{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,11,14]],"date-time":"2026-11-14T12:46:29Z","timestamp":1794660389732,"version":"4.9.1"},"reference-count":85,"publisher":"American Chemical Society (ACS)","issue":"29","license":[{"start":{"date-parts":[[2026,7,12]],"date-time":"2026-07-12T00:00:00Z","timestamp":1783814400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,12]],"date-time":"2026-07-12T00:00:00Z","timestamp":1783814400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,12]],"date-time":"2026-07-12T00:00:00Z","timestamp":1783814400000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key R&D Program of China","doi-asserted-by":"crossref","id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"crossref"}]},{"name":"State Key Laboratory of New Ceramic Materials Tsinghua University"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,7,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>P2-type layered transition metal oxides (NaxTMO2 TM are transition metal elements) are air-stability and low-cost but intrinsically limited in capacity, necessitating elevated charging voltages to unlock deeper Na+ extraction and higher energy density. However, practical high-voltage operation over wide temperature ranges is impeded by sluggish Na+ desolvation, aggravated parasitic reactions, and rapid cycling degradation. Here, we identify 1,1,1-trifluoro-N,N-dimethylmethanesulfonamide (Me2TFMSA) as a polar inducer that restructures Na+ solvation by confining carbonate molecules predominantly within the first solvation sheath, suppressing free-carbonate preferential accumulation at the cathode interface and enabling rapid ligand exchange during desolvation, while FSI\u2013 coordination forms an aggregate-rich solvation structure with weakened Na+\u2013solvent interaction. This confining solvation electrolyte (CSE) allows a 4.3 V cutoff (vs 4.1 V conventionally) and delivers a 25.8% capacity gain for P2-type Na0.6[Mg0.04Ca0.02Ti0.1Mn0.55Ni0.29]O2 (NaNMO) cathodes, effectively suppressing parasitic reactions, transition-metal dissolution, surface phase reconstruction, and impedance growth. In 4.3-V-class Ah-level hard carbon||NaNMO pouch cells with the CSE deliver 74.8% capacity retention after 800 cycles at 0.5 C, whereas conventional carbonate electrolytes fail within 200 cycles. Stable performance is achieved from \u221230 to 45 \u00b0C, with good cycling performance at \u221220 \u00b0C. These results correlate solvation confinement with interfacial stability and 4.3-V-class pouch-cell performance in P2-type sodium-ion batteries.<\/jats:p>","DOI":"10.1021\/acsnano.6c03000","type":"journal-article","created":{"date-parts":[[2026,7,12]],"date-time":"2026-07-12T13:04:21Z","timestamp":1783861461000},"page":"20585-20598","source":"Crossref","is-referenced-by-count":4,"title":["Confined\nSolvation Electrolyte for 4.3-V-Class High-Voltage\nSodium-Ion Pouch Cells"],"prefix":"10.1021","volume":"20","author":[{"given":"Chenxi","family":"Liu","sequence":"first","affiliation":[{"name":"Xi\u2019an Jiaotong University , , , ,","place":["Xi\u2019an, Shaanxi, China, 710049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ting","family":"Ma","sequence":"additional","affiliation":[{"name":"Inner Mongolia University , , ,","place":["Hohhot, China, 010021"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xue","family":"Han","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6736-355X","authenticated-orcid":true,"given":"Yao","family":"Li","sequence":"additional","affiliation":[{"name":"Shanghai Jiao Tong University , , ,","place":["Shanghai, China, 200240"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9084-6776","authenticated-orcid":true,"given":"Ding","family":"Nan","sequence":"additional","affiliation":[{"name":"Inner Mongolia University , , ,","place":["Hohhot, China, 010021"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3060-4580","authenticated-orcid":true,"given":"Weijiang","family":"Xue","sequence":"additional","affiliation":[{"name":"Xi\u2019an Jiaotong University , , , ,","place":["Xi\u2019an, Shaanxi, China, 710049"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,12]]},"reference":[{"key":"2026072810081078600_cit1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-67352-w","article-title":"Architected Continuum Mixed Ionic and Electronic Conducting Alloy\nNegative Electrode for Fast-Charging All-Solid-State Lithium Batteries","volume":"17","author":"Liu","year":"2026","journal-title":"Nat. Commun."