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Substituting one component with an organic semiconductor (OSC) enables the design of hybrid heterostructures with tunable functionalities for optoelectronic, photovoltaic, and spintronic applications. In this work, exploiting scanning tunneling spectroscopy (STS), photoemission orbital tomography (POT), and G0W0 electronic structure calculations, we experimentally and theoretically demonstrate the self-assembly of an ordered single layer of pentacene (5A) above monolayer WS2, exhibiting a type-II (staggered) band alignment in the hybrid 5A\/WS2 interface. Central to this result is the synthesis of extended, atomically flat WS2 \u2500 an essential prerequisite for a highly ordered and electronically homogeneous OSC\/TMD interface \u2500 which can only be reliably achieved via bottom-up growth, most notably molecular beam epitaxy (MBE). We realize this by leveraging Au(111) as an atomically clean and conductive sample for epitaxial growth \u2500 a necessary requirement for reliable and comparable STS\/POT characterizations. The high quality of the synthesized heterostructure, together with its type-II band alignment, establishes pentacene\/WS2 as a model system for orbital-resolved studies of charge transfer, energy-level renormalization, and nonequilibrium interfacial processes in hybrid organic\/inorganic 2D heterostructures.<\/jats:p>","DOI":"10.1021\/acsnano.6c07654","type":"journal-article","created":{"date-parts":[[2026,9,5]],"date-time":"2026-09-05T04:45:27Z","timestamp":1788583527000},"page":"25410-25419","source":"Crossref","is-referenced-by-count":0,"title":["Bottom-Up\nRealization of a Type-II Organic\/Transition-Metal\nDichalcogenides Heterointerface: Pentacene on Monolayer WS2"],"prefix":"10.1021","volume":"20","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-2548-1028","authenticated-orcid":true,"given":"Michele","family":"Capra","sequence":"first","affiliation":[{"name":"TU Dortmund University , , ,","place":["Dortmund, Germany, 44227"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Christian S.","family":"Kern","sequence":"additional","affiliation":[{"name":"University of Graz , , ,","place":["Graz, Austria, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mira S.","family":"Arndt","sequence":"additional","affiliation":[{"name":"TU Dortmund University , , ,","place":["Dortmund, Germany, 44227"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-2720-4141","authenticated-orcid":true,"given":"Karl J.","family":"Schiller","sequence":"additional","affiliation":[{"name":"TU Dortmund University , , ,","place":["Dortmund, Germany, 44227"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Max","family":"Niederreiter","sequence":"additional","affiliation":[{"name":"University of Graz , , ,","place":["Graz, Austria, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Francesco","family":"Presel","sequence":"additional","affiliation":[{"name":"University of Graz , , ,","place":["Graz, Austria, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2364-5544","authenticated-orcid":true,"given":"Iolanda","family":"Di Bernardo","sequence":"additional","affiliation":[{"name":"Universidad Universidad Auto\u0301noma de Madrid and IFIMAC , ,","place":["Madrid, Spain, 28049"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1545-7831","authenticated-orcid":true,"given":"Marco","family":"Gruenewald","sequence":"additional","affiliation":[{"name":"Friedrich Schiller University Jena , , ,","place":["Jena, Germany, 07743"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6904-1909","authenticated-orcid":true,"given":"Torsten","family":"Fritz","sequence":"additional","affiliation":[{"name":"Friedrich Schiller University Jena , , ,","place":["Jena, Germany, 07743"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefan","family":"Tappertzhofen","sequence":"additional","affiliation":[{"name":"TU Dortmund University , , ,","place":["Dortmund, Germany, 44227"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9089-9061","authenticated-orcid":true,"given":"Martin","family":"Sterrer","sequence":"additional","affiliation":[{"name":"University of Graz , , ,","place":["Graz, Austria, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8057-7795","authenticated-orcid":true,"given":"Peter","family":"Puschnig","sequence":"additional","affiliation":[{"name":"University of Graz , , ,","place":["Graz, Austria, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0735-8921","authenticated-orcid":true,"given":"Mirko","family":"Cinchetti","sequence":"additional","affiliation":[{"name":"TU Dortmund University , , ,","place":["Dortmund, Germany, 44227"]}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0460-4958","authenticated-orcid":true,"given":"Giovanni","family":"Zamborlini","sequence":"additional","affiliation":[{"name":"TU Dortmund University , , ,","place":["Dortmund, Germany, 44227"]},{"name":"University of Graz , , ,","place":["Graz, Austria, 8010"]}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"316","published-online":{"date-parts":[[2026,9,4]]},"reference":[{"key":"2026092216102223800_cit1","doi-asserted-by":"publisher","first-page":"6236","DOI":"10.1021\/acs.chemrev.7b00633","article-title":"Exploring\nTwo-Dimensional Materials toward the Next-Generation Circuits: From\nMonomer Design to Assembly Control","volume":"118","author":"Zeng","year":"2018","journal-title":"Chem. 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