamental Studies and Development of Nickel-Catalyzed Trifluoromethylthiolation of Aryl Chlorides: Active Catalytic Species and Key Roles of Ligand and Traceless MeCN Additive Revealed","volume":"137","author":"Yin","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit47","doi-asserted-by":"publisher","first-page":"2012","DOI":"10.1021\/om500156q","article-title":"A Broadly Applicable Strategy for Entry into Homogeneous Nickel(0) Catalysts from Air-Stable Nickel(II) Complexes","volume":"33","author":"Standley","year":"2014","journal-title":"Organometallics"},{"key":"2026100204062551100_cit48","doi-asserted-by":"publisher","first-page":"6391","DOI":"10.1002\/anie.201900095","article-title":"PAd2-DalPhos Enables the Nickel-Catalyzed C\u2013N Cross-Coupling of Primary Heteroarylamines and (Hetero)Aryl Chlorides","volume":"58","author":"Clark","year":"2019","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026100204062551100_cit49","doi-asserted-by":"publisher","first-page":"679","DOI":"10.1021\/acs.organomet.6b00885","article-title":"Evaluating 1,1\u2032-Bis(Phosphino)Ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C\u2013N Cross-Coupling of (Hetero)Aryl Chlorides","volume":"36","author":"Clark","year":"2017","journal-title":"Organometallics"},{"key":"2026100204062551100_cit50","doi-asserted-by":"publisher","first-page":"955","DOI":"10.1039\/b617136b","article-title":"Structural Variation in Copper(I) Complexes with Pyridylmethylamide Ligands : Structural Analysis with a New Four-Coordinate Geometry Index, \u03c44","volume":"36","author":"Yang","year":"2007","journal-title":"Dalton Trans."},{"key":"2026100204062551100_cit51","doi-asserted-by":"publisher","first-page":"1688","DOI":"10.1021\/acs.organomet.9b00834","article-title":"[(Dcpp)Ni(\u03b72-Arene)] Precursors: Synthesis, Reactivity, and Catalytic Application to the Suzuki\u2013Miyaura Reaction","volume":"39","author":"D\u2019Accriscio","year":"2020","journal-title":"Organometallics"},{"key":"2026100204062551100_cit52"},{"key":"2026100204062551100_cit53"},{"key":"2026100204062551100_cit54"},{"key":"2026100204062551100_cit55","doi-asserted-by":"publisher","first-page":"1425","DOI":"10.1021\/acs.jchemed.0c00057","article-title":"Variable Temperature NMR Experiment Studying Restricted Bond Rotation","volume":"97","author":"Huggins","year":"2020","journal-title":"J. Chem. Educ."},{"key":"2026100204062551100_cit56","doi-asserted-by":"publisher","first-page":"6516","DOI":"10.1021\/jacs.2c01356","article-title":"Elucidating the Mechanism of Excited-State Bond Homolysis in Nickel\u2013Bipyridine Photoredox Catalysts","volume":"144","author":"Cagan","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit57","doi-asserted-by":"publisher","first-page":"63","DOI":"10.1016\/j.pnmrs.2003.08.001","article-title":"Chemical Exchange in NMR","volume":"43","author":"Bain","year":"2003","journal-title":"Prog. Nucl. Magn. Reson. Spectrosc."},{"key":"2026100204062551100_cit58","doi-asserted-by":"publisher","first-page":"4867","DOI":"10.1021\/ja00276a026","article-title":"Main Group Chemistry on a Metal Framework. Reactions of [(\u00b5-H)Fe3(CO)9BH2R]- (R = H, CH3) with Lewis Bases","volume":"108","author":"Housecroft","year":"1986","journal-title":"J. Am. Chem. Soc."},{"key":"2026100204062551100_cit59","doi-asserted-by":"publisher","first-page":"6124","DOI":"10.1021\/acs.chemrev.9b00682","article-title":"Trends in the Usage of Bidentate Phosphines as Ligands in Nickel Catalysis","volume":"120","author":"Clevenger","year":"2020","journal-title":"Chem. Rev."}],"container-title":["ACS Catalysis"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acscatal.6c05422","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/accacs\/article-pdf\/16\/19\/19470\/68490696\/cs-2026-05422t.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/accacs\/article-pdf\/16\/19\/19470\/68490696\/cs-2026-05422t.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T08:13:25Z","timestamp":1790928805000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/accacs\/article\/16\/19\/19470\/5428820\/DiploPhos-A-Hemilabile-Bisphosphine-for-Sterically"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,12]]},"references-count":59,"journal-issue":{"issue":"19","published-online":{"date-parts":[[2026,9,12]]},"published-print":{"date-parts":[[2026,10,2]]}},"URL":"https:\/\/doi.org\/10.1021\/acscatal.6c05422","relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv-2025-q7td5","asserted-by":"object"}]},"ISSN":["2155-5435"],"issn-type":[{"value":"2155-5435","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,12]]}}}