{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,29]],"date-time":"2026-09-29T01:41:49Z","timestamp":1790646109056,"version":"4.1.0"},"reference-count":75,"publisher":"American Chemical Society (ACS)","issue":"10","license":[{"start":{"date-parts":[[2020,9,16]],"date-time":"2020-09-16T00:00:00Z","timestamp":1600214400000},"content-version":"vor","delay-in-days":5,"URL":"https:\/\/pubs.acs.org\/page\/policy\/authorchoice_ccbyncnd_termsofuse.html"}],"funder":[{"DOI":"10.13039\/100010663","name":"H2020 European Research Council","doi-asserted-by":"publisher","award":["815128"],"award-info":[{"award-number":["815128"]}],"id":[{"id":"10.13039\/100010663","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100010665","name":"H2020 Marie Sklodowska-Curie Actions","doi-asserted-by":"publisher","award":["797153"],"award-info":[{"award-number":["797153"]}],"id":[{"id":"10.13039\/100010665","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100000780","name":"European Commission","doi-asserted-by":"publisher","award":["EUSMI E180900184"],"award-info":[{"award-number":["EUSMI E180900184"]}],"id":[{"id":"10.13039\/501100000780","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003246","name":"Nederlandse Organisatie voor Wetenschappelijk Onderzoek","doi-asserted-by":"publisher","award":["TOP.715.016.001"],"award-info":[{"award-number":["TOP.715.016.001"]}],"id":[{"id":"10.13039\/501100003246","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2020,10,27]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Despite recent advances, the synthesis of colloidal InSb quantum dots (QDs) remains underdeveloped, mostly due to the lack of suitable precursors. In this work, we use Lewis acid\u2013base interactions between Sb(III) and In(III) species formed at room temperature in situ from commercially available compounds (viz., InCl3, Sb[NMe2]3 and a primary alkylamine) to obtain InSb adduct complexes. These complexes are successfully used as precursors for the synthesis of colloidal InSb QDs ranging from 2.8 to 18.2 nm in diameter by fast coreduction at sufficiently high temperatures (\u2265230 \u00b0C). Our findings allow us to propose a formation mechanism for the QDs synthesized in our work, which is based on a nonclassical nucleation event, followed by aggregative growth. This yields ensembles with multimodal size distributions, which can be fractionated in subensembles with relatively narrow polydispersity by postsynthetic size fractionation. InSb QDs with diameters below 7.0 nm have the zinc blende crystal structure, while ensembles of larger QDs (\u226510 nm) consist of a mixture of wurtzite and zinc blende QDs. The QDs exhibit photoluminescence with small Stokes shifts and short radiative lifetimes, implying that the emission is due to band-edge recombination and that the direct nature of the bandgap of bulk InSb is preserved in InSb QDs. Finally, we constructed a sizing curve correlating the peak position of the lowest energy absorption transition with the QD diameters, which shows that the band gap of colloidal InSb QDs increases with size reduction following a 1\/d dependence.