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The use of the hemilabile ligand H8-BINAP(O) is key to providing high enantioselectivity in this transformation. We show that this methodology opens the door to the synthesis of a variety of planar-chiral chromium derivatives which can be easily transformed into planar chiral mono- or diphosphines. Mechanistic studies, including synthesis and characterization of Pd and Ag complexes and their detection in the reaction mixture, suggest a Pd-catalyzed\/Ag-promoted catalytic system where Ag carries out the C\u2013H activation step.<\/jats:p>","DOI":"10.1021\/acscatal.9b00918","type":"journal-article","created":{"date-parts":[[2019,4,25]],"date-time":"2019-04-25T10:16:29Z","timestamp":1556187389000},"page":"5268-5278","source":"Crossref","is-referenced-by-count":53,"title":["Catalytic Asymmetric C\u2013H Arylation of (\u03b76-Arene)Chromium Complexes: Facile Access to Planar-Chiral\nPhosphines"],"prefix":"10.1021","volume":"9","author":[{"given":"Mari\u0301a","family":"Batuecas","sequence":"first","affiliation":[{"name":"University of Manchester , , Oxford Road , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junfei","family":"Luo","sequence":"additional","affiliation":[{"name":"University of Manchester , , Oxford Road , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ivana","family":"Gergelitsova\u0301","sequence":"additional","affiliation":[{"name":"University of Manchester , , Oxford Road , ,","place":["Manchester, United Kingdom, M13 9PL"]},{"name":"Charles University , , Hlavova 2030\/8 , ,","place":["Prague 2, Czech Republic, 128 43"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katrina","family":"Kra\u0308mer","sequence":"additional","affiliation":[{"name":"University of Manchester , , Oxford Road , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Daniel","family":"Whitaker","sequence":"additional","affiliation":[{"name":"University of Manchester , , Oxford Road , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"In\u0303igo J.","family":"Vitorica-Yrezabal","sequence":"additional","affiliation":[{"name":"University of Manchester , , Oxford Road , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5391-7424","authenticated-orcid":true,"given":"Igor","family":"Larrosa","sequence":"additional","affiliation":[{"name":"University of Manchester , , Oxford Road , ,","place":["Manchester, United Kingdom, M13 9PL"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2019,4,25]]},"reference":[{"key":"2026090203335937800_cit1a","doi-asserted-by":"publisher","first-page":"2917","DOI":"10.1021\/cr9902852","article-title":"Transition-Metal-Mediated\nDearomatization Reactions","volume":"100","author":"Pape","year":"2000","journal-title":"Chem. 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