},{"key":"2026072810081078600_cit2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202511223","article-title":"Sparingly\nSolvating Electrolyte with Hofmeister Selectivity for Practical Long-Lived\nLi-Se Batteries","volume":"64","author":"Zhang","year":"2025","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026072810081078600_cit3","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2024.110052","article-title":"Challenges\nand Industrial Perspectives on the Development of Sodium Ion Batteries","volume":"129","author":"Cai","year":"2024","journal-title":"Nano Energy"},{"key":"2026072810081078600_cit4","doi-asserted-by":"publisher","first-page":"215","DOI":"10.1038\/s41560-023-01215-w","article-title":"Opportunities\nfor Moderate-Range\nElectric Vehicles Using Sustainable Sodium-Ion Batteries","volume":"8","author":"Rudola","year":"2023","journal-title":"Nat. Energy"},{"key":"2026072810081078600_cit5","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-021-22523-3","article-title":"Tuning\nLocal Chemistry of P2 Layered-Oxide Cathode for High Energy and Long\nCycles of Sodium-Ion Battery","volume":"12","author":"Wang","year":"2021","journal-title":"Nat. Commun."},{"key":"2026072810081078600_cit6","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202411618","article-title":"A Customized Strategy Realizes Stable\nCycle of Large-Capacity and\nHigh-Voltage Layered Cathode for Sodium-Ion Batteries","volume":"63","author":"Peng","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026072810081078600_cit7","doi-asserted-by":"publisher","first-page":"24797","DOI":"10.1039\/D4RA04790G","article-title":"Recent Progress in High-Voltage P2-NaXTMO2 Materials\nand Their Future Perspectives","volume":"14","author":"Li","year":"2024","journal-title":"RSC Adv."},{"key":"2026072810081078600_cit8","doi-asserted-by":"publisher","first-page":"14511","DOI":"10.1002\/anie.202003972","article-title":"Realizing Complete Solid-Solution\nReaction in High Sodium Content\nP2-Type Cathode for High-Performance Sodium-Ion Batteries","volume":"59","author":"Jin","year":"2020","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026072810081078600_cit9","doi-asserted-by":"publisher","first-page":"10356","DOI":"10.1021\/jacs.5c10619","article-title":"Out-of-Plane\nSymmetry Design Arrests Structural Evolution in Layered-Type Framework\nfor Sustainable Sodium Shuttling","volume":"148","author":"Ren","year":"2026","journal-title":"J. Am. Chem.\nSoc."},{"key":"2026072810081078600_cit10","doi-asserted-by":"publisher","first-page":"11228","DOI":"10.1021\/jacs.5c23314","article-title":"Regulating Na-Ion Occupations of P-Type Na0.67Ti0.10Fe0.05Mn0.85O2 for\nImproving Electrochemical Reversibility and Kinetics","volume":"148","author":"Xiao","year":"2026","journal-title":"J. Am. Chem. Soc."},{"key":"2026072810081078600_cit11","doi-asserted-by":"publisher","first-page":"15605","DOI":"10.1021\/jacs.5c20111","article-title":"Rational Design\nof High-Na P2-Type Cathodes for Sodium-Ion Batteries: Unveiling Phase\nFormation Principles and Composition\u2013Structure\u2013Performance\nCorrelations","volume":"148","author":"Zhou","year":"2026","journal-title":"J. Am. Chem. Soc."},{"key":"2026072810081078600_cit12","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.157032","article-title":"Study on the Impact\nof Cutoff Voltage on Structural and Electrochemical Stability of Sodium-Ion\nLayered Cathodes","volume":"500","author":"Wang","year":"2024","journal-title":"Chem. Eng. J."