<\/jats:p>","DOI":"10.1021\/acsnano.0c04744","type":"journal-article","created":{"date-parts":[[2020,9,11]],"date-time":"2020-09-11T16:20:09Z","timestamp":1599841209000},"page":"13146-13160","source":"Crossref","is-referenced-by-count":69,"title":["Luminescent\nColloidal InSb Quantum Dots from\n                    <i>In Situ<\/i>\n                    Generated\nSingle-Source Precursor"],"prefix":"10.1021","volume":"14","author":[{"given":"Serena","family":"Busatto","sequence":"first","affiliation":[{"name":"Utrecht University , , P.O. Box 80000, ,","place":["Utrecht, The Netherlands, 3508 TA"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mariska","family":"de Ruiter","sequence":"additional","affiliation":[{"name":"Utrecht University , , P.O. Box 80000, ,","place":["Utrecht, The Netherlands, 3508 TA"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Johann T. B. H.","family":"Jastrzebski","sequence":"additional","affiliation":[{"name":"Utrecht University , , Universiteitsweg 99 , ,","place":["Utrecht, The Netherlands, 3584 CG"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wiebke","family":"Albrecht","sequence":"additional","affiliation":[{"name":"University of Antwerp , , Groenenborgerlaan 171 , ,","place":["Antwerp, Belgium, B-2020"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3792-3661","authenticated-orcid":true,"given":"Valerio","family":"Pinchetti","sequence":"additional","affiliation":[{"name":"Universita\u0300 degli Studi di Milano Bicocca , , via Roberto Cozzi 55 , ,","place":["Milano, Italy, I-20125"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5993-855X","authenticated-orcid":true,"given":"Sergio","family":"Brovelli","sequence":"additional","affiliation":[{"name":"Universita\u0300 degli Studi di Milano Bicocca , , via Roberto Cozzi 55 , ,","place":["Milano, Italy, I-20125"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4249-8017","authenticated-orcid":true,"given":"Sara","family":"Bals","sequence":"additional","affiliation":[{"name":"University of Antwerp , , Groenenborgerlaan 171 , ,","place":["Antwerp, Belgium, B-2020"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3137-6073","authenticated-orcid":true,"given":"Marc-Etienne","family":"Moret","sequence":"additional","affiliation":[{"name":"Utrecht University , , Universiteitsweg 99 , ,","place":["Utrecht, The Netherlands, 3584 CG"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4403-3627","authenticated-orcid":true,"given":"Celso","family":"de Mello Donega","sequence":"additional","affiliation":[{"name":"Utrecht University , , P.O. Box 80000, ,","place":["Utrecht, The Netherlands, 3508 TA"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,9,11]]},"reference":[{"key":"2026090119224694600_cit1","doi-asserted-by":"crossref","first-page":"191","DOI":"10.1142\/9789812832078_0009","volume-title":"Handbook Series on\nSemiconductor Parameters","author":"Goldbery","year":"1996"},{"key":"2026090119224694600_cit2","doi-asserted-by":"publisher","first-page":"6112","DOI":"10.1021\/nl302803e","article-title":"Wavelength-Dependent\nAbsorption in Structurally Tailored Randomly Branched Vertical Arrays\nof InSb Nanowires","volume":"12","author":"Mohammad","year":"2012","journal-title":"Nano Lett."},{"key":"2026090119224694600_cit3","doi-asserted-by":"publisher","first-page":"153505","DOI":"10.1063\/1.3402760","article-title":"Temperature\nDependent Properties of InSb and InAs Nanowire\nField-Effect Transistors","volume":"96","author":"Nilsson","year":"2010","journal-title":"Appl. Phys. Lett."},{"key":"2026090119224694600_cit4","doi-asserted-by":"publisher","first-page":"105","DOI":"10.1038\/nmat2090","article-title":"Complex Thermoelectric\nMaterials","volume":"7","author":"Snyder","year":"2008","journal-title":"Nat. Mater."},{"key":"2026090119224694600_cit5","doi-asserted-by":"publisher","first-page":"312","DOI":"10.1103\/PhysRev.169.312","article-title":"Electron\nSpin Resonance in n-Type InSb","volume":"169","author":"Isaacson","year":"1968","journal-title":"Phys. Rev."},{"key":"2026090119224694600_cit6","doi-asserted-by":"publisher","first-page":"483","DOI":"10.1038\/nmat3585","article-title":"Single\nSpins in Self-Assembled Quantum Dots","volume":"12","author":"Warburton","year":"2013","journal-title":"Nat. Mater."