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Most of the 2D magnetic compounds discovered so far host only one single magnetic phase unless the system is at a phase boundary. In this work, we report the near degeneracy of magnetic phases in ultrathin chromium telluride (Cr2Te3) layers with strong perpendicular magnetic anisotropy highly desired for stabilizing 2D magnetic order. Single-crystalline Cr2Te3 nanoplates with a trigonal structure (space group P3\u03051c) were grown by chemical vapor deposition. The bulk magnetization measurements suggest a ferromagnetic (FM) order with an enhanced perpendicular magnetic anisotropy, as evidenced by a coercive field as large as \u223c14 kOe when the field is applied perpendicular to the basal plane of the thin nanoplates. Magneto-optical Kerr effect studies confirm the intrinsic ferromagnetism and characterize the magnetic ordering temperature of individual nanoplates. First-principles density functional theory calculations suggest the near degeneracy of magnetic orderings with a continuously varying canting from the c-axis FM due to their comparable energy scales, explaining the zero-field kink observed in the magnetic hysteresis loops. Our work highlights Cr2Te3 as a promising 2D Ising system to study magnetic phase coexistence and switches for ultracompact information storage and processing.<\/jats:p>","DOI":"10.1021\/acsnano.0c05534","type":"journal-article","created":{"date-parts":[[2020,10,30]],"date-time":"2020-10-30T10:50:33Z","timestamp":1604055033000},"page":"15256-15266","source":"Crossref","is-referenced-by-count":69,"title":["Near\nDegeneracy of Magnetic Phases in Two-Dimensional\nChromium Telluride with Enhanced Perpendicular Magnetic Anisotropy"],"prefix":"10.1021","volume":"14","author":[{"given":"Amanda\nL.","family":"Coughlin","sequence":"first","affiliation":[{"name":"Indiana University , , , ,","place":["Bloomington, Indiana, United States, 47405"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dongyue","family":"Xie","sequence":"additional","affiliation":[{"name":"University of Nebraska , , , ,","place":["Lincoln, Nebraska, United States, 68588"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue","family":"Yao","sequence":"additional","affiliation":[{"name":"University of Utah , , , ,","place":["Salt Lake City, Utah, United\nStates, 84112"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xun","family":"Zhan","sequence":"additional","affiliation":[{"name":"Indiana University , , , ,","place":["Bloomington, Indiana, United States, 47405"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiang","family":"Chen","sequence":"additional","affiliation":[{"name":"University of Tennessee , , , ,","place":["Knoxville, Tennessee, United States, 37996"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Heshan","family":"Hewa-Walpitage","sequence":"additional","affiliation":[{"name":"University of Utah , , , ,","place":["Salt Lake City, Utah, United\nStates, 84112"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaohang","family":"Zhang","sequence":"additional","affiliation":[{"name":"University of Maryland , , , ,","place":["College Park, Maryland, United States, 20742"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hua","family":"Guo","sequence":"additional","affiliation":[{"name":"Rice University , , , ,","place":["Houston, Texas, United States, 77005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haidong","family":"Zhou","sequence":"additional","affiliation":[{"name":"University of Tennessee , , , ,","place":["Knoxville, Tennessee, United States, 37996"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4351-9561","authenticated-orcid":true,"given":"Jun","family":"Lou","sequence":"additional","affiliation":[{"name":"Rice University , , , ,","place":["Houston, Texas, United States, 77005"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian","family":"Wang","sequence":"additional","affiliation":[{"name":"University of Nebraska , , , ,","place":["Lincoln, Nebraska, United States, 68588"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan S.","family":"Li","sequence":"additional","affiliation":[{"name":"University of Utah , , , ,","place":["Salt Lake City, Utah, United\nStates, 84112"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Herbert A.","family":"Fertig","sequence":"additional","affiliation":[{"name":"Indiana University , , , ,","place":["Bloomington, Indiana, United States, 47405"]},{"name":"Indiana University , , , ,","place":["Bloomington, Indiana, United\nStates, 47405"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1004-0597","authenticated-orcid":true,"given":"Shixiong","family":"Zhang","sequence":"additional","affiliation":[{"name":"Indiana University , , , ,","place":["Bloomington, Indiana, United States, 47405"]},{"name":"Rice University , , , ,","place":["Houston, Texas, United States, 77005"]},{"name":"Indiana University , , , ,","place":["Bloomington, Indiana, United\nStates, 47405"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2020,10,30]]},"reference":[{"key":"2026081720104144700_cit1","doi-asserted-by":"publisher","first-page":"117","DOI":"10.1103\/PhysRev.65.117","article-title":"Crystal Statistics.\nI. 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Lett."