},{"key":"2026072810081078600_cit13","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202205045","article-title":"Anion-Reinforced Solvation for a\nGradient Inorganic-Rich Interphase\nEnables High-Rate and Stable Sodium Batteries","volume":"61","author":"Zhou","year":"2022","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026072810081078600_cit14","doi-asserted-by":"publisher","first-page":"10","DOI":"10.1016\/j.ensm.2022.07.030","article-title":"Precisely Modulating the Structural Stability and Redox Potential\nof Sodium Layered Cathodes through the Synergetic Effect of Co-Doping\nStrategy","volume":"52","author":"Cheng","year":"2022","journal-title":"Energy Storage Mater."},{"key":"2026072810081078600_cit15","doi-asserted-by":"publisher","first-page":"3212","DOI":"10.1021\/acsenergylett.0c01712","article-title":"Highly\nReversible Sodium Ion Batteries Enabled by Stable Electrolyte-Electrode\nInterphases","volume":"5","author":"Jin","year":"2020","journal-title":"ACS Energy Lett."},{"key":"2026072810081078600_cit16","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2024.109389","article-title":"Stabilizing Cathode-Electrolyte Interphase\nby Localized High-Concentration\nElectrolytes for High-Voltage Sodium-Ion Batteries","volume":"123","author":"Liu","year":"2024","journal-title":"Nano Energy"},{"key":"2026072810081078600_cit17","doi-asserted-by":"publisher","first-page":"12061","DOI":"10.1021\/jacs.4c18374","article-title":"Inner-Outer Sheath Synergistic Shielding\nof Polysulfides in Asymmetric Solvent-Based Electrolytes for Stable\nSodium-Sulfur Batteries","volume":"147","author":"Yao","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026072810081078600_cit18","doi-asserted-by":"publisher","first-page":"4655","DOI":"10.1021\/acsenergylett.4c01560","article-title":"Ternary Electrolyte\nEnables High-Voltage and High-Temperature Na-Ion Batteries","volume":"9","author":"Ma","year":"2024","journal-title":"ACS Energy Lett."},{"key":"2026072810081078600_cit19","doi-asserted-by":"publisher","first-page":"718","DOI":"10.1038\/s41560-022-01055-0","article-title":"Low-Solvation Electrolytes for High-Voltage Sodium-Ion\nBatteries","volume":"7","author":"Jin","year":"2022","journal-title":"Nat. Energy"},{"key":"2026072810081078600_cit20","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202311475","article-title":"Inorganic\nSodium Solid Electrolytes: Structure Design, Interface Engineering\nand Application","volume":"36","author":"Liu","year":"2024","journal-title":"Adv. Mater."},{"key":"2026072810081078600_cit21","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202405301","article-title":"Electrolyte Design Strategies to\nConstruct Stable Cathode-Electrolyte Interphases for High-Voltage\nSodium-Ion Batteries","volume":"15","author":"Xie","year":"2025","journal-title":"Adv. Energy Mater."},{"key":"2026072810081078600_cit22","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-022-30113-0","article-title":"Entropy\nand Crystal-Facet Modulation of P2-Type Layered Cathodes for Long-Lasting\nSodium-Based Batteries","volume":"13","author":"Fu","year":"2022","journal-title":"Nat. Commun."},{"key":"2026072810081078600_cit23","doi-asserted-by":"publisher","first-page":"5376","DOI":"10.1021\/acs.chemmater.8b03270","article-title":"P3 Na0.9Ni0.5Mn0.5O2 Cathode Material for Sodium\nIon Batteries","volume":"31","author":"Risthaus","year":"2019","journal-title":"Chem. Mater."},{"key":"2026072810081078600_cit24","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202410080","article-title":"Surface Gradient Desodiation\nChemistry in Layered Oxide Cathode Materials","volume":"63","author":"Jiang","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026072810081078600_cit25","doi-asserted-by":"publisher","first-page":"44060","DOI":"10.1021\/jacs.5c10193","article-title":"Tailored Interphase Chemistry Enables Ultra-Stable O3-Type Sodium\nLayered Oxide Cathodes","volume":"147","author":"Yang","year":"2025","journal-title":"J. Am. Chem. Soc."