},{"key":"2026090119224694600_cit7","doi-asserted-by":"publisher","first-page":"066806","DOI":"10.1103\/PhysRevLett.110.066806","article-title":"Fast Spin-Orbit\nQubit in an Indium Antimonide Nanowire","volume":"110","author":"van den Berg","year":"2013","journal-title":"Phys.\nRev. Lett."},{"key":"2026090119224694600_cit8","doi-asserted-by":"publisher","first-page":"1179","DOI":"10.1126\/science.1231473","article-title":"Topological Quantum\nComputation- From Basic Concepts\nto First Experiments","volume":"339","author":"Stern","year":"2013","journal-title":"Science"},{"key":"2026090119224694600_cit9","doi-asserted-by":"publisher","first-page":"74","DOI":"10.1038\/nature26142","article-title":"Quantized Majorana Conductance","volume":"556","author":"Zhang","year":"2018","journal-title":"Nature"},{"key":"2026090119224694600_cit10","doi-asserted-by":"publisher","first-page":"044202","DOI":"10.1103\/PhysRevMaterials.2.044202","article-title":"Engineering\nHybrid Epitaxial InAsSb\/Al Nanowires for Stronger Topological Protection","volume":"2","author":"Sestoft","year":"2018","journal-title":"Phys. Rev. Mater."},{"key":"2026090119224694600_cit11","doi-asserted-by":"publisher","first-page":"52","DOI":"10.1038\/s41578-018-0003-1","article-title":"Majorana Zero Modes in Superconductor-Semiconductor\nHeterostructures","volume":"3","author":"Lutchyn","year":"2018","journal-title":"Nat. Rev. Mater."},{"key":"2026090119224694600_cit12","doi-asserted-by":"publisher","DOI":"10.1126\/science.aac5523","article-title":"Building Devices\nfrom Colloidal Quantum Dots","volume":"353","author":"Kagan","year":"2016","journal-title":"Science"},{"key":"2026090119224694600_cit13","doi-asserted-by":"publisher","first-page":"1900165","DOI":"10.1002\/lpor.201900165","article-title":"Acquisition\nof Hyperspectral Data\nwith Colloidal Quantum Dots","volume":"13","author":"Tang","year":"2019","journal-title":"Laser Photonics\nRev."},{"key":"2026090119224694600_cit14","doi-asserted-by":"publisher","first-page":"168","DOI":"10.1039\/C5NH00073D","article-title":"Exploiting\nthe Biological Windows: Current Perspectives on Fluorescent Bioprobes\nEmitting above 1000 nm","volume":"1","author":"Hemmer","year":"2016","journal-title":"Nanoscale Horiz."},{"key":"2026090119224694600_cit15","doi-asserted-by":"publisher","first-page":"456","DOI":"10.1038\/s41565-018-0117-z","article-title":"2D Matrix\nEngineering for Homogeneous Quantum Dot Coupling in Photovoltaic Solids","volume":"13","author":"Xu","year":"2018","journal-title":"Nat. Nanotechnol."},{"key":"2026090119224694600_cit16","doi-asserted-by":"publisher","first-page":"31","DOI":"10.1021\/acs.jpclett.5b02408","article-title":"Exciton Dynamics in\nInSb Colloidal\nQuantum Dots","volume":"7","author":"Sills","year":"2016","journal-title":"J. Phys. Chem. Lett."},{"key":"2026090119224694600_cit17","doi-asserted-by":"publisher","first-page":"235437","DOI":"10.1103\/PhysRevB.95.235437","article-title":"Universal\nBehavior of Electron g-Factors\nin Semiconductor Nanostructures","volume":"95","author":"Tadjine","year":"2017","journal-title":"Phys. Rev.\nB: Condens. Matter Mater. Phys."},{"key":"2026090119224694600_cit18","doi-asserted-by":"publisher","first-page":"195305","DOI":"10.1103\/PhysRevB.84.195305","article-title":"Measurement of the g-Factor Tensor\nin a Quantum Dot and Disentanglement of Exciton Spins","volume":"84","author":"Witek","year":"2011","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"2026090119224694600_cit19","doi-asserted-by":"publisher","first-page":"9170","DOI":"10.1021\/acs.chemrev.9b00075","article-title":"Synthesis\nand Applications of III-V Nanowires","volume":"119","author":"Barrigon\u0301","year":"2019","journal-title":"Chem. Rev."