{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T00:47:43Z","timestamp":1789174063715,"version":"build-2803163510"},"reference-count":33,"publisher":"American Chemical Society (ACS)","issue":"29","license":[{"start":{"date-parts":[[2026,7,13]],"date-time":"2026-07-13T00:00:00Z","timestamp":1783900800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-029"},{"start":{"date-parts":[[2026,7,13]],"date-time":"2026-07-13T00:00:00Z","timestamp":1783900800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-037"},{"start":{"date-parts":[[2026,7,13]],"date-time":"2026-07-13T00:00:00Z","timestamp":1783900800000},"content-version":"stm-asf","delay-in-days":0,"URL":"https:\/\/doi.org\/10.15223\/policy-045"}],"funder":[{"DOI":"10.13039\/100000183","name":"Army Research Office","doi-asserted-by":"publisher","award":["W911NF-25-1-0201"],"award-info":[{"award-number":["W911NF-25-1-0201"]}],"id":[{"id":"10.13039\/100000183","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100006770","name":"American Chemical Society Petroleum Research Fund","doi-asserted-by":"publisher","award":["68244-DNI10"],"award-info":[{"award-number":["68244-DNI10"]}],"id":[{"id":"10.13039\/100006770","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","award":["DE-AC02-06CH11357"],"award-info":[{"award-number":["DE-AC02-06CH11357"]}],"id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation (NSF)","doi-asserted-by":"crossref","award":["DMR-2340751"],"award-info":[{"award-number":["DMR-2340751"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"crossref"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation (NSF)","doi-asserted-by":"crossref","award":["DMR-2442399"],"award-info":[{"award-number":["DMR-2442399"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":[],"published-print":{"date-parts":[[2026,7,28]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>Oxide twistronics extends moire\u0301 engineering beyond van der Waals materials, offering a promising platform for accessing emergent interfacial phenomena arising from the strong coupling of lattice, charge, and orbital degrees of freedom in complex oxides. However, deterministic fabrication of high-crystallinity oxide moire\u0301 superlattices over large lateral dimensions remains challenging due to the three-dimensional bonding network of oxides. Here, we demonstrate a scalable, generalized fabrication strategy that enables the formation of high-crystallinity oxide moire\u0301 superlattices with clean, chemically bonded interfaces and precisely controlled twist angles down to nominal values of 0.1\u00b0, achieving subdegree twist-angle accuracy across large contiguous lateral dimensions approaching the millimeter scale. Using NaNbO3 as a model system, we show that the resulting interlayer coupling drives pronounced structural reconstruction that modifies both the phase structure and ferroelectric domain configuration. Synchrotron-based X-ray 3D reciprocal space mapping reveals the emergence of a single-phase state in twisted bilayers, in contrast to the mixed-phase structure observed in single-layer membranes prior to twist assembly. The structural signatures are further consistent with gradual lattice rotation distributed along the thickness direction that may accommodate interfacial shear strain, distinct from reconstruction observed in van der Waals moire\u0301 systems which primarily occurs through in-plane stacking rearrangement. This collective lattice response is correlated with twist-dependent nanoscale electromechanical modulations observed by piezoresponse force microscopy. These results establish a scalable materials platform for oxide twistronics and support the implementation of twist-engineered functionalities in practical, macroscale device architectures.