},{"key":"2026072810081078600_cit26","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202312287","article-title":"Pentafluoro(Phenoxy)Cyclotriphosphazene\nStabilizes Electrode\/Electrolyte Interfaces for Sodium-Ion Pouch Cells\nof 145 Wh kg\u20131","volume":"36","author":"Liao","year":"2024","journal-title":"Adv. Mater."},{"key":"2026072810081078600_cit27","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202512236","article-title":"Dilute Electrolyte with Vehicular\nAggregates for Stable High-Energy Lithium-Metal Batteries","author":"Han","year":"2025","journal-title":"Adv. Mater."},{"key":"2026072810081078600_cit28","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202519965","article-title":"Fundamentals, Status, and Prospects of Liquid Organic Electrolytes\nfor High-Energy Sodium-Ion Batteries","volume":"38","author":"Cui","year":"2026","journal-title":"Adv. Mater."},{"key":"2026072810081078600_cit29","doi-asserted-by":"publisher","first-page":"6030","DOI":"10.1039\/D1EE01265G","article-title":"Stabilizing Electrode\u2013Electrolyte Interfaces\nto Realize High-Voltage\nLi||LiCoO2 Batteries by a Sulfonamide-Based Electrolyte","volume":"14","author":"Xue","year":"2021","journal-title":"Energy Environ. Sci."},{"key":"2026072810081078600_cit30","doi-asserted-by":"publisher","first-page":"495","DOI":"10.1038\/s41560-021-00792-y","article-title":"Ultra-high-voltage Ni-rich layered cathodes in practical\nLi metal batteries enabled by a sulfonamide-based electrolyte","volume":"6","author":"Xue","year":"2021","journal-title":"Nat. Energy"},{"key":"2026072810081078600_cit31","doi-asserted-by":"publisher","first-page":"2868","DOI":"10.1021\/acsenergylett.3c00706","article-title":"A Nonflammable Electrolyte\nfor High-Voltage Lithium Metal Batteries","volume":"8","author":"Zhang","year":"2023","journal-title":"ACS\nEnergy Lett."},{"key":"2026072810081078600_cit32","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202401615","article-title":"Electrolyte\nDesign for High-Voltage Lithium-Metal Batteries\nwith Synthetic Sulfonamide-Based Solvent and Electrochemically Active\nAdditives","volume":"36","author":"Kim","year":"2024","journal-title":"Adv. Mater."},{"issue":"19","key":"2026072810081078600_cit33","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202400761","article-title":"Reduction-Tolerance\nElectrolyte Design for High-Energy Lithium Batteries","volume":"63","author":"Sun","year":"2024","journal-title":"Angew. Chem., Int. Ed."},{"key":"2026072810081078600_cit34","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.75549","article-title":"Dimethylsulfamoyl Fluoride-Based Electrolyte with Dual Cathodic-Anodic\nStability for Sodium-Ion and Sodium-Metal Batteries","volume":"36","author":"Lee","year":"2026","journal-title":"Adv. Funct. Mater."},{"key":"2026072810081078600_cit35","doi-asserted-by":"publisher","first-page":"388","DOI":"10.1038\/s41565-024-01848-2","article-title":"Salt-in-Presalt\nElectrolyte Solutions for High-Potential Non-Aqueous Sodium Metal\nBatteries","volume":"20","author":"Li","year":"2025","journal-title":"Nat. Nanotechnol."},{"key":"2026072810081078600_cit36","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2024.101811","article-title":"Hybrid\nSolvating Electrolytes for Practical Sodium-Metal Batteries","volume":"9","author":"Chen","year":"2025","journal-title":"Joule"},{"key":"2026072810081078600_cit37","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202415611","article-title":"4.2 V O3-Layered\nCathodes in Sodium-Ion Pouch Cells\nEnabled by an Intermolecular-Reinforced Ether Electrolyte","volume":"37","author":"Cui","year":"2025","journal-title":"Adv. Mater."