},{"key":"2026090119224694600_cit20","doi-asserted-by":"publisher","first-page":"4311","DOI":"10.1002\/adfm.201303390","article-title":"Tuning the Au-Free\nInSb Nanocrystal Morphologies Grown by Patterned Metal\u2013Organic\nChemical Vapor Deposition","volume":"24","author":"Lin","year":"2014","journal-title":"Adv. Funct. Mater."},{"key":"2026090119224694600_cit21","doi-asserted-by":"publisher","first-page":"3575","DOI":"10.1021\/acs.nanolett.9b00545","article-title":"High Mobility\nStemless InSb Nanowires","volume":"19","author":"Badawy","year":"2019","journal-title":"Nano Lett."},{"key":"2026090119224694600_cit22","doi-asserted-by":"publisher","first-page":"20258","DOI":"10.1021\/ja309821j","article-title":"Colloidal InSb Nanocrystals","volume":"134","author":"Liu","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"2026090119224694600_cit23","doi-asserted-by":"publisher","first-page":"1788","DOI":"10.1021\/cm400320r","article-title":"Colloidal Synthesis of InSb Nanocrystals with Controlled\nPolymorphism Using Indium and Antimony Amides","volume":"25","author":"Yarema","year":"2013","journal-title":"Chem. Mater."},{"key":"2026090119224694600_cit24","doi-asserted-by":"publisher","first-page":"15145","DOI":"10.1021\/jacs.9b06652","article-title":"General Synthetic Route to High-Quality\nColloidal III-V Semiconductor Quantum Dots Based on Pnictogen Chlorides","volume":"141","author":"Zhao","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"2026090119224694600_cit25","doi-asserted-by":"publisher","first-page":"5727","DOI":"10.1021\/cm702856v","article-title":"Synthesis\nand Use of Tris(trimethylsilyl)antimony for the Preparation of InSb\nQuantum Dots","volume":"20","author":"Evans","year":"2008","journal-title":"Chem. Mater."},{"key":"2026090119224694600_cit26","doi-asserted-by":"publisher","first-page":"828","DOI":"10.1002\/ppsc.201300137","article-title":"Synthesis of Colloidal\nIndium Antimonide Nanocrystals Using Stibine","volume":"30","author":"Maurice","year":"2013","journal-title":"Part. Part. Syst. Charact."},{"key":"2026090119224694600_cit27","doi-asserted-by":"publisher","first-page":"11110","DOI":"10.1039\/C8NR02381F","article-title":"Selective Antimony Reduction Initiating the Nucleation\nand Growth of InSb Quantum Dots","volume":"10","author":"Crisp","year":"2018","journal-title":"Nanoscale"},{"key":"2026090119224694600_cit28","doi-asserted-by":"publisher","first-page":"16923","DOI":"10.1039\/C5DT02181B","article-title":"Synthesis of Colloidal\nInSb Nanocrystals via in Situ Activation of InCl3.","volume":"44","author":"Tamang","year":"2015","journal-title":"Dalton Trans."},{"key":"2026090119224694600_cit29","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1016\/S0010-8545(00)00401-X","article-title":"The Chemistry\nof Group 13\/15 Compounds (III\u2013V Compounds) with the Higher\nHomologues of Group 15, Sb and Bi","volume":"215","author":"Schulz","year":"2001","journal-title":"Coord. Chem.\nRev."},{"key":"2026090119224694600_cit30","doi-asserted-by":"publisher","first-page":"2963","DOI":"10.1039\/DT9940002963","article-title":"Intramolecular versus Intermolecular\nBonding in Amidoantimony Dimers; Syntheses and Structures of {Sb(NMe2)[\u03bc-N(mpy)]}2 (mpy = 4-Methylpyridin-2-yl)\nand [Sb(NMe2){\u03bc-N[C6H2 (OMe)3-3,4,5]}]2","author":"Edwards","year":"1994","journal-title":"J. Chem. Soc.,\nDalton Trans."