<\/jats:p>","DOI":"10.1021\/acsnano.6c04794","type":"journal-article","created":{"date-parts":[[2026,7,13]],"date-time":"2026-07-13T12:33:48Z","timestamp":1783946028000},"page":"20647-20655","source":"Crossref","is-referenced-by-count":1,"title":["Deterministic Fabrication\nof Large-Area, High-Crystallinity\nOxide Moire\u0301 Superlattices"],"prefix":"10.1021","volume":"20","author":[{"given":"Reza","family":"Ghanbari","sequence":"first","affiliation":[{"name":"North Carolina State University , , , ,","place":["Raleigh, North Carolina, United States, 27606"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Eli","family":"Rodrigues","sequence":"additional","affiliation":[{"name":"North Carolina State University , , , ,","place":["Raleigh, North Carolina, United States, 27606"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Young-Hoon","family":"Kim","sequence":"additional","affiliation":[{"name":"Oak Ridge National Laboratory , , , ,","place":["Oak Ridge, Tennessee, United States, 37830"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Konnor","family":"Koons","sequence":"additional","affiliation":[{"name":"North Carolina State University , , , ,","place":["Raleigh, North Carolina, United States, 27606"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9121-7077","authenticated-orcid":true,"given":"Yan","family":"Li","sequence":"additional","affiliation":[{"name":"Argonne National Laboratory , , , ,","place":["Lemont, Illinois, United States, 60439"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kabelo","family":"Lebogang","sequence":"additional","affiliation":[{"name":"North Carolina State University , , , ,","place":["Raleigh, North Carolina, United States, 27606"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yiming","family":"Ding","sequence":"additional","affiliation":[{"name":"North Carolina State University , , , ,","place":["Raleigh, North Carolina, United States, 27606"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Douglas W.","family":"Barefoot","sequence":"additional","affiliation":[{"name":"North Carolina State University , , , ,","place":["Raleigh, North Carolina, United States, 27606"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yueyin","family":"Wang","sequence":"additional","affiliation":[{"name":"North Carolina State University , , , ,","place":["Raleigh, North Carolina, United States, 27606"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5234-6922","authenticated-orcid":true,"given":"Yin","family":"Liu","sequence":"additional","affiliation":[{"name":"North Carolina State University , , , ,","place":["Raleigh, North Carolina, United States, 27606"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9642-8674","authenticated-orcid":true,"given":"Hua","family":"Zhou","sequence":"additional","affiliation":[{"name":"Argonne National Laboratory , , , ,","place":["Lemont, Illinois, United States, 60439"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miaofang","family":"Chi","sequence":"additional","affiliation":[{"name":"Oak Ridge National Laboratory , , , ,","place":["Oak Ridge, Tennessee, United States, 37830"]},{"name":"Duke University , , , ,","place":["Durham, North Carolina, United States, 27708"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5046-0599","authenticated-orcid":true,"given":"Ruijuan","family":"Xu","sequence":"additional","affiliation":[{"name":"North Carolina State University , , , ,","place":["Raleigh, North Carolina, United States, 27606"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,7,13]]},"reference":[{"key":"2026072810083246500_cit1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0176307","article-title":"Twisted oxide membranes: A perspective","volume":"12","author":"Pryds","year":"2024","journal-title":"APL\nMater."},{"key":"2026072810083246500_cit2","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adq8561","article-title":"From oxide epitaxy to\nfreestanding membranes: Opportunities and challenges","volume":"10","author":"Choo","year":"2024","journal-title":"Sci. Adv."