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Among these, on-surface synthesized two-dimensional conjugated polymers (2DCPs) with Kagome\u0301 lattice symmetry have recently emerged as promising candidates, thanks to their ability to form large, ordered domains and their unique electronic structures featuring both flat bands and Dirac cones. In this work, we report the integration of atomically thin, surface-confined 2DCPs into field-effect transistors (FETs), marking a step toward their use in functional devices. The fabricated FETs exhibit ohmic transport behavior with Pt contacts and reveal ambipolar graphene-like field-induced conductivity modulation, directly linked to the Dirac cone in the electronic band structure. These findings are supported by ab initio density functional theory (DFT) calculations and finite element simulations of the drift-diffusion equation, confirming the transport characteristics. Our results highlight the potential of 2DCPs with Kagome\u0301 lattice symmetry as highly tunable, organic systems for future applications in nanoelectronics and high-performance sensing.<\/jats:p>","DOI":"10.1021\/acsnano.6c02365","type":"journal-article","created":{"date-parts":[[2026,7,17]],"date-time":"2026-07-17T16:17:12Z","timestamp":1784305032000},"page":"21093-21102","source":"Crossref","is-referenced-by-count":0,"title":["Atomically\nThin Two-Dimensional \u03c0-Conjugated\nKagome\u0301 Polymers with Dirac Cone-Driven Charge Transport"],"prefix":"10.1021","volume":"20","author":[{"given":"Dominik","family":"Dettmann","sequence":"first","affiliation":[{"name":"Institut National de la Recherche Scientifique Department , , 1650 Boulevard Lionel-Boulet , , ,","place":["Varennes, Que\u0301bec, Canada, J3X 1P7"]},{"name":"Istituto di Struttura della Materia-CNR (ISM-CNR) , via Fosso del Cavaliere 100 , ,","place":["Roma, Italy, 00133"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alessandro","family":"Pecchia","sequence":"additional","affiliation":[{"name":"National Research Council , , Via Salaria Km 29.300 , , Monterotondo, ,","place":["Roma, Italy, 00017"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Andrea","family":"Notargiacomo","sequence":"additional","affiliation":[{"name":"National Research Council , , Via del Fosso del Cavaliere, 100 , ,","place":["Roma, Italy, 00133"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Marialilia","family":"Pea","sequence":"additional","affiliation":[{"name":"National Research Council , , Via del Fosso del Cavaliere, 100 , ,","place":["Roma, Italy, 00133"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5009-9147","authenticated-orcid":true,"given":"Stefano","family":"Franchi","sequence":"additional","affiliation":[{"name":"Istituto di Struttura della Materia-CNR (ISM-CNR) , via Fosso del Cavaliere 100 , ,","place":["Roma, Italy, 00133"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1074-0411","authenticated-orcid":true,"given":"Michele","family":"Re Fiorentin","sequence":"additional","affiliation":[{"name":"Politecnico di Torino , , Corso Duca degli Abruzzi 24 , ,","place":["Torino, Italy, 10129"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ehsan","family":"Hamzehpoor","sequence":"additional","affiliation":[{"name":"Universite\u0301 de Montre\u0301al , , 1375 Avenue The\u0301re\u0300se-Lavoie-Roux , , ,","place":["Montre\u0301al, Que\u0301bec, Canada, H2 V 0B3"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Aleksandar","family":"Mikov","sequence":"additional","affiliation":[{"name":"McGill University , , 801 Sherbrooke Street West , , ,","place":["Montreal, Quebec, Canada, H3A 0B8"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2899-5495","authenticated-orcid":true,"given":"Navathej","family":"Preetha Genesh","sequence":"additional","affiliation":[{"name":"Institut National de la Recherche Scientifique Department , , 1650 Boulevard Lionel-Boulet , , ,","place":["Varennes, Que\u0301bec, Canada, J3X 1P7"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Gianluca","family":"Galeotti","sequence":"additional","affiliation":[{"name":"Institut National de la Recherche Scientifique Department , , 1650 Boulevard Lionel-Boulet , , ,","place":["Varennes, Que\u0301bec, Canada, J3X 1P7"]},{"name":"Istituto di Struttura della Materia-CNR (ISM-CNR) , via Fosso del Cavaliere 100 , ,","place":["Roma, Italy, 00133"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Barbara","family":"Paci","sequence":"additional","affiliation":[{"name":"Istituto di Struttura della Materia-CNR (ISM-CNR) , via Fosso del Cavaliere 100 , ,","place":["Roma, Italy, 00133"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tarnjit K.","family":"Johal","sequence":"additional","affiliation":[{"name":"Institut National de la Recherche Scientifique Department , , 1650 Boulevard Lionel-Boulet , , ,","place":["Varennes, Que\u0301bec, Canada, J3X 1P7"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Valerio","family":"Di Palma","sequence":"additional","affiliation":[{"name":"University of Milano\u2500Bicocca , , Via R. 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