},{"key":"2026090119224694600_cit31","doi-asserted-by":"publisher","first-page":"4267","DOI":"10.1021\/acs.inorgchem.7b00523","article-title":"Synthesis and Crystal\nStructures\nof the First Antimony(III) Aziridinides","volume":"56","author":"Harmgarth","year":"2017","journal-title":"Inorg.\nChem."},{"key":"2026090119224694600_cit32","doi-asserted-by":"publisher","first-page":"10734","DOI":"10.1021\/ic061660t","article-title":"Bis(1-Amino)cyclodistib(III)azanes: The First Structural\nCharacterization of Cis and Trans Isomers of a Single Cyclodipnict(III)azane","volume":"45","author":"Eisler","year":"2006","journal-title":"Inorg. Chem."},{"key":"2026090119224694600_cit33","doi-asserted-by":"publisher","first-page":"1508","DOI":"10.1002\/anie.199615081","article-title":"[Sb12{(2-MeO)C6H4N}18]\u00b76 THF; A Twenty-Four Membered Imidoantimony(III) Metallacycle","volume":"35","author":"Beswick","year":"1996","journal-title":"Angew. Chem., Int. Ed. Engl."},{"key":"2026090119224694600_cit34","doi-asserted-by":"publisher","first-page":"4007","DOI":"10.1039\/b007020n","article-title":"Antimony Imido\nand Imido\u2013Amido Compounds: A\nNew Route to an Imidoantimony Macrocycle","author":"Bryant","year":"2000","journal-title":"J.\nChem. Soc., Dalton Trans."},{"key":"2026090119224694600_cit35","doi-asserted-by":"publisher","first-page":"9","DOI":"10.1002\/zaac.19673500103","article-title":"Die Kristall-\nund Moleku\u0308lstruktur von As4(NCH3)6","volume":"350","author":"Weiss","year":"1967","journal-title":"Z. Anorg.\nAllg. Chem."},{"key":"2026090119224694600_cit36","doi-asserted-by":"publisher","first-page":"5925","DOI":"10.1021\/acs.chemmater.6b02456","article-title":"Mechanistic\nInsight and Optimization of InP Nanocrystals Synthesized with Aminophosphines","volume":"28","author":"Buffard","year":"2016","journal-title":"Chem. Mater."},{"key":"2026090119224694600_cit37","doi-asserted-by":"publisher","first-page":"5035","DOI":"10.1021\/om960581u","article-title":"Synthesis and Characterization of\nPotential Single-Source\nPrecursors to Group 13 \u2013 Antimonides","volume":"15","author":"Baldwin","year":"1996","journal-title":"Organometallics"},{"key":"2026090119224694600_cit38","doi-asserted-by":"publisher","first-page":"121","DOI":"10.1023\/A:1022608802635","article-title":"Preparation of Nanocrystalline Indium\nAntimonide through t-Hydride Elimination from New Indium-Antimony\nSingle-Source Precursors","volume":"10","author":"Foos","year":"1999","journal-title":"J. Cluster Sci."},{"key":"2026090119224694600_cit39","doi-asserted-by":"publisher","first-page":"635","DOI":"10.1021\/cm5045144","article-title":"A General\nSynthesis Strategy for Monodisperse Metallic and Metalloid Nanoparticles\n(In, Ga, Bi, Sb, Zn, Cu, Sn and Their Alloys) via in Situ Formed Metal Long-Chain Amides","volume":"27","author":"He","year":"2015","journal-title":"Chem. Mater."},{"key":"2026090119224694600_cit40","doi-asserted-by":"publisher","first-page":"1512","DOI":"10.1039\/C0CS00055H","article-title":"Synthesis and Properties\nof Colloidal Heteronanocrystals","volume":"40","author":"Donega","year":"2011","journal-title":"Chem. Soc.\nRev."},{"key":"2026090119224694600_cit41","doi-asserted-by":"publisher","first-page":"1233","DOI":"10.1021\/cm3035642","article-title":"Conversion\nReactions of Cadmium Chalcogenide Nanocrystal Precursors","volume":"25","author":"Garci\u0301a-Rodri\u0301guez","year":"2013","journal-title":"Chem. Mater."},{"key":"2026090119224694600_cit42","doi-asserted-by":"publisher","first-page":"1351","DOI":"10.1021\/cm400005c","article-title":"Chemical Mechanisms of Semiconductor\nNanocrystal Synthesis","volume":"25","author":"Sowers","year":"2013","journal-title":"Chem. Mater."