},{"key":"2026072810081078600_cit38","doi-asserted-by":"publisher","first-page":"495","DOI":"10.1038\/s41560-021-00792-y","article-title":"Ultra-High-Voltage Ni-Rich\nLayered Cathodes in Practical\nLi Metal Batteries Enabled by a Sulfonamide-Based Electrolyte","volume":"6","author":"Xue","year":"2021","journal-title":"Nat. Energy"},{"key":"2026072810081078600_cit39","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202515562","article-title":"4.5-V-Class Safe Lithium-Ion\nBatteries\nwith Silicon-Majority-Graphite Anodes Enabled by Self-Limiting Interphase","author":"Xu","year":"2025","journal-title":"Adv. Mater."},{"key":"2026072810081078600_cit40","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-026-70592-z","article-title":"Asymmetric Sulfonamide\nDesign Enabling High-Voltage\nSodium-Ion Pouch Cells in Wide Temperature","volume":"17","author":"Cui","year":"2026","journal-title":"Nat. Commun."},{"key":"2026072810081078600_cit41","doi-asserted-by":"publisher","first-page":"5542","DOI":"10.1021\/acsenergylett.5c02840","article-title":"High-Entropy-Driven\nSolvation Engineering for Sodium Ion Full Cell","volume":"10","author":"Niu","year":"2025","journal-title":"ACS Energy Lett."},{"key":"2026072810081078600_cit42","doi-asserted-by":"publisher","DOI":"10.1038\/srep12085","article-title":"Small-Angle X-Ray Scattering Method\nto Characterize\nMolecular Interactions: Proof of Concept","volume":"5","author":"Allec","year":"2015","journal-title":"Sci.\nRep."},{"key":"2026072810081078600_cit43","doi-asserted-by":"publisher","first-page":"42","DOI":"10.1016\/j.molliq.2009.11.001","article-title":"Medium-Range Order in Al-Based Liquid Binary Alloys","volume":"151","author":"Roik","year":"2010","journal-title":"J. Mol. Liq."},{"key":"2026072810081078600_cit44","doi-asserted-by":"publisher","first-page":"987","DOI":"10.1038\/s41560-024-01565-z","article-title":"Towards Long-Life 500 Wh kg\u20131 Lithium\nMetal Pouch Cells Via Compact Ion-Pair Aggregate Electrolytes","volume":"9","author":"Jie","year":"2024","journal-title":"Nat. Energy"},{"key":"2026072810081078600_cit45","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2023.102815","article-title":"Suppressing the Formation\nof OP4 Phase in P2-Structured Na0.67Ni0.1Co0.1Mn0.8O2 by in-Situ Formed NiF2 Layer","volume":"60","author":"Ren","year":"2023","journal-title":"Energy Storage Mater."},{"key":"2026072810081078600_cit46","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2025.110993","article-title":"Introducing High-Valence Element\ninto P2-Type Layered Cathode Material\nfor High-Rate Sodium-Ion Batteries","volume":"36","author":"Kong","year":"2025","journal-title":"Chin. Chem.\nLett."},{"key":"2026072810081078600_cit47","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202406771","article-title":"Nonmetal\nSubstitution in Interstitial Site of O3-NaNi0.5Mn0.5O2 Induces the Generation of a Nearly Zero Strain P2&O3\nBiphasic Structure as Ultrastable Sodium-Ion Cathode","volume":"34","author":"Yu","year":"2024","journal-title":"Adv. Funct. Mater."},{"key":"2026072810081078600_cit48","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202408012","article-title":"Negative\nEnthalpy Doping Stabilizes P2-Type Oxides Cathode for High-Performance\nSodium-Ion Batteries","volume":"37","author":"Huang","year":"2025","journal-title":"Adv. Mater."},{"key":"2026072810081078600_cit49","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-025-61603-6","article-title":"Locking-Chain Electrolyte Additive Enabling Moisture-Tolerant\nElectrolytes for Sodium-Ion Batteries","volume":"16","author":"Li","year":"2025","journal-title":"Nat.\nCommun."},{"issue":"14","key":"2026072810081078600_cit50","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202517602","article-title":"Optimising Orbital Hybridization\nInduced Quenching Multistage Phase\nTransitions and Enhancing Redox Kinetics for Ultralow-Temperature\n(\u221270 \u00b0C) Sodium Storage","volume":"36","author":"Lai","year":"2025","journal-title":"Adv. Funct.\nMater."