},{"key":"2026072810083246500_cit3","doi-asserted-by":"publisher","first-page":"102286","DOI":"10.1016\/j.matt.2025.102286","article-title":"The birth\nof oxide twistronics","volume":"8","author":"Catalan","year":"2025","journal-title":"Matter"},{"key":"2026072810083246500_cit4","doi-asserted-by":"publisher","first-page":"43","DOI":"10.1038\/nature26160","article-title":"Unconventional superconductivity in magic-angle graphene\nsuperlattices","volume":"556","author":"Cao","year":"2018","journal-title":"Nature"},{"key":"2026072810083246500_cit5","doi-asserted-by":"publisher","first-page":"529","DOI":"10.1038\/s41586-023-06978-6","article-title":"A 2D ferroelectric\nvortex pattern in twisted BaTiO3 freestanding\nlayers","volume":"626","author":"Sa\u0301nchez-Santolino","year":"2024","journal-title":"Nature"},{"key":"2026072810083246500_cit6","doi-asserted-by":"publisher","first-page":"10915","DOI":"10.1038\/s41467-024-55328-1","article-title":"Polar vortex hidden\nin twisted bilayers of paraelectric SrTiO3","volume":"15","author":"Sha","year":"2024","journal-title":"Nat. Commun."},{"key":"2026072810083246500_cit7","doi-asserted-by":"publisher","first-page":"195420","DOI":"10.1103\/PhysRevB.111.195420","article-title":"Prediction of polarization\nvortices, charge modulation, flat bands,\nand moire\u0301 magnetism in twisted oxide bilayers","volume":"111","author":"Shahed","year":"2025","journal-title":"Phys. Rev. B"},{"key":"2026072810083246500_cit8","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adq0293","article-title":"Moire\u0301\npolar vortex, flat bands, and Lieb lattice in twisted\nbilayer BaTiO3","volume":"10","author":"Lee","year":"2024","journal-title":"Sci. Adv."},{"key":"2026072810083246500_cit9","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.111.L180103","article-title":"Understanding and controlling\ndipolar Moire\u0301 pattern in ferroelectric\nperovskite oxide nanolayers","volume":"111","author":"Prosandeev","year":"2025","journal-title":"Phys. Rev. B"},{"key":"2026072810083246500_cit10","doi-asserted-by":"publisher","first-page":"125131","DOI":"10.1103\/PhysRevB.111.125131","article-title":"Stacking-dependent electronic\nstructure of ultrathin perovskite bilayers","volume":"111","author":"Larson","year":"2025","journal-title":"Phys. Rev. B"},{"key":"2026072810083246500_cit11","doi-asserted-by":"publisher","first-page":"3141","DOI":"10.1038\/s41467-020-16912-3","article-title":"Strain-induced\nroom-temperature ferroelectricity in SrTiO3 membranes","volume":"11","author":"Xu","year":"2020","journal-title":"Nat. Commun."},{"key":"2026072810083246500_cit12","doi-asserted-by":"publisher","first-page":"2003780","DOI":"10.1002\/adma.202003780","article-title":"Beyond substrates: strain\nengineering of ferroelectric membranes","volume":"32","author":"Pesquera","year":"2020","journal-title":"Adv.\nMater."},{"key":"2026072810083246500_cit13","doi-asserted-by":"publisher","first-page":"2309543","DOI":"10.1002\/adfm.202309543","article-title":"Freestanding perovskite\noxide membranes: a new playground for novel\nferroic properties and applications","volume":"34","author":"Han","year":"2024","journal-title":"Adv. Funct.\nMater."},{"key":"2026072810083246500_cit14","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202521388","article-title":"Emergent Freestanding\nComplex Oxide Membranes for Multifunctional\nApplications","volume":"38","author":"Li","year":"2026","journal-title":"Adv. Mater."},{"key":"2026072810083246500_cit15","doi-asserted-by":"publisher","first-page":"87","DOI":"10.1038\/s41586-019-1255-7","article-title":"Freestanding crystalline\noxide perovskites down to the monolayer\nlimit","volume":"570","author":"Ji","year":"2019","journal-title":"Nature"},{"key":"2026072810083246500_cit16","doi-asserted-by":"publisher","first-page":"1255","DOI":"10.1038\/nmat4749","article-title":"Synthesis of freestanding\nsingle-crystal perovskite films and heterostructures\nby etching of sacrificial water-soluble layers","volume":"15","author":"Lu","year":"2016","journal-title":"Nat. Mater."},{"key":"2026072810083246500_cit17","doi-asserted-by":"publisher","first-page":"2565","DOI":"10.1038\/s41467-022-30321-8","article-title":"Twisted oxide lateral\nhomostructures with conjunction tunability","volume":"13","author":"Wu","year":"2022","journal-title":"Nat. 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Mater."