},{"key":"2026090119224694600_cit43","doi-asserted-by":"publisher","first-page":"7181","DOI":"10.1021\/acs.chemmater.6b03408","article-title":"Shining\nLight on Indium Phosphide Quantum Dots: Understanding the Interplay\namong Precursor Conversion, Nucleation, and Growth","volume":"28","author":"Cossairt","year":"2016","journal-title":"Chem. Mater."},{"key":"2026090119224694600_cit44","doi-asserted-by":"publisher","first-page":"559","DOI":"10.1002\/cphc.201500976","article-title":"Prospects\nof Colloidal Copper Chalcogenide Nanocrystals","volume":"17","author":"Van der Stam","year":"2016","journal-title":"ChemPhysChem"},{"key":"2026090119224694600_cit45","doi-asserted-by":"publisher","first-page":"3128","DOI":"10.1021\/la000856h","article-title":"Silver Nanoparticle\nFormation: Predictions and Verification of the Aggregative Growth\nModel","volume":"17","author":"Van Hyning","year":"2001","journal-title":"Langmuir"},{"key":"2026090119224694600_cit46","doi-asserted-by":"publisher","first-page":"1076","DOI":"10.1021\/nn901499c","article-title":"Nucleation\nand Growth of Gold Nanoparticles Studied via in Situ Small Angle X-Ray Scattering at Millisecond Time Resolution","volume":"4","author":"Polte","year":"2010","journal-title":"ACS Nano"},{"key":"2026090119224694600_cit47","doi-asserted-by":"publisher","first-page":"5791","DOI":"10.1021\/nn301724z","article-title":"Formation\nMechanism of Colloidal Silver Nanoparticles: Analogies and Differences\nto the Growth of Gold Nanoparticles","volume":"6","author":"Polte","year":"2012","journal-title":"ACS Nano"},{"key":"2026090119224694600_cit48","doi-asserted-by":"publisher","first-page":"1309","DOI":"10.1126\/science.1172104","article-title":"Observation\nof Single Colloidal Platinum\nNanocrystal Growth Trajectories","volume":"324","author":"Zheng","year":"2009","journal-title":"Science"},{"key":"2026090119224694600_cit49","doi-asserted-by":"publisher","first-page":"61","DOI":"10.1126\/science.1217654","article-title":"High-Resolution\nEM of Colloidal Nanocrystal Growth Using Graphene Liquid Cells","volume":"336","author":"Yuk","year":"2012","journal-title":"Science"},{"key":"2026090119224694600_cit50","doi-asserted-by":"publisher","first-page":"6705","DOI":"10.1021\/acs.chemmater.6b03098","article-title":"Shape Control\nof Colloidal Cu2-xS Polyhedral Nanocrystals by Tuning\nthe Nucleation Rates","volume":"28","author":"van der Stam","year":"2016","journal-title":"Chem. Mater."},{"key":"2026090119224694600_cit51","doi-asserted-by":"publisher","first-page":"16034","DOI":"10.1038\/natrevmats.2016.34","article-title":"Nonclassical Nucleation\nand Growth of Inorganic Nanoparticles","volume":"1","author":"Lee","year":"2016","journal-title":"Nat.\nRev. Mater."},{"key":"2026090119224694600_cit52","doi-asserted-by":"publisher","first-page":"5","DOI":"10.1021\/cm402139r","article-title":"Kinetics and Mechanisms\nof Aggregative Nanocrystal Growth","volume":"26","author":"Wang","year":"2014","journal-title":"Chem. Mater."},{"key":"2026090119224694600_cit53","doi-asserted-by":"publisher","first-page":"36","DOI":"10.1006\/jcis.1999.6106","article-title":"Mechanism\nof Formation of Monodispersed Colloids by Aggregation of Nanosize\nPrecursors","volume":"213","author":"Privman","year":"1999","journal-title":"J. Colloid Interface Sci."},{"key":"2026090119224694600_cit54","doi-asserted-by":"publisher","first-page":"051602","DOI":"10.1103\/PhysRevE.66.051602","article-title":"Nucleation Rates\nand Induction Times during Colloidal\nCrystallization: Links between Models and Experiments","volume":"66","author":"Dixit","year":"2002","journal-title":"Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip.\nTop."