},{"key":"2026072810081078600_cit51","doi-asserted-by":"publisher","first-page":"4753","DOI":"10.1021\/acsenergylett.3c02075","article-title":"Converting Residual\nAlkali into Sodium Compensation\nAdditive for High-Energy Na-Ion Batteries","volume":"8","author":"Zhang","year":"2023","journal-title":"ACS\nEnergy Lett."},{"key":"2026072810081078600_cit52","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202509342","article-title":"Universal\nChemical Presodiation under Air Condition for Highly Stable\nNa-Deficient Oxide Cathodes","volume":"64","author":"Li","year":"2025","journal-title":"Angew. Chem., Int.\nEd."},{"key":"2026072810081078600_cit53","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202406184","article-title":"Gradient Structural Design Inducing Rocksalt Interface and P2\/P3\nBiphasic Bulk for Layered Oxide Cathode with Prolonged Sodium Ion\nStorage","author":"Yin","year":"2025","journal-title":"Adv. Energy Mater."},{"key":"2026072810081078600_cit54","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.162150","article-title":"Weakly Anion-Driven\nSolvation Towards Stable Operation of Carbonate Ester-Based Sodium\nMetal Batteries At \u2013 40 \u00b0C","volume":"511","author":"Huang","year":"2025","journal-title":"Chem.\nEng. J."},{"key":"2026072810081078600_cit55","doi-asserted-by":"publisher","first-page":"184","DOI":"10.1038\/s41560-023-01425-2","article-title":"Achieving a High-Performance Sodium-Ion Pouch Cell\nby Regulating Intergrowth Structures in a Layered Oxide Cathode with\nAnionic Redox","volume":"9","author":"Wang","year":"2024","journal-title":"Nat. Energy"},{"key":"2026072810081078600_cit56","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202502251","article-title":"Active Organic\nSalts Enabling Non-Intrusive Electrolyte Presodiation Strategy","volume":"37","author":"Chen","year":"2025","journal-title":"Adv. Mater."},{"key":"2026072810081078600_cit57","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2025.104197","article-title":"Thermal Runaway and Gas Venting Behaviors\nof Large-Format Prismatic Sodium-Ion Battery","volume":"77","author":"Li","year":"2025","journal-title":"Energy Storage Mater."},{"key":"2026072810081078600_cit58","doi-asserted-by":"publisher","first-page":"4349","DOI":"10.1021\/acsenergylett.3c01689","article-title":"Constructing\nMagnetic Ion Accelerator at Na2\/3Ni1\/3Mn2\/3O2 Surface for Sodium Ion Batteries","volume":"8","author":"Sun","year":"2023","journal-title":"ACS Energy Lett."},{"key":"2026072810081078600_cit59","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2021.230324","article-title":"Reversible OP4 Phase in P2\u2013Na2\/3Ni1\/3Mn2\/3O2 Sodium Ion Cathode","volume":"508","author":"Liu","year":"2021","journal-title":"J. Power Sources"},{"key":"2026072810081078600_cit60","doi-asserted-by":"publisher","first-page":"2997","DOI":"10.1007\/s12598-024-03196-5","article-title":"Medium-Entropy\nConfiguration Enabling Reversible P2-OP4\nphase Transition in Layered Oxides for High-Rate Sodium-Ion Batteries","volume":"44","author":"Hong","year":"2025","journal-title":"Rare Met."},{"key":"2026072810081078600_cit61","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202408642","article-title":"Deconstructing the High Voltage Degradation\nMechanisms\nin Na2\/3Ni1\/3Mn2\/3O2 with\nSingle Crystals and Advanced Electrolyte","volume":"34","author":"Darga","year":"2024","journal-title":"Adv.\nFunct. Mater."},{"key":"2026072810081078600_cit62","doi-asserted-by":"publisher","DOI":"10.1007\/s40820-025-01697-1","article-title":"Mechanisms and Mitigation Strategies of Gas\nGeneration in Sodium-Ion\nBatteries","volume":"17","author":"Li","year":"2025","journal-title":"Nanomicro Lett."},{"key":"2026072810081078600_cit63","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202503105","article-title":"Thermally Engineered Rock-Salt Surface\nNanolayer for Environmentally\nStable P2-Type Sodium-Ion Battery Cathodes","volume":"15","author":"Liang","year":"2025","journal-title":"Adv. Energy Mater."