},{"key":"2026072810083246500_cit21","doi-asserted-by":"publisher","first-page":"2405065","DOI":"10.1002\/adma.202405065","article-title":"Interface Design beyond Epitaxy: Oxide Heterostructures Comprising\nSymmetry-Forbidden Interfaces","volume":"36","author":"Wang","year":"2024","journal-title":"Adv. Mater."},{"key":"2026072810083246500_cit22","unstructured":"Kim, Y.-H.; Ghanbari, R.; Jung, M.-H.; Kim, Y.-M.; Xu, R.; Chi, M.\n          Establishing\nAtomic Coherence in Twisted Oxide Membranes\nContaining Volatile Elements. Preprint,  arXiv, 2026.10.48550\/arXiv.2601.20108."},{"key":"2026072810083246500_cit23","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202519300","article-title":"\u201cTear-And-Stack\u201d Twisted SrTiO3 Moire\u0301\nSuperlattices for Precise Interfacial Reconstruction and Polar Topology","volume":"38","author":"Zhang","year":"2026","journal-title":"Adv. Mater."},{"key":"2026072810083246500_cit24","doi-asserted-by":"publisher","first-page":"206","DOI":"10.1080\/00150193.2012.671741","article-title":"Incipient ferroelectric properties of NaTaO3","volume":"426","author":"Kamba","year":"2012","journal-title":"Ferroelectrics"},{"key":"2026072810083246500_cit25","doi-asserted-by":"publisher","first-page":"5944","DOI":"10.1021\/acsnano.0c10435","article-title":"Moire\u0301 patterns in 2D materials: a review","volume":"15","author":"He","year":"2021","journal-title":"ACS Nano"},{"key":"2026072810083246500_cit26","doi-asserted-by":"publisher","first-page":"256802","DOI":"10.1103\/PhysRevLett.99.256802","article-title":"Graphene bilayer with a twist: Electronic structure","volume":"99","author":"Lopes dos Santos","year":"2007","journal-title":"Phys. Rev. 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B"},{"key":"2026072810083246500_cit30","doi-asserted-by":"publisher","first-page":"224102","DOI":"10.1103\/PhysRevB.98.224102","article-title":"Relaxation and domain\nformation in incommensurate two-dimensional\nheterostructures","volume":"98","author":"Carr","year":"2018","journal-title":"Phys. Rev. B"},{"key":"2026072810083246500_cit31","doi-asserted-by":"publisher","first-page":"448","DOI":"10.1038\/s41563-019-0346-z","article-title":"Atomic and electronic\nreconstruction at the van der Waals interface\nin twisted bilayer graphene","volume":"18","author":"Yoo","year":"2019","journal-title":"Nat. Mater."},{"key":"2026072810083246500_cit32","doi-asserted-by":"publisher","first-page":"2210562","DOI":"10.1002\/adma.202210562","article-title":"Size-Induced Ferroelectricity\nin Antiferroelectric Oxide Membranes","volume":"35","author":"Xu","year":"2023","journal-title":"Adv. Mater."},{"issue":"9","key":"2026072810083246500_cit33","doi-asserted-by":"publisher","first-page":"1433","DOI":"10.1038\/s41563-025-02205-x","article-title":"Electron ptychography\nreveals a ferroelectricity dominated by anion\ndisplacements","volume":"24","author":"KP","year":"2025","journal-title":"Nat. Mater."}],"container-title":["ACS Nano"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/pubs.acs.org\/doi\/pdf\/10.1021\/acsnano.6c04794","content-type":"application\/pdf","content-version":"vor","intended-application":"unspecified"},{"URL":"https:\/\/pubs.acs.org\/ancac3\/article-pdf\/20\/29\/20647\/65889869\/acsnano.6c04794.pdf","content-type":"application\/pdf","content-version":"vor","intended-application":"syndication"},{"URL":"https:\/\/pubs.acs.org\/ancac3\/article-pdf\/20\/29\/20647\/65889869\/acsnano.6c04794.pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,7,28]],"date-time":"2026-07-28T14:42:08Z","timestamp":1785249728000},"score":1,"resource":{"primary":{"URL":"https:\/\/pubs.acs.org\/ancac3\/article\/20\/29\/20647\/5207344\/Deterministic-Fabrication-of-Large-Area-High"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,13]]},"references-count":33,"journal-issue":{"issue":"29","published-online":{"date-parts":[[2026,7,13]]},"published-print":{"date-parts":[[2026,7,28]]}},"URL":"https:\/\/doi.org\/10.1021\/acsnano.6c04794","relation":{},"ISSN":["1936-0851","1936-086X"],"issn-type":[{"value":"1936-0851","type":"print"},{"value":"1936-086X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,13]]}}}