},{"key":"2026090119224694600_cit55","doi-asserted-by":"publisher","first-page":"959","DOI":"10.1021\/op0600759","article-title":"Lithium Aminoborohydrides:\nPowerful,\nSelective, Air-Stable Reducing Agents","volume":"10","author":"Pasumansky","year":"2006","journal-title":"Org.\nProcess Res. Dev."},{"key":"2026090119224694600_cit56","doi-asserted-by":"publisher","first-page":"7183","DOI":"10.1021\/acs.nanolett.7b01266","article-title":"Straight Indium Antimonide Nanowires with Twinning Superlattices via a Solution Route","volume":"17","author":"Qian","year":"2017","journal-title":"Nano Lett."},{"key":"2026090119224694600_cit57","doi-asserted-by":"publisher","first-page":"3493","DOI":"10.1002\/smll.201101819","article-title":"Two-Fold Emission\nfrom the S-Shell of PbSe(Core)\/CdSe(Shell)\nQuantum Dots","volume":"7","author":"Grodzinska","year":"2011","journal-title":"Small"},{"key":"2026090119224694600_cit58","doi-asserted-by":"publisher","first-page":"7120","DOI":"10.1103\/PhysRevB.58.7120","article-title":"Quantum Size Level\nStructure of Narrow-Gap Semiconductor Nanocrystals:\nEffect of Band Coupling","volume":"58","author":"Efros","year":"1998","journal-title":"Phys. Rev. B: Condens.\nMatter Mater. Phys."},{"key":"2026090119224694600_cit59","doi-asserted-by":"publisher","first-page":"51","DOI":"10.1016\/j.mssp.2014.06.017","article-title":"Tight-Binding\nTheory of the Excitonic States in Colloidal InSb Nanostructures","volume":"27","author":"Sukkabot","year":"2014","journal-title":"Mater. Sci. Semicond. Process."},{"key":"2026090119224694600_cit60","doi-asserted-by":"publisher","first-page":"8987","DOI":"10.1021\/ac0715064","article-title":"Quantitative\nAnalysis of Cadmium Selenide Nanocrystal Concentration by Comparative\nTechniques","volume":"79","author":"Kuc\u0327ur","year":"2007","journal-title":"Anal. Chem."},{"key":"2026090119224694600_cit61","doi-asserted-by":"publisher","first-page":"10337","DOI":"10.1021\/ja063166u","article-title":"Size-Dependent Extinction Coefficients of PbS Quantum\nDots","volume":"128","author":"Cademartiri","year":"2006","journal-title":"J. Am. Chem. Soc."},{"key":"2026090119224694600_cit62","doi-asserted-by":"publisher","first-page":"6101","DOI":"10.1021\/cm071410q","article-title":"Composition\nand Size-Dependent Extinction Coefficient of Colloidal PbSe Quantum\nDots","volume":"19","author":"Moreels","year":"2007","journal-title":"Chem. Mater."},{"key":"2026090119224694600_cit63","doi-asserted-by":"publisher","first-page":"6511","DOI":"10.1021\/jp811329r","article-title":"Size Dependence of the Spontaneous\nEmission Rate and Absorption Cross Section of CdSe and CdTe Quantum\nDots","volume":"113","author":"de Mello Donega","year":"2009","journal-title":"J. Phys. Chem. C"},{"key":"2026090119224694600_cit64","doi-asserted-by":"publisher","first-page":"19468","DOI":"10.1021\/jp906827m","article-title":"Re-Examination\nof the Size-Dependent Absorption Properties of CdSe Quantum Dots","volume":"113","author":"Jasieniak","year":"2009","journal-title":"J. Phys. Chem. C"},{"key":"2026090119224694600_cit65","doi-asserted-by":"publisher","first-page":"8350","DOI":"10.1021\/acsnano.8b03641","article-title":"Size-Dependent Band-Gap and Molar\nAbsorption Coefficients of Colloidal CuInS2 Quantum Dots","volume":"12","author":"Xia","year":"2018","journal-title":"ACS Nano"},{"key":"2026090119224694600_cit66","doi-asserted-by":"publisher","first-page":"2306","DOI":"10.1063\/1.476797","article-title":"Size-Dependent Electronic Level Structure of InAs Nanocrystal Quantum\nDots: Test of Multiband Effective Mass Theory","volume":"109","author":"Banin","year":"1998","journal-title":"J. Chem. Phys."