},{"key":"2026072810081078600_cit64","doi-asserted-by":"publisher","first-page":"8286","DOI":"10.1021\/jacs.2c02353","article-title":"Using High-Entropy\nConfiguration Strategy to Design Na-Ion Layered Oxide Cathodes with\nSuperior Electrochemical Performance and Thermal Stability","volume":"144","author":"Ding","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"2026072810081078600_cit65","doi-asserted-by":"publisher","DOI":"10.1002\/ente.202200547","article-title":"Detection of Lithium-Ion Cells\u2019\nDegradation through Deconvolution of Electrochemical Impedance Spectroscopy\nwith Distribution of Relaxation Time","volume":"10","author":"Iurilli","year":"2022","journal-title":"Energy\nTechnol."},{"key":"2026072810081078600_cit66","doi-asserted-by":"publisher","first-page":"8865","DOI":"10.1021\/acs.langmuir.3c00931","article-title":"Study of Predominant Dynamics on\nthe O3-Type Layered Transition-Metal Oxide Cathode by Electrochemical\nImpedance Spectroscopy for Sodium-Ion Batteries","volume":"39","author":"Li","year":"2023","journal-title":"Langmuir"},{"key":"2026072810081078600_cit67","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202502024","article-title":"Synergistic\nCathode\/Anode Interphase Stabilization Via Single-Cosolvent Engineering\nfor Fast-Charging and Durable Sodium-Ion Batteries","volume":"15","author":"Liu","year":"2025","journal-title":"Adv. Energy Mater."},{"key":"2026072810081078600_cit68","doi-asserted-by":"publisher","first-page":"2630","DOI":"10.1016\/j.chempr.2019.07.003","article-title":"Molecular\nDesign of Stable Sulfamide-\nand Sulfonamide-Based Electrolytes for Aprotic Li-O2 Batteries","volume":"5","author":"Feng","year":"2019","journal-title":"Chem"},{"key":"2026072810081078600_cit69","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2024.101811","article-title":"Hybrid Solvating Electrolytes for\nPractical Sodium-Metal Batteries","volume":"9","author":"Chen","year":"2025","journal-title":"Joule"},{"key":"2026072810081078600_cit70","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevA.38.3098","article-title":"Density-Functional\nExchange-Energy Approximation with Correct Asymptotic Behavior","volume":"38","author":"Becke","year":"1988","journal-title":"Phys. Rev. A"},{"key":"2026072810081078600_cit71","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785","article-title":"Development of the Colle-Salvetti\nCorrelation-Energy Formula into A Functional of the Electron Density","volume":"37","author":"Lee","year":"1988","journal-title":"Phys. Rev. B"},{"key":"2026072810081078600_cit72","doi-asserted-by":"publisher","first-page":"1456","DOI":"10.1002\/jcc.21759","article-title":"Effect of the Damping Function in\nDispersion Corrected Density Functional Theory","volume":"32","author":"Grimme","year":"2011","journal-title":"J. Comput. Chem."},{"key":"2026072810081078600_cit73","doi-asserted-by":"publisher","first-page":"33","DOI":"10.1016\/0263-7855(96)00018-5","article-title":"VMD: Visual Molecular Dynamics","volume":"14","author":"Humphrey","year":"1996","journal-title":"J. Mol. Graph."},{"key":"2026072810081078600_cit74","doi-asserted-by":"publisher","first-page":"580","DOI":"10.1002\/jcc.22885","article-title":"Multiwfn: A Multifunctional\nWavefunction Analyzer","volume":"33","author":"Lu","year":"2012","journal-title":"J. Comput. Chem."},{"key":"2026072810081078600_cit75","doi-asserted-by":"publisher","first-page":"73","DOI":"10.1002\/wcms.81","article-title":"The ORCA Program\nSystem","volume":"2","author":"Neese","year":"2012","journal-title":"WIREs Comput. Mol. Sci."},{"key":"2026072810081078600_cit76","doi-asserted-by":"publisher","first-page":"215","DOI":"10.1007\/s00214-007-0310-x","article-title":"The M06 Suite of\nDensity Functionals for Main Group\nThermochemistry, Thermochemical Kinetics, Noncovalent Interactions,\nExcited States, and Transition Elements: Two New Functionals and Systematic\nTesting of Four M06-Class Functionals and 12 Other Functionals","volume":"120","author":"Zhao","year":"2008","journal-title":"Theor. Chem. Acc."