},{"key":"2026081720104144700_cit3","doi-asserted-by":"publisher","first-page":"311","DOI":"10.1016\/0040-6090(89)90845-6","article-title":"Evidence for\nPerpendicular Magnetic Anisotropy in Fe\n(110) Epitaxial Films in the Monolayer Range on Gold","volume":"175","author":"Lugert","year":"1989","journal-title":"Thin Solid Films"},{"key":"2026081720104144700_cit4","doi-asserted-by":"publisher","first-page":"579","DOI":"10.1007\/BF00616983","article-title":"Ferromagnetic\nOrder and Critical Behavior at Surfaces of Ultrathin Epitaxial Films","volume":"49","author":"Rau","year":"1989","journal-title":"Appl. Phys. A: Solids Surf."},{"key":"2026081720104144700_cit5","doi-asserted-by":"publisher","first-page":"1909","DOI":"10.1016\/0304-8853(92)91600-X","article-title":"Spin Polarised\nNeutron Reflection Studies of Ultrathin Magnetic Films","volume":"104","author":"Bland","year":"1992","journal-title":"J. Magn. Magn. Mater."},{"key":"2026081720104144700_cit6","doi-asserted-by":"publisher","first-page":"265","DOI":"10.1038\/nature22060","article-title":"Discovery\nof Intrinsic Ferromagnetism in Two-Dimensional Van Der Waals Crystals","volume":"546","author":"Gong","year":"2017","journal-title":"Nature"},{"key":"2026081720104144700_cit7","doi-asserted-by":"publisher","first-page":"270","DOI":"10.1038\/nature22391","article-title":"Layer-Dependent Ferromagnetism in\na Van Der Waals Crystal Down to the Monolayer Limit","volume":"546","author":"Huang","year":"2017","journal-title":"Nature"},{"key":"2026081720104144700_cit8","first-page":"493","article-title":"Destruction\nof Long Range Order in One-Dimensional and Two-Dimensional Systems\nHaving a Continuous Symmetry Group. I. Classical Systems","volume":"32","author":"Berezinsky","year":"1970","journal-title":"Zh. Eksp. Teor. Fiz."},{"key":"2026081720104144700_cit9","doi-asserted-by":"publisher","first-page":"1181","DOI":"10.1088\/0022-3719\/6\/7\/010","article-title":"Ordering, Metastability and Phase Transitions in Two-Dimensional\nSystems","volume":"6","author":"Kosterlitz","year":"1973","journal-title":"J. Phys. C: Solid State Phys."},{"key":"2026081720104144700_cit10","doi-asserted-by":"publisher","first-page":"1133","DOI":"10.1103\/PhysRevLett.17.1133","article-title":"Absence of Ferromagnetism\nor Antiferromagnetism in\nOne-or Two-Dimensional Isotropic Heisenberg Models","volume":"17","author":"Mermin","year":"1966","journal-title":"Phys. Rev. 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Adv."},{"key":"2026081720104144700_cit20","doi-asserted-by":"publisher","first-page":"3823","DOI":"10.1021\/acs.nanolett.8b01105","article-title":"Valley Manipulation\nby Optically Tuning the Magnetic Proximity Effect in Wse2\/Cri3 Heterostructures","volume":"18","author":"Seyler","year":"2018","journal-title":"Nano Lett."},{"key":"2026081720104144700_cit21","doi-asserted-by":"publisher","first-page":"549","DOI":"10.1038\/s41565-018-0135-x","article-title":"Controlling Magnetism\nin 2d Cri 3 by Electrostatic Doping","volume":"13","author":"Jiang","year":"2018","journal-title":"Nat. Nanotechnol."},{"key":"2026081720104144700_cit22","doi-asserted-by":"publisher","first-page":"554","DOI":"10.1038\/s41565-018-0186-z","article-title":"Electric-Field\nControl\nof Magnetism in a Few-Layered Van Der Waals Ferromagnetic Semiconductor","volume":"13","author":"Wang","year":"2018","journal-title":"Nat. Nanotechnol."},{"key":"2026081720104144700_cit23","doi-asserted-by":"publisher","first-page":"144404","DOI":"10.1103\/PhysRevB.92.144404","article-title":"Magnetic Correlations\nin the Quasi-Two-Dimensional\nSemiconducting Ferromagnet Crsite 3","volume":"92","author":"Williams","year":"2015","journal-title":"Phys. Rev.\nB: Condens. Matter Mater. Phys."},{"key":"2026081720104144700_cit24","doi-asserted-by":"publisher","first-page":"7433","DOI":"10.1021\/acs.nanolett.6b03052","article-title":"Ising-Type Magnetic\nOrdering in Atomically Thin Feps3","volume":"16","author":"Lee","year":"2016","journal-title":"Nano Lett."},{"key":"2026081720104144700_cit25","doi-asserted-by":"publisher","first-page":"031009","DOI":"10.1088\/2053-1583\/3\/3\/031009","article-title":"Raman Spectroscopy\nof Atomically Thin Two-Dimensional Magnetic Iron Phosphorus Trisulfide\n(Feps3)","volume":"3","author":"Wang","year":"2016","journal-title":"2D Mater."},{"key":"2026081720104144700_cit26","doi-asserted-by":"publisher","first-page":"032601","DOI":"10.1063\/1.4942637","article-title":"Room Temperature Weak Ferromagnetism\nin Sn1\u2013\nXmnxse2 2d Films Grown by Molecular Beam Epitaxy","volume":"4","author":"Dong","year":"2016","journal-title":"APL Mater."},{"key":"2026081720104144700_cit27","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1038\/s41467-017-02077-z","article-title":"A Two-Dimensional Fe-Doped\nSns 2 Magnetic Semiconductor","volume":"8","author":"Li","year":"2017","journal-title":"Nat. Commun."},{"key":"2026081720104144700_cit28","doi-asserted-by":"publisher","first-page":"35368","DOI":"10.1021\/acsami.7b08499","article-title":"Two-Dimensional Magnetic\nSemiconductor in Feroxyhyte","volume":"9","author":"Khan","year":"2017","journal-title":"ACS Appl. 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Soc."},{"key":"2026081720104144700_cit44","doi-asserted-by":"publisher","first-page":"1","DOI":"10.1063\/5.0014865","article-title":"Electrically Tunable, High Curie\nTemperature 2d Ferromagnetism in Van Der Waals Layered Crystals","volume":"117","author":"Qi","year":"2018","journal-title":"Appl. Phys. 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