},{"key":"2026090119224694600_cit67","doi-asserted-by":"publisher","first-page":"414","DOI":"10.1007\/s11664-999-0089-8","article-title":"Indirect Band\nGaps in Quantum Dots Made from Direct-Gap Bulk Materials","volume":"28","author":"Williamson","year":"1999","journal-title":"J. Electron. Mater."},{"key":"2026090119224694600_cit68","doi-asserted-by":"publisher","first-page":"8513","DOI":"10.1021\/nn5031274","article-title":"Carrier\nDynamics in Highly Quantum-Confined\nColloidal Indium Antimonide Nanocrystals","volume":"8","author":"Chang","year":"2014","journal-title":"ACS\nNano"},{"key":"2026090119224694600_cit69","doi-asserted-by":"publisher","first-page":"725","DOI":"10.1021\/nn5061805","article-title":"Size-Dependent Energy\nLevels of InSb Quantum Dots Measured by Scanning Tunneling Spectroscopy","volume":"9","author":"Wang","year":"2015","journal-title":"ACS Nano"},{"key":"2026090119224694600_cit70","doi-asserted-by":"publisher","first-page":"245321","DOI":"10.1103\/PhysRevB.70.245321","article-title":"Confinement Effects in PbSe Quantum Wells and Nanocrystals","volume":"70","author":"Allan","year":"2004","journal-title":"Phys. Rev. B: Condens. Matter Mater. Phys."},{"key":"2026090119224694600_cit71","doi-asserted-by":"publisher","first-page":"3023","DOI":"10.1021\/nn900863a","article-title":"Size-Dependent\nOptical Properties of Colloidal PbS Quantum Dots","volume":"3","author":"Moreels","year":"2009","journal-title":"ACS Nano"},{"key":"2026090119224694600_cit72","doi-asserted-by":"publisher","first-page":"2539","DOI":"10.1021\/nn9004507","article-title":"The Effect\nof Temperature and Dot Size on the Spectral Properties of Colloidal\nInP\/ZnS Core-Shell Quantum Dots","volume":"3","author":"Narayanaswamy","year":"2009","journal-title":"ACS Nano"},{"key":"2026090119224694600_cit73","doi-asserted-by":"publisher","first-page":"215201","DOI":"10.1088\/0957-4484\/24\/21\/215201","article-title":"Modeling on the Size\nDependent Properties of InP Quantum Dots: A Hybrid Functional Study","volume":"24","author":"Cho","year":"2013","journal-title":"Nanotechnology"},{"key":"2026090119224694600_cit74","doi-asserted-by":"publisher","first-page":"A330","DOI":"10.1103\/PhysRev.140.A330","article-title":"Electrical and Optical Properties\nof Epitaxial Films of PbS, PbSe, PbTe, and SnTe","volume":"140","author":"Zemel","year":"1965","journal-title":"Phys. Rev."},{"key":"2026090119224694600_cit75","doi-asserted-by":"publisher","first-page":"1057","DOI":"10.1016\/0038-1098(69)90470-0","article-title":"The Optical Frequencies and Dielectric\nConstants of InP","volume":"7","author":"Hilsum","year":"1969","journal-title":"Solid State Commun."}],"container-title":["ACS Nano"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsnano.0c04744","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/ancac3\/article-pdf\/14\/10\/13146\/67554241\/acsnano.0c04744.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/ancac3\/article-pdf\/14\/10\/13146\/67554241\/acsnano.0c04744.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,1]],"date-time":"2026-09-01T23:22:57Z","timestamp":1788304977000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/ancac3\/article\/14\/10\/13146\/883207\/Luminescent-Colloidal-InSb-Quantum-Dots-from-In"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,9,11]]},"references-count":75,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2020,9,11]]},"published-print":{"date-parts":[[2020,10,27]]}},"URL":"https:\/\/doi.org\/10.1021\/acsnano.0c04744","relation":{},"ISSN":["1936-0851","1936-086X"],"issn-type":[{"value":"1936-0851","type":"print"},{"value":"1936-086X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,9,11]]}}}