},{"key":"2026072810081078600_cit77","doi-asserted-by":"publisher","first-page":"3297","DOI":"10.1039\/b508541a","article-title":"Balanced Basis Sets of Split Valence,\nTriple Zeta Valence\nand Quadruple Zeta Valence Quality for H to Rn: Design and Assessment\nof Accuracy","volume":"7","author":"Weigend","year":"2005","journal-title":"Phys. Chem. Chem. Phys."},{"key":"2026072810081078600_cit78","doi-asserted-by":"publisher","first-page":"9982","DOI":"10.1063\/1.472933","article-title":"Rationale for Mixing Exact Exchange\nwith Density Functional Approximations","volume":"105","author":"Perdew","year":"1996","journal-title":"J. Chem.\nPhys."},{"key":"2026072810081078600_cit79","doi-asserted-by":"publisher","DOI":"10.1063\/1.3382344","article-title":"A Consistent and Accurate\nab Initio Parametrization of Density Functional Dispersion Correction\n(DFT-D) for the 94 Elements H-Pu","volume":"132","author":"Grimme","year":"2010","journal-title":"J. Chem. Phys."},{"key":"2026072810081078600_cit80","doi-asserted-by":"publisher","first-page":"314","DOI":"10.1016\/j.jmgm.2012.07.004","article-title":"Quantitative Analysis of Molecular Surface Based on Improved Marching\nTetrahedra Algorithm","volume":"38","author":"Lu","year":"2012","journal-title":"J. Mol. Graph. Model."},{"key":"2026072810081078600_cit81","doi-asserted-by":"publisher","first-page":"19","DOI":"10.1016\/j.softx.2015.06.001","article-title":"GROMACS: High\nPerformance\nMolecular Simulations Through Multi-Level Parallelism from Laptops\nto Supercomputers","volume":"1\u20132","author":"Abraham","year":"2015","journal-title":"SoftwareX"},{"key":"2026072810081078600_cit82","doi-asserted-by":"publisher","first-page":"1157","DOI":"10.1002\/jcc.20035","article-title":"Development\nand Testing of A General Amber Force Field","volume":"25","author":"Wang","year":"2004","journal-title":"J. Comput. Chem."},{"key":"2026072810081078600_cit83","doi-asserted-by":"publisher","first-page":"274","DOI":"10.1021\/acs.jctc.7b00785","article-title":"Harmonic Force Constants for Molecular\nMechanics Force Fields via Hessian Matrix Projection","volume":"14","author":"Allen","year":"2018","journal-title":"J. Chem. Theory Comput."},{"key":"2026072810081078600_cit84","doi-asserted-by":"publisher","DOI":"10.1063\/1.5121392","article-title":"A Force Field of Li+,\nNa+, K+, Mg2+, Ca2+, Cl\u2013, and SO42\u2013 in Aqueous\nSolution Based on the TIP4P\/2005 Water Model and Scaled Charges for\nThe Ions","volume":"151","author":"Zeron","year":"2019","journal-title":"J. Chem. Phys."},{"key":"2026072810081078600_cit85","doi-asserted-by":"publisher","first-page":"2157","DOI":"10.1002\/jcc.21224","article-title":"PACKMOL: A Package\nfor Building Initial Configurations for Molecular Dynamics Simulations","volume":"30","author":"Marti\u0301nez","year":"2009","journal-title":"J. Comput. Chem."}],"container-title":["ACS Nano"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsnano.6c03000","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/ancac3\/article-pdf\/20\/29\/20585\/65884478\/acsnano.6c03000.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/ancac3\/article-pdf\/20\/29\/20585\/65884478\/acsnano.6c03000.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,28]],"date-time":"2026-07-28T14:41:11Z","timestamp":1785249671000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/ancac3\/article\/20\/29\/20585\/5207016\/Confined-Solvation-Electrolyte-for-4-3-V-Class"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,12]]},"references-count":85,"journal-issue":{"issue":"29","published-online":{"date-parts":[[2026,7,12]]},"published-print":{"date-parts":[[2026,7,28]]}},"URL":"https:\/\/doi.org\/10.1021\/acsnano.6c03000","relation":{"has-part":[{"id-type":"doi","id":"https:\/\/doi.org\/10.1021\/acsnano.6c03000.s001","asserted-by":"subject"}]},"ISSN":["1936-0851","1936-086X"],"issn-type":[{"value":"1936-0851","type":"print"},{"value":"1936-086X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,12]]}}}